Filled polyetherimide resin compositions

• US 6,111,031 A
• Filed: 12/09/1997
• Issued: 08/29/2000
• Est. Priority Date: 12/09/1997
• Status: Expired due to Term

• Current Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Nazareth, Darryl, Puyenbroek, Robert
• Primary Examiner(s): Acquah, Samuel A.
• Application Number:
  US08/987,453
• Time in Patent Office: 994 Days
• Field of Search: 524/261, 524/401, 524/423, 524/425, 524/430, 524/432, 524/436, 524/437, 524/492, 525/55, 525/132, 525/422, 525/437, 525/540
• US Class Current: 525/422
• CPC Class Codes: C08L 23/00 Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 79/08 Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers

Abstract

A thermoplastic resin composition that contains a polyetherimide resin, a mineral filler and a gloss-enhancing additive selected from linear polysiloxane polymers, polyethylene resins and crystalline thermoplastic resins imparts improved surface gloss to shaped articles molded therefrom.

Claims

1. A thermoplastic resin composition, comprising:

(a) a polyetherimide resin;

(b) an inert particulate filler; and

(c) a gloss-enhancing additive selected from the group consisting of linear polysiloxane polymers, polyethylene resins and crystalline thermoplastic resins and mixtures thereof, in an amount that is effective to improve the surface gloss of articles molded from the thermoplastic resin composition.

2. The composition of claim 1, wherein the composition comprises, based on 100 parts by weight of combined amount of polyetherimide resin and particulate inert filler, from 35 to 99.9 parts by weight polyetherimide resin, from 0.1 to 65 parts by weight inert particulate filler and from 0.01 to 10 parts by weight gloss-enhancing additive.

3. The composition of claim 1, wherein the polyetherimide resin comprises structural units of the formula (I):

##STR15## wherein the divalent T moiety bridges the 3,3'"'"', 3,4'"'"', 4,3'"'"', or 4,4'"'"' positions of the aryl rings of the respective aryl imide moieties of formula (I);

T is --O-- or a group of the formula --O--Z--O--;

Z is a divalent radical selected from the group consisting of formulae (II);

##STR16## wherein X is a member selected from the group consisting of divalent radicals of the formulae (III);

##STR17## wherein y is an integer from 1 to about 5, and q is 0 or 1;

R is a divalent organic radical selected from the group consisting of;

(a) aromatic hydrocarbon radicals having from 6 to about 20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals having from 2 to about 20 carbon atoms, (c) cycloalkylene radicals having from 3 to about 20 carbon atoms, and (d) divalent radicals of the general formula (IV);

##STR18## where Q is a member selected from the group consisting of formulae (V);

##STR19## where y'"'"' is an integer from about 1 to about 5.

4. The composition of claim 1, wherein the polyetherimide resin is the reaction product formed by melt polymerization of 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride with metaphenylene diamine.

5. The composition of claim 1, wherein the polyetherimide resin has a molecular weight of from about 10,000 to about 65,000 grams per mole.

6. The composition of claim 1, wherein the polyetherimide resin has a molecular weight of from about 10,000 to about 55,000 grams per mole.

7. The composition of claim 1, wherein the inert particulate filler comprises a mineral filler selected from the group consisting of alumina, barium carbonate, barium sulfate, barium titanate, barium trioxide, bismuth trioxide, calcium carbonate, magnesium silicate, strontium ferrite, titanium dioxide, wollastonite, zinc oxide and mixtures thereof.

8. The composition of claim 1, wherein the inert particulate filler comprises barium sulfate.

9. The composition of claim 1, wherein the inert particulate filler has an average particle size of from about 0.2 micrometer to about 40 micrometers.

10. The composition of claim 1, wherein the composition comprises from 0.01 to 2.0 parts by weight, based on 100 parts by weight of combined amount of the polyetherimide resin and the inert particulate filler, of a methyl-terminated poly(dimethyl siloxane) or a poly(methyl hydrogen siloxane) fluid as the gloss enhancing additive.

11. The composition of claim 1, wherein the composition comprises 0.5 to 8 parts by weight, based on 100 parts by weight of combined amount of the polyetherimide resin and the inert particulate filler, of a high density polyethylene resin as the gloss enhancing additive.

12. The composition of claim 1, wherein the composition comprises 0.05 to 10 parts by weight, based on 100 parts by weight of combined amount of the polyetherimide resin and the inert particulate filler, of a crystalline thermoplastic resin as the gloss enhancing additive.

13. The composition of claim 12, wherein the crystalline thermoplastic resin comprises a crystalline thermoplastic polyamide resin.

14. The composition of claim 13, wherein the crystalline thermoplastic polyamide resin comprises a nylon 6 or a nylon 6,6.

15. The composition of claim 12, wherein the crystalline thermoplastic resin comprises a crystalline thermoplastic polyester resin.

16. The composition of claim 12, wherein the crystalline thermoplastic resin comprises a poly(alkylene terephthalate) resin.

17. A method for making a filled thermoplastic resin article, comprising molding the thermoplastic resin composition of claim 1 under molding conditions effective to subject the thermoplastic resin composition to a shear rate of greater than 8,500 reciprocal seconds.

18. The method of claim 17, wherein the molding conditions are effective to subject the thermoplastic resin to shear rate of greater than or equal to 10,000 reciprocal seconds.

19. The method of claim 17, wherein the molding conditions are effective to subject the thermoplastic resin to shear rate of greater than or equal to 12,000 reciprocal seconds.

20. A shaped article made by the method of claim 17.

21. A shaped article made by molding the composition of claim 1.

22. A thermoplastic resin composition, comprising the composition obtained by blending a polyetherimide resin, an inert particulate filler;

and a gloss-enhancing additive selected from the group consisting of linear polysiloxane polymers, polyethylene resins and crystalline thermoplastic resins and mixtures thereof, in an amount that is effective to improve the surface gloss of articles molded from the thermoplastic resin composition.