Metal-matrix diamond or cubic boron nitride composites

• US 6,106,957 A
• Filed: 03/10/1999
• Issued: 08/22/2000
• Est. Priority Date: 03/19/1998
• Status: Expired due to Term

• Current Assignee: Smith International Incorporated (Schlumberger NV)
• Original Assignee: Smith International Incorporated (Schlumberger NV)
• Inventors: Fang, Zhigang
• Primary Examiner(s): MAI, NGOCLAN THI
• Application Number:
  US09/266,111
• Time in Patent Office: 531 Days
• Field of Search: 75/245, 75/246, 75/244, 428/545, 419/16, 419/23, 419/32, 419/35
• US Class Current: 428/545
• CPC Class Codes: B01J 2203/062 Diamond
• CPC Class Codes: B01J 2203/0645 Boronitrides
• CPC Class Codes: B01J 2203/0655 Diamond
• CPC Class Codes: B01J 2203/066 Boronitrides
• CPC Class Codes: B01J 2203/0685 Crystal sintering
• CPC Class Codes: B01J 3/062 characterised by the composition of the materials to be processed
• CPC Class Codes: B22F 2201/013 Hydrogen
• CPC Class Codes: B22F 2998/10 Processes characterised by the sequence of their steps
• CPC Class Codes: B22F 2999/00 Aspects linked to processes or compositions used in powder metallurgy
• CPC Class Codes: B22F 3/02 Compacting only
• CPC Class Codes: B22F 3/14 simultaneously
• CPC Class Codes: B22F 3/15 Hot isostatic pressing
• CPC Class Codes: B22F 3/24 After-treatment of workpieces or articles B22F3/1146 takes precedence
• CPC Class Codes: B22F 9/04 starting from solid material, e.g. by crushing, grinding or milling C22C1/1084 takes precedence; crushing, grinding or milling, in general, see the relevant subclasses, e.g. B02C
• CPC Class Codes: B24D 18/0054 by impressing abrasive powder in a matrix
• CPC Class Codes: B24D 3/06 metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
• CPC Class Codes: C22C 26/00 Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
• CPC Class Codes: Y10T 428/12007 Component of composite having metal continuous phase interengaged with nonmetal continuous phase

Abstract

A metal-matrix diamond or cubic boron nitride composite and method of making the same are disclosed. The metal-matrix/diamond composite includes grains of diamond uniformly distributed in a metal matrix. Alternatively, grains of cubic boron nitride may be used. Suitable metals for the metal matrix material may include nickel, cobalt, iron, and mixtures or alloys thereof. Other transition metals also may be used. The metal-matrix/diamond or metal-matrix/cubic boron nitride composite has high fracture toughness due to its fine microstructure. Such a metal-matrix/diamond or metal-matrix/cubic boron nitride composite is suitable for use in blanks or cutting elements for cutting tools, drill bits, dressing tools, and wear parts. It also may be used to make wire drawing dies.

Claims

1. A super-hard composite material comprising:

a super-hard component representing about 40%-85% of the volume of the super-hard material;

a metal matrix component representing about 15%-60% of the volume of the super-hard material, the metal matrix component selected from the group of nickel, iron, cobalt, molybdenum, tungsten, niobium, tantalum, vanadium and alloys thereof; and

wherein the super-hard component and the metal matrix component are combined in a uniform composite mixture with an actual density at least 95% of the theoretical maximum density of the composite mixture.

2. The super-hard composite material of claim 1 wherein the super-hard component is cubic boron nitride.

3. The super-hard composite material of claim 1 wherein the super-hard component is diamond.

4. The super-hard composite material of claim 3 wherein the diamond is natural.

5. The super-hard composite material of claim 3 wherein the diamond is synthetic.

6. The super-hard composite material of claim 1 wherein the size of grains of the super-hard component is between 1 μ

m and 30 μ

m.

7. The super-hard composite material of claim 1 wherein the super-hard component is coated with a layer of metal different from the metal matrix component.

8. The super-hard composite material of claim 7 wherein the metal in the layer of metal is selected from the group consisting of copper, titanium nitride, titanium carbonitride, zirconium nitride, cobalt, tungsten, and nickel.

9. The super-hard material of claim 1 wherein the size of grains of the metal matrix component is between 1 μ

m and 30 μ

m.

10. A super-hard composite material comprising:

a super-hard component representing about 40%-85% of the volume of the super-hard material;

a metal matrix component representing about 15%-60% of the volume of the super-hard material, the metal matrix component selected from the group of nickel, iron, cobalt, molybdenum, tungsten, niobium, tantalum, vanadium and alloys thereof; and

wherein the super-hard component and the metal matrix component are combined in a uniform composite mixture under cold compression so as to have an actual density at least 95% of the theoretical maximum density of the composite mixture.

11. The super-hard composite material as defined in claim 10 wherein the super-hard component comprises cubic boron nitride.

12. The super-hard composite material as defined in claim 10 wherein the super-hard component comprises diamond.

13. The super-hard composite material as defined in claim 10 wherein the super-hard component comprises grains having a size between 1 micrometer and 30 micrometers.

14. The super-hard composite material as defined in claim 10 wherein grains of the super-hard component are coated with a metal different from the metal forming the metal matrix component.

15. The super-hard composite material as defined in claim 14 wherein the metal coating the grains of the super-hard material is selected from the group of nickel, iron, cobalt, molybdenum, tungsten, niobium, tantalum, vanadium and alloys thereof.

16. A super-hard composite material comprising:

a super-hard component representing about 40%-85% of the volume of the super-hard material;

a metal matrix component representing about 15%-60% of the volume of the super-hard material, the metal matrix component selected from the group of nickel, iron, cobalt, molybdenum, tungsten, niobium, tantalum, vanadium and alloys thereof; and

wherein the super-hard component and the metal matrix component are combined in a uniform composite mixture so as to have an actual density at least 95% of the theoretical maximum density of the composite mixture, and wherein particles of said super-hard component are substantially separated from each other by particles of said metal matrix component.

17. The super-hard composite material as defined in claim 16 wherein the super-hard component comprises cubic boron nitride.

18. The super-hard composite material as defined in claim 16 wherein the super-hard component comprises diamond.

19. The super-hard composite material as defined in claim 16 wherein the super-hard component comprises grains having a size between 1 micrometer and 30 micrometers.

20. The super-hard composite material as defined in claim 16 wherein grains of the super-hard component are coated with a metal different from the metal forming the metal matrix component.

21. The super-hard composite material as defined in claim 20 wherein the metal coating the grains of the super-hard material is selected from the group of nickel, iron, cobalt, molybdenum, tungsten, niobium, tantalum, vanadium and alloys thereof.