Method for the production of thermoplastic and thermoadhesive reinforcing materials used in the construction of footwear

• US 6,100,328 A
• Filed: 09/13/1996
• Issued: 08/08/2000
• Est. Priority Date: 09/13/1996
• Status: Expired due to Fees

• Current Assignee: Fapiquim SA
• Original Assignee: Fapiquim SA
• Inventors: Zoia, Daniel Angel, Lopez Poy, Jorge Alejandro
• Primary Examiner(s): REDDICK, MARIE L
• Application Number:
  US08/713,725
• Time in Patent Office: 1,425 Days
• Field of Search: 524/700, 524/732, 524/733, 524/788, 524/791, 524/589, 524/590, 524/599, 524/612, 264/331.12, 264/331.19
• US Class Current: 524/733
• CPC Class Codes: B29D 35/12 Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
• CPC Class Codes: B29D 35/14 Multilayered parts
• CPC Class Codes: C08G 18/08 Processes
• CPC Class Codes: C08G 18/40 High-molecular-weight compounds C08G18/2805 takes precedence
• CPC Class Codes: C08G 18/4238 derived from dicarboxylic acids and dialcohols
• CPC Class Codes: C08G 2410/00 Soles
• CPC Class Codes: C08G 69/00 Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule products obtained from isocyanates or isothiocyanates C08G18/00; polyamide-imides C08G73/14
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: C08L 75/06 from polyesters
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

Disclosed herein is a method for the production of reinforced thermoplastic and thermoadhesive polymers, used to make shaped reinforcing pieces for footwear in general, including sports shoes, these reinforced condensation polymers resulting from the polymerization of monomers such as lactones--specifically epsilon caprolactone, and condensable systems of two components, specifically polyisocyanates, polyols or polyolpolyesters--in the presence of reinforcing materials and, optionally, filling materials. The reinforced thermoplastic and thermoadhesive polymers are obtained in the form of sheets, from which the units or pieces are cut to a specified pattern, for example for the toecap, the heel piece or the inner sole.

Claims

1. A method of producing reinforced thermoplastic and thermoadhesive polymers which can be used for footwear pieces comprising the steps of:

forming a first mixture comprising

(A) a reinforcing material and

(B) (i) a lactone monomer,

(ii) a mixture of a polyisocyanate and a polyol, or

(iii) a mixture of a polyisocyanate and a polyolpolyester;

polymerizing the first mixture simultaneously with said forming step under polymerization conditions; and

shaping the polymerized mixture while being heated.

2. The method according to claim 1 wherein said reinforcing material comprises at least one of woven, felted or loose filaments.

3. The method according to claim 2, in which said reinforcing material includes filaments of 1 to 30 dtex.

4. The method according to claim 1 wherein said reinforcing material comprises at least one of fibrillar particles from 1 to 300 microns in diameter and up to 3 mm long or microgranules between 10 and 600 microns in diameter.

5. The method according to claim 1 wherein said polyisocyanate is selected from the group consisting of methylene diisocyanate, hexamethylene diisocyanate, diphenylmethane diisocyanate, and 2,4-toluene diisocyanate.

6. The method according to claim 1 wherein said polyol is a condensation product of sebacic, azelaic or adipic acid esterified with at least one of hexylene glycol, butylene glycol or ethylene glycol.

7. The method according to claim 6, in which the condensation product is a dimer.

8. The method according to claim 1 wherein the step of forming the mixture further includes adding a filler material.

9. The method according to claim 8 wherein said filler comprises at least one of ground wood, non-thermoplastic particles or thermoplastic particles.

10. The method according to claim 8, wherein said filler comprises at least one of powdered calcium carbonate or sodium silicate.

11. The method according to claim 1 wherein said lactone comprises an epsilon caprolactone.

12. The method according to claim 1 further comprising the step of cooling the heated shaped piece into solid pieces.

13. The method according to claim 1 wherein the shaping is carried out by rolling.

14. The method according to claim 1, wherein said lactone monomer comprises a caprolactone monomer.

15. The method according to claim 1, wherein said polyisocyanate comprises a diisocyanate.