Rewritable, color image recording medium and image recording method using same

• US 6,103,431 A
• Filed: 03/22/1999
• Issued: 08/15/2000
• Est. Priority Date: 09/07/1998
• Status: Expired due to Fees

• Current Assignee: Industrial Science & Technology KOZO Iizuka Director-General of Agency
• Original Assignee: Director-General of the Agency of Industrial Science and Technology, the Ministry of International Trade and Industry of Japan (Government of Japan)
• Inventors: Song, Soyoung, Tamaoki, Nobuyuki, Matsuda, Hiroo
• Primary Examiner(s): McPherson, John A.
• Application Number:
  US09/273,491
• Time in Patent Office: 512 Days
• Field of Search: 430/20, 430/962, 430/19, 349/24
• US Class Current: 430/20
• CPC Class Codes: G03C 1/73 containing organic compounds
• CPC Class Codes: G03C 2005/166 Ultraviolet sensitive material or UV exposure
• CPC Class Codes: Y10S 430/163 Radiation-chromic compound

Abstract

A rewritable, color image recording medium composed of a pair of opposed substrates at least one of which is transparent, and an intermediate layer interposed between the substrates. The intermediate layer contains at least one cholesteric liquid crystal compound having a molecular weight of not greater than 2,000 and a glass transition point of at least 35° C., and a photochromic compound. By irradiating the intermediate layer imagewise with the light through the transparent substrate, while maintaining the intermediate layer at such a temperature that the cholesteric liquid crystal compound assumes a cholesteric liquid crystal phase, an image is formed. The image may be fixed by rapidly cooling the recording medium to a temperature lower than the glass transition.

Claims

1. A rewritable, color image recording medium comprising a pair of opposed substrates at least one of which is transparent, and an intermediate layer interposed between said substrates, said intermediate layer comprising at least one cholesteric liquid crystal compound having a molecular weight of not greater than 2,000 and a glass transition point of at least 35°

C., and a photochromic compound, said photochromic compound being present in an amount of 0.5-10% by weight based on the weight of said cholesteric liquid crystal compound.

2. A recording medium as set forth in claim 1, wherein said cholesteric liquid crystal compound is represented by the formula:

space="preserve" listing-type="equation">Z--O--CO--R--CO--O--Y

wherein Z and Y are each independently selected from the group consisting of a cholesteryl group, a hydrogen atom and an alkyl group with the proviso that at least one of Z and Y stands for a cholesteryl group, and R stands for a divalent hydrocarbyl group having 2-30 carbon atoms.

3. A recording medium as set forth in claim 1, wherein said cholesteric liquid crystal compound is represented by the formula:

space="preserve" listing-type="equation">Z--O--CO--R--CO--O--Y

wherein Z and Y are each independently selected from the group consisting of a cholesteryl group, a hydrogen atom and an alkyl group with the proviso that at least one of Z and Y stands for a cholesteryl group, and R stands for a divalent hydrocarbyl group represented by the formula;

space="preserve" listing-type="equation">--(CH.sub.2).sub.m --C.tbd.C--C.tbd.C--(CH.sub.2).sub.n --

wherein m and n are each independently an integer of 1 or more with the proviso that the total of m and n does not exceed 30.

4. A recording medium as set forth in claim 1, wherein said photochromic compound is an azobenzene compound.

5. A method of recording a color image, comprising the steps of:

(a) providing a rewritable, color image recording medium comprising a pair of opposed substrates at least one of which is transparent, and an intermediate layer interposed between said substrates, said intermediate layer comprising at least one cholesteric liquid crystal compound having a molecular weight of not greater than 2,000 and a glass transition point of at least 35°

C., and a photochromic compound capable of changing a color thereof upon irradiation with a light, said photochromic compound being present in an amount of 0.5-10% by weight based on the weight of said cholesteric liquid crystal compound;

(b) while maintaining said intermediate layer at such a temperature that said cholesteric liquid crystal compound assumes a cholesteric liquid crystal phase, irradiating said intermediate layer imagewise with the light through the transparent substrate to form an image;

(c) then rapidly cooling said recording medium obtained in step (b) to a temperature lower than said glass transition point to fix said image.

6. A method as set forth in claim 5, wherein said cooling is at a rate of at least 1°

C./second.

7. A method as set forth in claim 5, wherein step (b) is by irradiation with ultraviolet rays.