Aromatics and/or heavies removal from a methane-rich feed gas by condensation and stripping

• US 6,112,549 A
• Filed: 01/09/1998
• Issued: 09/05/2000
• Est. Priority Date: 06/07/1996
• Status: Expired due to Term

• Current Assignee: Conocophillips Company (ConocoPhillips)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Houser, Clarence G., Yao, Jame, Low, William R.
• Primary Examiner(s): DOERRLER, WILLIAM CHARLES
• Application Number:
  US09/004,979
• Time in Patent Office: 970 Days
• Field of Search: 62/618, 62/620, 62/625, 62/632, 62/640, 62/643, 62/647, 62/935
• US Class Current: 62/620
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0045 by vaporising a liquid return stream
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/021 using a deep flash recycle loop
• CPC Class Codes: F25J 1/0237 integrating refrigeration provided for liquefaction and purification/treatment of the gas to be liquefied, e.g. heavy hydrocarbon removal from natural gas details related to rectification F25J3/02; details related to partial condensation F25J3/06; working-up natural gas C10L3/10
• CPC Class Codes: F25J 1/0238 Purification or treatment step is integrated within one refrigeration cycle only, i.e. the same or single refrigeration cycle provides feed gas cooling (if present) and overhead gas cooling
• CPC Class Codes: F25J 1/0265 comprising cores associated exclusively with the cooling of a refrigerant stream, e.g. for auto-refrigeration or economizer
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2200/74 Refluxing the column with at least a part of the partially condensed overhead gas
• CPC Class Codes: F25J 2210/06 Splitting of the feed stream, e.g. for treating or cooling in different ways
• CPC Class Codes: F25J 2220/60 Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2235/60 the fluid being (a mixture of) hydrocarbons
• CPC Class Codes: F25J 2245/02 Recycle of a stream in general, e.g. a by-pass stream
• CPC Class Codes: F25J 2270/02 Internal refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/08 Internal refrigeration by flash gas recovery loop
• CPC Class Codes: F25J 2270/12 External refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/60 Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
• CPC Class Codes: F25J 2280/02 : Control in general, load changes, different modes ("runs"), measurements
• CPC Class Codes: F25J 3/0209 : Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 : separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 : separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: F25J 3/0242 : separation of CnHm with 3 carbon atoms or more
• CPC Class Codes: F25J 3/0295 : Start-up or control of the process; Details of the apparatus used, e.g. sieve plates, packings

Abstract

A process and associated apparatus for removing aromatics and/or higher molecular weight hydrocarbons from a methane-based gas stream comprising the steps of (a) condensing a minor portion of the methane-based gas stream thereby producing a two-phase stream, (b) feeding said two phase stream to the upper section of a column, (c) removing from the upper section of the column an aromatic- and/or heavies-depleted gas stream, (d) removing from the lower section of the column an aromatic- and/or heavies-rich liquid stream, (e) contacting via indirect heat exchange the aromatic- and/or heavies-rich liquid stream with a methane-rich stripping gas thereby producing a warmed liquid stream and a cooled stripping gas stream, (f) feeding said cooled stripping gas stream to the lower section of the column; and (g) contacting said two-phase stream and the cooled stripping gas stream in the column thereby producing the aromatic- and/or heavies-depleted gas stream and the aromatic- and/or heavies-rich liquid stream.

Claims

1. A apparatus comprising:

(a) a condenser;

(b) a column;

(c) a heat exchanger providing for indirect heat exchange between two fluids;

(d) a conduit between said condenser and the upper section of the column for flow of a two-phase stream to the column;

(e) a conduit connected to the upper section of the column for the removal of a vapor stream from the column;

(f) a conduit between said column and heat exchanger for flow of a cooled gas stream from the heat exchanger;

(g) a conduit between said column and said heat exchanger for flow of a liquid stream from the column;

(h) a conduit connected to the heat exchanger for flow of a warmed liquid stream from the heat exchanger; and

(i) a conduit connected to the heat exchanger for flow of a gas stream to the heat exchanger.

2. A apparatus according to claim 1 additionally comprised of a

(j) a first conduit;

(k) a splitting means connected to the first conduit;

(l) a second conduit and a third conduit connected to said splitting means where said second conduit is connected to the condenser;

(m) a control valve connected at the inlet side to the second conduit,

(n) a conduit connected to the outlet side of said control valve;

(o) a junction or combining means connected to said conduit of element (n) and the conduit of element (d) prior to connection with the column;

(p) a temperature sensing means with sensing element situated in conduit of element (d) between said junction means and connection with the column; and

(q) a control means operably attached to control valve of element (m) and operably responsive to input received from the temperature sensing device of element (p) and a temperature setpoint.

3. An apparatus according to claim 1 additionally comprising of

(j) a pressure reduction means situated in said conduit of element (g).

4. An apparatus according to claim 1 wherein said column contains 2 to 12 theoretical stages.

5. An apparatus according to claim 1 additional comprising two or more indirect heat exchange means situated in a sequential manner, conduits between each heat exchange means for the sequential flow of a common fluid through the heat exchangers whereupon the last conduit is connected to the condenser of element (a), conduits to and from each heat exchanger providing for the flow of a refrigerating agent to each heat exchanger and wherein the conduit of element (i) is in flow communication with one of the above conduits for flow of a common fluid between heat exchangers.

6. An apparatus according to claim 5 wherein propane is employed as the refrigerating agent in at least one of the heat exchange means;

and ethane, ethylene or a mixture thereof is employed as the refrigerating agent in at least one of heat exchange means.

7. A apparatus according to claim 1 additionally comprising:

(j) a fractionation column;

(k) a reboiler;

(l) a second condenser;

(m) an overhead conduit connecting the upper section of the column to the condenser for removal of the overhead vapor, a reflux conduit connected the condenser to the column for the return of the reflux fluid, a vapor product conduit connected to the condenser for removal of uncondensed vapors;

(n) a bottoms conduit connecting the lower section of the column to the reboiler, a vapor conduit for returning stripping vapor to the column, and a bottoms product line connected to the reboiler for removal of unvaporized product from the reboiler; and

wherein the conduit of element (h) is connected to the fractionation column at a point between the top and the bottom theoretical stages.

8. A apparatus according to claim 7 wherein the condenser of element (l) is comprised of an indirect heat exchange means and coolant to such means is provided by a junction connecting the cooling side of the indirect heat exchange means to the conduit of element (g).

9. An apparatus according to claim 7 additionally comprising

(o) a pressure reduction means situated in conduit (g) and wherein the condenser of element (k) is comprised of an indirect heat exchange means and said coolant to such means is provided by a junction connecting the cooling side of the indirect heat exchange means to the conduit of element (g) downstream of pressure reduction means (o).

10. An apparatus according to claim 7 additionally comprising a

(o) a conduit connected to condenser of element (a),

(p) a compressor connected at the inlet port to the vapor conduit line of element (m);

and

(q) a conduit connecting the outlet port of said compressor element (p) to the conduit of element (o).

11. A apparatus according to claim 5 additionally comprising:

(j) a fractionation column;

(k) a reboiler;

(l) a condenser;

(m) an overhead conduit connecting the upper section of the column to the condenser for removal of the overhead vapor, a reflux conduit connecting the condenser to the column for the return of the reflux fluid, a vapor product conduit connected to the condenser for removal of uncondensed vapors;

(n) a bottoms conduit connecting the lower section of the column to the reboiler, a vapor conduit for returning stripping vapor to the column, and a bottoms product line connected to the reboiler for removal of unvaporized product from the reboiler; and

wherein the conduit of element (h) is connected to the fractionation column at a midpoint location.

12. An apparatus according to claim 11 additionally comprising a

(o) a compressor connected at the inlet port to the vapor conduit line of element (m) and

(p) conduit connecting the outlet port of said compressor to one of the common flow conduits of claim 5.