Breathable backing for an adhesive article

• US 6,107,219 A
• Filed: 02/11/1998
• Issued: 08/22/2000
• Est. Priority Date: 02/11/1998
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Joseph, Eugene G., Stickels, Steven C.
• Primary Examiner(s): ZIRKER, DANIEL R
• Application Number:
  US09/022,303
• Time in Patent Office: 923 Days
• Field of Search: 442/340, 442/341, 442/347, 442/361, 442/362, 442/363, 442/364, 442/400, 442/401, 442/151, 428/343
• US Class Current: 442/361
• CPC Class Codes: A61F 13/023 wound covering film layers without a fluid retention layer
• CPC Class Codes: A61F 13/025 having a special distribution arrangement of the adhesive
• CPC Class Codes: A61L 15/42 Use of materials characterised by their function or physical properties liquid bandages A61L26/00
• CPC Class Codes: C09J 2301/302 the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
• CPC Class Codes: C09J 2400/263 in the substrate
• CPC Class Codes: C09J 7/21 Paper; Textile fabrics
• CPC Class Codes: D01F 8/06 with at least one polyolefin as constituent
• CPC Class Codes: D01F 8/16 with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
• CPC Class Codes: D04H 1/56 in association with fibre formation, e.g. immediately following extrusion of staple fibres
• CPC Class Codes: D04H 3/16 with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 442/2754 Pressure-sensitive adhesive
• CPC Class Codes: Y10T 442/622 Microfiber is a composite fiber
• CPC Class Codes: Y10T 442/637 Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
• CPC Class Codes: Y10T 442/638 Side-by-side multicomponent strand or fiber material
• CPC Class Codes: Y10T 442/64 Islands-in-sea multicomponent strand or fiber material
• CPC Class Codes: Y10T 442/641 Sheath-core multicomponent strand or fiber material
• CPC Class Codes: Y10T 442/68 Melt-blown nonwoven fabric

Abstract

There is provided pressure-sensitive adhesive coated breathable nonwoven tape backing substrate where the nonwoven tape backing comprises a fibrous nonwoven web formed in part by multicomponent fibers having an adhesive component region. The multicomponent fibers are distributed throughout the width dimension of the nonwoven tape backing such that adhesive component region is exposed on both outer faces of the nonwoven tape backing. The adhesive component region is preferably a pressure-sensitive adhesive region formed by hot melt coextrusion of at least two components to form the multicomponent fibers. A pressure-sensitive adhesive tape layer is coated onto at least one face of the nonwoven tape backing which pressure-sensitive adhesive tape layer is preferably of the same type of adhesive as that forming the adhesive region of the multicomponent fiber or is at least compatible with the adhesive region of the multicomponent fiber such that the adhesive has enhanced adhesive properties to the pressure-sensitive adhesive tape layer.

Claims

1. A pressure-sensitive adhesive coated substrate comprising a nonwoven backing substrate comprising conjugate multicomponent melt spun fibers having at least one pressure-sensitive adhesive component region forming at least a portion of the outer surface of the multicomponent fibers and at least one non-adhesive component region, the conjugate multicomponent fibers being distributed throughout the width dimension of the nonwoven backing substrate such that the adhesive component region is exposed on both outer faces of the nonwoven backing substrate, and a pressure-sensitive adhesive layer coated onto at least one face of the nonwoven backing substrate which pressure-sensitive adhesive layer has adhesive properties to the adhesive component region of the multicomponent melt spun fibers.

2. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive layer is breathable.

3. The pressure-sensitive adhesive coated substrate of claim 2 wherein the pressure-sensitive adhesive layer is a nonwoven web comprised of pressure-sensitive adhesive fibers.

4. The pressure-sensitive adhesive coated substrate of claim 2 wherein the nonwoven backing substrate has a basis weight of from 15 to 200 g/m².

5. The pressure-sensitive adhesive coated substrate of claim 2 wherein the nonwoven backing substrate has a basis weight of from 75 to 125 g/m².

6. The pressure-sensitive adhesive coated substrate of claim 3 wherein the nonwoven adhesive layer has a basis weight of from 15 to 125 g/m².

7. The pressure-sensitive adhesive coated substrate of claim 1 wherein the multicomponent melt spun fibers are melt blown fibers.

8. The pressure-sensitive adhesive coated substrate of claim 1 wherein the multicomponent melt spun fibers are spun bond fibers.

9. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive component region of the multicomponent fibers and the pressure-sensitive adhesive layer are compatible adhesives.

10. The pressure-sensitive adhesive coated substrate of claim 1 wherein the nonwoven backing substrate comprises said multicomponent fibers and commingled second fibers.

11. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive component region material comprises 1 to 60 percent by weight of the nonwoven backing substrate.

12. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive component region material comprises 15 to 40 percent by weight of the nonwoven backing substrate.

13. The pressure-sensitive adhesive coated substrate of claim 1 wherein the non-adhesive component region is selected from the group consisting of a polymer, copolymer or blend of a polystyrene, a polyolefin, a polyurethane, a polyester, a polyamide, an epoxy, a polyacrylate or a polyvinyl acrylate.

14. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive component region comprises a tackified polystyrene polydiene block copolymer adhesive.

15. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive component region comprises a polyacrylate adhesive.

16. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive component region comprises a tackified acrylate copolymer adhesive.

17. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive component region comprises a tackified polydiorganosiloxane polyurea copolymer represented by the repeating unit:

##STR3## wherein;

each R is a moiety that independently is;

an alkyl moiety having 1 to 12 carbon atoms optionally substituted with trifluoroalkyl or vinyl groups;

a vinyl moiety or higher alkenyl moiety represented by the formula --R² (CH₂)_a CH═

CH₂ wherein R² is --(CH₂)_b -- or --(CH₂)_c CH═

CH-- and a is 1, 2, or 3, b is 0, 3, or 6, and c is 3, 4, or 5;

a cycloalkyl moiety having 6 to 12 carbon atoms optionally substituted with alkyl, fluoroalkyl, and vinyl groups;

an aryl moiety having 6 to 20 carbon atoms optionally substituted with alkyl, cycloalkyl, fluoroalkyl and vinyl groups;

a perfluoroalkyl group;

a fluorine-containing group;

or

a perfluoroether-containing group;

each Z is a polyvalent moiety that is an arylene moiety or an aralkylene moiety having 6 to 20 carbon atoms, or an alkylene or cycloalkylene moiety having 6 to 20 carbon atoms;

each Y is a polyvalent moiety that independently is an alkylene moiety having 1 to 10 carbon atoms, or an aralkylene moiety or an arylene moiety having 6 to 20 carbon atoms;

each D is independently selected from the group of hydrogen, an alkyl moiety of 1 to 10 carbon atoms, phenyl, and a moiety that completes a ring structure including Y to form a heterocycle;

B is a polyvalent moiety selected from the group consisting of alkylene, aralkylene, cycloalkylene, phenylene, polyalkylene oxide, including for example, polyethylene oxide, polypropylene oxide, polytetramethylene oxide, and copolymers and mixtures thereof;

m is a number that is 0 to 1000;

n is a number that is equal to or greater than 1; and

p is a number that is about 5 or larger

18. The pressure-sensitive adhesive coated substrate of claim 2 wherein the pressure-sensitive adhesive layer is an intermittent adhesive layer.

19. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive coated substrate comprises a bandage.

20. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive adhesive layer is a continuous adhesive layer.

21. The pressure-sensitive adhesive coated substrate of claim 1 wherein the pressure-sensitive layer is a fibrous nonwoven adhesive.

22. The pressure-sensitive adhesive coated substrate of claim 21 wherein the fibrous nonwoven adhesive comprises a tackified polystyrene polydiene block copolymer adhesive.

23. The pressure-sensitive adhesive coated substrate of claim 21 wherein the fibrous nonwoven adhesive comprises a polyacrylate adhesive.

24. The pressure-sensitive adhesive coated substrate of claim 21 wherein the fibrous nonwoven adhesive comprises a tackified polyacrylate adhesive.

25. The pressure-sensitive adhesive coated substrate of claim 21 wherein the fibrous nonwoven adhesive comprises a tackified polydiorganosiloxane polyurea copolymer represented by the repeating unit:

##STR4## wherein;

each R is a moiety that independently is;

an alkyl moiety having 1 to 12 carbon atoms optionally substituted with trifluoroalkyl or vinyl groups;

a vinyl moiety or higher alkenyl moiety represented by the formula --R² (CH₂)_a CH═

CH₂ wherein R² is --(CH₂)_b -- or --(CH₂)_c CH═

CH-- and a is 1, 2, or 3, b is 0, 3, or 6, and c is 3, 4, or 5;

a cycloalkyl moiety having 6 to 12 carbon atoms optionally substituted with alkyl, fluoroalkyl, and vinyl groups;

an aryl moiety having 6 to 20 carbon atoms optionally substituted with alkyl, cycloalkyl, fluoroalkyl and vinyl groups;

a perfluoroalkyl group;

a fluorine-containing group;

or

a perfluoroether-containing group;

each Z is a polyvalent moiety that is an arylene moiety or an aralkylene moiety having 6 to 20 carbon atoms, or an alkylene or cycloalkylene moiety having 6 to 20 carbon atoms;

each Y is a polyvalent moiety that independently is an alkylene moiety having 1 to 10 carbon atoms, or an aralkylene moiety or an arylene moiety having 6 to 20 carbon atoms;

each D is independently selected from the group of hydrogen, an alkyl moiety of 1 to 10 carbon atoms, phenyl, and a moiety that completes a ring structure including Y to form a heterocycle;

B is a polyvalent moiety selected from the group consisting of alkylene, aralkylene, cycloalkylene, phenylene, polyalkylene oxide, including for example, polyethylene oxide, polypropylene oxide, polytetramethylene oxide, and copolymers and mixtures thereof;

m is a number that is 0 to 1000;

n is a number that is equal to or greater than 1; and

p is a number that is about 5 or larger