Polymerization process controller

• US 6,106,785 A
• Filed: 06/30/1997
• Issued: 08/22/2000
• Est. Priority Date: 06/30/1997
• Status: Expired due to Fees

• Current Assignee: Honeywell Incorporated (Honeywell International Inc.)
• Original Assignee: Honeywell Incorporated (Honeywell International Inc.)
• Inventors: Horak, Josef, Havlena, Vladimir, Jelinek, Jan
• Primary Examiner(s): Knode, Marian C.
• Assistant Examiner(s): OHORODNIK, SUSAN K
• Application Number:
  US08/885,562
• Time in Patent Office: 1,149 Days
• Field of Search: 422/108, 422/109, 422/116, 422/110-111, 422/62, 364/150, 364/151, 364/528.01, 364/528.03, 364/528.04
• US Class Current: 422/109
• CPC Class Codes: B01J 19/0006 Controlling or regulating processes controlling or regulating in general G05
• CPC Class Codes: B01J 19/0013 Controlling the temperature of the process
• CPC Class Codes: B01J 2219/00058 Temperature measurement
• CPC Class Codes: B01J 2219/00094 Jackets
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 2/00 Processes of polymerisation
• CPC Class Codes: G05B 13/042 in which a parameter or coefficient is automatically adjusted to optimise the performance

Abstract

A batch polymerization process controller using inferential sensing to determine the integral reaction heat which in turn is used to indicate the degree of polymerization of the reaction mixture batch. The system uses a reaction temperature compared with a desired temperature, and the result is used as a feedback to monitor and control the process. One version of the process controller also uses a feedforward signal which is an integral reaction heat indication from a process model. In another version of the process controller, the integral reaction heat is compared with a desired integral reaction heat, and result is used as another feedback to monitor and control the process. Heat production and reaction temperature profiles may be used, along with the thermokinetic equations to determine the polymerization process and reactor models which are utilized by the process controller to optimize the polymerization process in terms of efficient use of cooling water and desired polymerization of each mixture batch.

Claims

1. A batch polymerization process control device for controlling a batch process in a reactor, comprising:

a controller connected to the reactor, for receiving a process temperature feedback signal from said reactor and providing reactor cooling control signals to said reactor; and

an inferential sensor, connected to said reactor and to said controller, for receiving parameter signals from said reactor, providing a reaction model heat feedforward signal to said controller, and receiving reactor cooling control signals from said controller.

2. The batch polymerization process control device of claim 1, wherein said controller comprises a summer for receiving the process temperature feedback signal and a predetermined process temperature signal, and outputting a signal indicating a difference between the process temperature and the predetermined process temperature.

3. The batch polymerization process control device of claim 2, wherein said inferential sensor comprises:

a reactor model wherein said reactor model receives parameter signals from said reactor and the reactor cooling control signals from said controller and outputs a signal indicating total heat removed from said reactor; and

a reaction model for receiving the signal indicating the total heat removed from said reactor and providing the reaction model heat feedforward signal to said controller and to said reactor model.

4. The batch polarization process control device of claim 3, inferential sensor further comprising a coordinator for receiving a reaction model temperature signal from said reaction model and the process temperature feedback signal from said reactor, coordinating corresponding states of activity and simulated activity of said reactor and said reactor model, respectively, and outputting a coordinating signal.

5. The batch polarization process control device of claim 4, wherein said reaction model comprises:

a combiner for receiving the signal indicating the total heat removed from said reactor and the coordinating signal, and having an output;

a scale factor adjuster having an input connected to the output of said combiner, and having an output;

a first integrator having an input connected to the output of said scale factor adjuster, and having an output that provides the reaction model temperature signal to said reactor model and to said coordinator;

a first processor having an input connected to the output of said first integrator, having an output for providing a rate of reaction model heat production signal to said combiner; and

a second integrator having an input connected to the output of said first processor and having an output for providing the reaction model heat feedforward signal to said controller, to said reactor model, and to the input of said first processor.

6. The batch polymerization process control device of claim 5, wherein said reaction model further comprises a second processor having an input connected to the output of said second integrator of said reaction model, and having an output, wherein said second processor converts the reaction model heat feedforward signal into a signal indicative of a degree of the polymerization process of the process in said reactor.

7. A batch polymerization process control device for controlling a batch process in a reactor, comprising:

a first summer for receiving a reaction model heat feedback signal and a predetermined reaction heat signal and outputting a heat difference signal;

a second summer for receiving a process temperature signal from said reactor and a predetermined process temperature signal and outputting a process temperature difference signal;

a controller for receiving the heat difference signal and the process temperature difference signal and providing a dosing signal and reactor cooling control signals to said reactor; and

an inferential sensor, connected to said reactor and to said controller, for receiving parameter signals from the reactor, providing a reaction model heat feedback signal to said controller, and receiving the reactor cooling control signals from said controller.

8. The batch polymerization process control device of claim 7, wherein said inferential sensor comprises:

a reactor model wherein said reactor model receives some parameter signals from said reactor and the reactor cooling control signals from said controller and outputs a signal indicating total heat removed from said reactor; and

a reaction model for receiving the signal indicating the total heat removed from said reactor and providing the reaction model heat feedback signal to said first summer and to said reactor model.

9. The batch polymerization process control device of claim 8 inferential sensor further comprising a coordinator for receiving a reaction model temperature signal from said reaction model and the process temperature signal from said reactor, coordinating corresponding states of activity and simulated activity of said reactor and said reactor model, respectively, and outputting a coordinating signal.

10. The batch polymerization process control device of claim 9, wherein said reaction model comprises:

a combiner for receiving the signal indicating the total heat removed from said reactor and the coordinating signal, and providing an output;

a scale factor adjuster having an input connected to the output of said combiner, and having an output;

a first integrator having an input connected to the output of said scale factor adjuster, and having an output that provides the reaction model temperature signal to said reactor model and to said coordinator;

a first processor for receiving the dosing signal from said controller, having an input connected to the output of said first integrator, and having an output for providing a rate of reaction model heat production signal to said combiner; and

a second integrator having an input connected to the output of said first processor and having an output for providing the reaction model heat feedback signal to said first summer, to said reactor model, and to the input of said first processor.

11. The batch polymerization process control device of claim 10, wherein said reaction model further comprises a second processor having an input connected to the output of said second integrator of said reaction model, and having an output, wherein said second processor converts the reaction model heat feedback signal into a signal indicative of a degree of polymerization of the batch process in said reactor.