Water vapor plasma treatment of glass surfaces

• US 6,106,653 A
• Filed: 03/31/1998
• Issued: 08/22/2000
• Est. Priority Date: 03/31/1998
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Yeganeh, Mohsen, Dougal, Shawn M., Polizzotti, Richard S.
• Primary Examiner(s): DIXON, MERRICK L
• Application Number:
  US09/052,045
• Time in Patent Office: 875 Days
• Field of Search: 427/398.3, 427/374.1, 427/37, 427/38, 427/422, 427/316, 156/73.1, 156/73.3, 156/379.6, 156/272.2
• US Class Current: 156/272.2
• CPC Class Codes: C03C 17/30 with silicon-containing compounds
• CPC Class Codes: C03C 2218/31 Pre-treatment
• CPC Class Codes: C03C 23/006 by plasma or corona discharge
• CPC Class Codes: C03C 25/40 Organo-silicon compounds
• CPC Class Codes: C03C 25/6293 Plasma or corona discharge

Abstract

The density of hydroxyl groups present on the surface of glass, such as E-glass fibers, is increased by subjecting the surface to a radio frequency induced gas plasma containing water vapor. Surfaces so treated exhibit enhanced adsorption of hydrolyzed organo silane coupling agents applied to improve adhesion between glass fibers and resin matrices in the manufacture of reinforced composites.

Claims

1. A process for increasing the number density of hydroxyl groups on a clean glass surface comprising contacting said surface with a radio frequency induced gas plasma containing water vapor.

2. The process of claim 1 wherein said plasma is at least about 30% saturated with water vapor.

3. The process of claim 2 wherein said plasma is at least 50% saturated with water vapor.

4. The process of claim 1 wherein said gas comprises air.

5. The process of claim 1 wherein said glass comprises glass fibers.

6. The process of claim 1 wherein said contacting takes place at a temperature in the range of about 20°

C. to 100°

C.

7. The process of claim 6 wherein said temperature is about 25°

C.

8. A hydroxyl group--containing glass surface prepared by the process of claim 1.