Slurry circulation process and system for fluidized particle contacting

• US 6,110,356 A
• Filed: 05/06/1998
• Issued: 08/29/2000
• Est. Priority Date: 05/06/1998
• Status: Expired due to Fees

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Schnaith, Mark, Lacijan, Lawrence A, Hedrick, Brian W.
• Primary Examiner(s): Griffin, Walter D.
• Assistant Examiner(s): NORTON, NADINE GEORGIANNA
• Application Number:
  US09/073,482
• Time in Patent Office: 846 Days
• Field of Search: 208/113, 208/120.01, 585/648, 585/653
• US Class Current: 208/113
• CPC Class Codes: C10G 11/18 according to the "fluidised-bed" technique

Abstract

The invention improves a system and apparatus for the recovery of fine solid particles entering the slurry system of a fluidized catalytic contacting process by returning a portion of the recovered solids from the main separator directly back to the reactor stripper. The invention recovers fine particulate material from an FCC main column and returns the particulate material to an FCC stripper to reduce the amount of fine material that continues to recycle through the FCC reactor and product separator. By returning fine particulate material from the FCC product separation zone directly to a low velocity area of the stripping section, the invention breaks the reactor--main column recycle loop that concentrates the fines. Fines entering the reactor stripper will not be carried back into the cyclones for unwanted return to the main column. By the recycling of fines to the stripper via this invention, the fines concentration in the slurry system can decrease by up to 300%.

Claims

1. A process for the production and separation of a fluidized catalytic cracking (FCC) product stream wherein the product stream contains fine catalyst particle, the process comprising:

a) passing an FCC feedstock and regenerated catalyst particles to a reaction zone to convert said feedstock;

b) separating catalyst particles from gaseous hydrocarbons and recovering an FCC product stream containing fine catalyst particles and passing separated particles to a relatively dense bed;

c) passing the FCC product stream to a fractionation zone and to separating the FCC product stream in the fractionation zone into at least a relatively light hydrocarbon stream and a relatively heavy hydrocarbon stream;

d) recovering a particle recycle stream containing fine catalyst particles and at least a portion of the relatively heavy hydrocarbon stream;

e) concentrating particles in the particle recycle stream to provide a concentrated particle stream having a higher concentration of particles than the particle recycle stream;

f) injecting the concentrated particle stream directly into the relatively dense bed at an injection point;

g) withdrawing a coked catalyst stream comprising at least a portion of the fine particles from the relatively dense bed at a location below the injection point and passing the coked catalyst stream to a regeneration zone; and

,

h) combusting coke from catalyst particles in the regeneration zone to generate flue gas that passes out of the regeneration zone carrying entrained fine catalyst particles therewith to supply regenerated catalyst to the reaction zone.

2. The process of claim 1 wherein said relatively dense bed comprises a stripping zone.

3. The process of claim 1 wherein the relatively heavy hydrocarbon stream comprises a hydrocarbon stream in the boiling range of a light cycle oil or a heavier hydrocarbon stream having a higher boiling point range.

4. The process of claim 1 wherein the fractionation zone comprises an FCC main column that separates the product stream into at least a light cycle oil stream and a bottom stream having a boiling point of at least 650°

F., a filter recovers fine catalyst particles from the bottom stream and the light cycle oil stream or a lower boiling fraction returns the fine particles from the filter to the relatively dense bed.

5. The process of claim 1 wherein the recycle stream containing fine particles comprises a portion of an FCC main column bottoms stream.

6. The process of claim 1 wherein the concentrated particle stream passes to a hydroclone to increase the concentration of fine catalyst particles and to produce a more concentrated stream that injects the fine particles from the concentrated particle stream into the relatively dense bed.

7. The process of claim 6 wherein the concentrated stream is the underflow from the hydroclone that passes directly to an FCC stripper and the overflow from the hydroclone comprises a light cycle of heavy naphtha boiling range stream.

8. The process of claim 1 wherein the fine catalyst particles comprise particles having a size of less than 40 μ

m.

9. The process of claim 8 wherein the concentration of fine catalyst particles having a size of less 20 μ

m in the FCC product stream is in a range of 1.5 to 0.05 wt % of the FCC product stream.

10. The process of claim 1 wherein the separated particles in the relatively dense bed comprise spent catalyst and the relatively dense bed has a temperature that is less than the temperature of the regenerated catalyst particles that enter the reaction zone.