Broadband reflective polarizer

• US 6,099,758 A
• Filed: 09/16/1998
• Issued: 08/08/2000
• Est. Priority Date: 09/17/1997
• Status: Expired due to Fees

• Current Assignee: Merck Patent GmbH (Merck & Co., Inc.)
• Original Assignee: Merck Patent GmbH (Merck & Co., Inc.)
• Inventors: Argent, John Philip, Verrall, Mark, Coates, David, Slaney, Kim
• Primary Examiner(s): Kelly, C. H.
• Application Number:
  US09/153,997
• Time in Patent Office: 692 Days
• Field of Search: 252/585, 252/299.01, 349/96
• US Class Current: 252/585
• CPC Class Codes: C09K 19/38 Polymers
• CPC Class Codes: G02B 5/3016 involving passive liquid crystal elements optical properties of liquid crystals G02F1/0063; polarising elements associated with active liquid crystal devices G02F1/133528
• CPC Class Codes: G02F 1/133536 Reflective polarizers G02F1/13362 takes precedence
• CPC Class Codes: G02F 1/133543 Cholesteric polarisers
• CPC Class Codes: G02F 1/13362 providing polarized light, e.g. by converting a polarisation component into another one
• CPC Class Codes: G02F 1/13363 Birefringent elements, e.g. for optical compensation

Abstract

The invention relates to a broadband reflective polarizer that comprises a layer of a polymerized mesogenic material exhibiting a helically twisted molecular structure with planar alignment, said reflective polarizer being obtainable by a process wherein a mixture of a chiral polymerizable mesogenic material comprising

a) at least one achiral polymerizable mesogenic compound,

b) at least one chiral compound that can in addition be polymerizable and/or mesogenic,

c) a polymerization initiator,

is coated on a substrate or between two substrates in form of a layer, aligned in a planar orientation so that the axis of the molecular helix extends transversely to the layer, and polymerized by exposure to heat or actinic radiation, and optionally the substrates are removed from the polymerized material, characterized in that said polymerizable material is coated and polymerized between two different substrates, and/or at least one of said substrates comprises a barrier layer on the surface adjacent to the layer of said polymerizable material, to a process of preparing such a broadband reflective polarizer and to a liquid crystal display comprising such a broadband reflective polarizer

Claims

1. A broadband reflective polarizer comprising a layer of a polymerized mesogenic material exhibiting a helically twisted molecular structure with planar alignment, said reflective polarizer being obtained by a process wherein a mixture of a chiral polymerizable mesogenic material comprising

a) at least one achiral polymerizable mesogenic compound,

b) at least one chiral compound which is optionally polymerizable and/or mesogenic, and

c) a polymerization initiator,

is coated on a substrate or between two substrates in form of a layer, aligned in a planar orientation so that the axis of the molecular helix extends transversely to the layer, and polymerized by exposure to heat or actinic radiation, and optionally the substrates are removed from the polymerized material, wherein

said polymerizable material is coated and polymerized between two different substrates, and/or

at least one substrate comprises a barrier layer on the surface adjacent to the layer of said polymerizable material.

2. A reflective polarizer according to claim 1, wherein at least one of said substrates is a plastic film.

3. A reflective polarizer according to claim 1, wherein two substrates are used that exhibit different polymerization inhibition characteristics.

4. A reflective polarizer according to claim 1, wherein at least one of the substrates comprises an oxygen barrier layer.

5. A reflective polarizer according to claim 4, wherein said oxygen barrier layer is polyvinylalcohol (PVA).

6. A reflective polarizer according to claim 4, wherein the thickness of said oxygen barrier layer is from 0.5 μ

m to 20 μ

m, in particular from 1 to 10 μ

m.

7. A reflective polarizer according to claim 1, having a pitch of the molecular helix varying asymmetrically in a direction normal to the plane of the polarizer.

8. A reflective polarizer according to claim 1, with a reflection bandwidth of at least 200 nm.

9. A reflective polarizer according to claim 1, wherein the reflection characteristics of said reflective polarizer including the central wavelength, the shape or the bandwidth of the reflected spectrum, or the viewing angle dependence of these characteristics are controlled with two different substrates and/or of a barrier layer being coated onto at least one of said substrates.

10. A liquid crystal display device comprising a liquid crystal cell and a reflective polarizer according to claim 1, optionally further comprising at least one of the following components

I) an optical retardation film with a retardation which is approximately 0.25 times the wavelength of the band reflected by the reflective polarizer, p1 II) a linear polarizer, or

III) a compensation film comprising a layer of an anisotropic polymer material with a homeotropic or tilted homeotropic orientation.

11. A process for the preparation of a broadband reflective polarizer comprising a layer of a polymerized mesogenic material exhibiting a helically twisted molecular structure with planar alignment, said process comprising coating a mixture of a chiral polymerizing mesogenic material comprising

a) at least one achiral polymerizing mesogenic compound,

b) at least one chiral compound which is optionally polymerizing and/or mesogenic, and

c) a polymerizing initiator, on a substrate comprising a barrier layer or between two different substrates in form of a layer, aligned in a planar orientation so that the axis of the molecular helix extends transversely to the layer, and polymerizing by exposure to heat or actinic radiation, and optionally removing the substrates from the polymerizing material.