Methods of refining agricultural residues to absorbent cellulose, xylose, and plant nutrient liquor, and products produced by such methods

• US 6,110,323 A
• Filed: 08/03/1999
• Issued: 08/29/2000
• Est. Priority Date: 08/03/1998
• Status: Expired due to Fees

• Current Assignee: Betafoods Corporation, Ceres (Land O'Lakes Incorporated)
• Original Assignee: Betafoods Corporation
• Inventors: Marsland, Charles
• Primary Examiner(s): Chin, Peter
• Assistant Examiner(s): Halpern, Mark
• Application Number:
  US09/368,249
• Time in Patent Office: 392 Days
• Field of Search: 127/37, 127/34, 162/81, 162/78, 162/82, 162/90, 162/97, 162/21, 162/23, 162/14, 162/16, 162/91, 162/96, 162/99, 162/189
• US Class Current: 162/14
• CPC Class Codes: C05F 11/00 Other organic fertilisers
• CPC Class Codes: D21C 3/003 with organic compounds D21C3/20 and D21C3/222 take precedence
• CPC Class Codes: D21C 3/04 with acids, acid salts or acid anhydrides D21C3/003 and D21C3/222 take precedence
• CPC Class Codes: D21C 5/00 Other processes for obtaining cellulose, e.g. cooking cotton linters obtaining fibres for spinning D01C; Processes characterised by the choice of cellulose-containing starting materials

Abstract

A method of creating a number of separate product streams from an agricultural waste material, comprising: providing a starting material consisting of an agricultural waste material; hydrolyzing the starting material with an acid solution at atmospheric pressure, and temperatures not exceeding about 100° C., to create an absorbent, hydrolyzed solid residue and a xylose-containing liquor; reserving the xylose-containing liquor; and delignifying the hydrolyzed solid residue with a basic solution, to create a fiber solid residue suitable for use as an absorbent material, and a dissolved lignin-containing solution.

Claims

1. A method of creating a number of separate product streams from an agricultural waste material, comprising:

providing a starting material consisting of an agricultural waste material;

hydrolyzing said starting material with an acid solution at atmospheric pressure, and temperatures not exceeding about 100°

C., to create an absorbent, hydrolyzed solid residue and a xylose-containing liquor;

reserving said xylose-containing liquor; and

delignifying said hydrolyzed solid residue with a basic solution with urea, to create a highly absorbent fiber residue suitable for use as an absorbent material, and a dissolved lignin-containing solution.

2. The method of claim 1 in which said hydrolysis step takes place with a mineral acid.

3. The method of claim 2 in which said mineral acid comprises sulfuric acid.

4. The method of claim 2 in which said hydrolysis step takes place at a pH between about 0 and about 3, at a temperature of at least about 70°

C.

5. The method of claim 1 further including the step of washing said hydrolyzed solid residue with a water wash including a complexing agent, to remove metals.

6. The method of claim 1 in which said delignification step takes place with an hydroxide solution.

7. The method of claim 6 in which said delignification step takes place at a pH of between about 11 and about 14, at a temperature not exceeding about 100°

C. and at atmospheric pressure.

8. The method of claim 1 in which said hydroxide solution includes potassium hydroxide.

9. The method of claim 1 further including reserving said lignin-containing solution for use as a plant nutrient including both potassium and nitrogen.

10. The method of claim 1 further including bleaching said high crude fiber solid residue in at least one bleaching step to create a bleached solid residue.

11. The method of claim 10 in which said bleaching step uses a water solution of a bleaching agent.

12. The method of claim 11 in which said bleaching step also uses urea.

13. The method of claim 11 in which said bleaching step takes place at atmospheric pressure, basic pH, and elevated temperature of no more than about 100°

C.

14. The method of claim 12, further including adding phosphoric acid during said bleaching step.

15. The xylose-containing liquor produced by the method of claim 1.

16. The dissolved lignin-containing solution produced by the method of claim 1.

17. The fiber solid residue produced by the method of claim 1.

18. The bleached solid residue produced by the method of claim 14, having a water absorption capacity of at least about 1000%.

19. The method of claim 1 in which said starting material is selected from the group of materials consisting of grain hulls, straws, and corn plant materials.