Process for preparing poly(trimethylene terephthalate) carpet yarn

• US 6,113,825 A
• Filed: 11/13/1997
• Issued: 09/05/2000
• Est. Priority Date: 05/08/1995
• Status: Expired due to Fees

• Current Assignee: PTT Poly Canada, L.P.
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Chuah, Hoe Hin
• Primary Examiner(s): Tentoni, Leo B.
• Application Number:
  US08/969,726
• Time in Patent Office: 1,027 Days
• Field of Search: 264/103, 264/210.7, 264/210.8, 264/211.12, 264/211.14, 28/271
• US Class Current: 264/103
• CPC Class Codes: D01D 5/16 using rollers, or like mechanical devices, e.g. snubbing pins
• CPC Class Codes: D01F 6/62 from polyesters

Abstract

Poly(trimethylene terephthalate) is formed into a bulk continuous filament yarn by melt-spinning poly(trimethylene terephthalate) at a temperature of 240 to 280° C. to produce a plurality of spun filaments, cooling the spun filaments, converging the spun filaments into a yarn, drawing the yarn at a first draw ratio of 1.01 to about 2 in a first drawing stage defined by at least one feed roller and at least one first draw roller wherein at least one feed roller is operated at less than 100° C. and each of the draw rollers is heated to a temperature greater than that of the feed roller and between 50 and 150° C., subsequently drawing the yarn at a second draw ratio of at least about 2.2 times that of the first draw ratio in the second drawing stage defined by at least one first draw roller and at least one second draw roller, wherein at least one second draw roller is heated to a temperature greater than that of the first draw roller and within the range of 100 to 200° C., and texturing the drawn yarn and cooling the textured filaments.

Claims

1. A process for preparing bulk continuous fiber yarn from poly(trimethylene terephthalate) comprising:

(a) melt-spinning poly(trimethylene terephthalate) at a temperature within the range of about 250 to about 280°

C. to produce a plurality of spun filaments;

(b) cooling the spun filaments;

(c) converging the spun filaments into a yarn;

(d) drawing the yarn at a first draw ratio within the range of about 1.01 to about 2 in a first drawing stage defined by at least one feed roller and at least one first draw roller, each of said at least one feed roller operated at a temperature less than about 100°

C. and each of said at least one draw roller heated to a temperature greater than the temperature of said at least one feed roller and within the range of about 50 to about 150°

C.;

(e) subsequently drawing the yarn at a second draw ratio of at least about 2.2 times that of the first draw ratio in a second drawing stage defined by said at least one first draw roller and at least one second draw roller, each of said at least one second draw roller heated to a temperature greater than said at least one first draw roller and within the range of about 100 to about 200°

C.; and

(f) winding the drawn yarn.

2. The process of claim 1 which further comprises texturing the drawn yarn and cooling the textured filaments.

3. The process of claim 1 in which each of said at least one feed rollers is maintained at a temperature within the range of about 40 to about 85°

C.

4. The process of claim 1 in which the first draw ratio is within the range of about 1.01 to about 1.35.

5. The process of claim 1 in which the second draw ratio is within the range of about 2.2 to about 3.4 times the first draw ratio.

6. The process of claim 1 in which the poly(trimethylene terephthalate) has an intrinsic viscosity within the range of about 0.80 to about 1.0 dl/g.

7. The process of claim 1 in which the poly(trimethylene terephthalate) has an intrinsic viscosity within the range of about 0.88 to about 0.96 dl/g.

8. The process of claim 1 in which the poly(trimethylene terephthalate) is the product of condensation polymerization of the reaction product of 1,3-propane diol and at least one of terephthalic acid and dimethyl terephthalate.

9. The process of claim 1 in which the poly(trimethylene terephthalate) is the product of condensation polymerization of the reaction product of (a) a mixture of 1,3-propane diol and a second alkane diol and (b) a mixture of terephthalic acid and isophthalic acid.

10. The process of claim 2 in which texturing is carried out with an air jet at a pressure within the range of about 50 to about 120 psi.

11. The process of claim 2 in which the product yarn bulk is within the range of about 15 to about 45 percent.

12. The process of claim 2 in which the yarn is fed to texturing via a feed roll maintained at a temperature within the range of about 150 to about 200°

C.

13. The process of claim 2 in which the texturing step is carried out at a temperature within the range of about 150 to about 210°

C.