Silicone resin-containing emulsion composition, method for making same, and article having a cured film of same

• US 6,114,440 A
• Filed: 06/14/1999
• Issued: 09/05/2000
• Est. Priority Date: 11/07/1996
• Status: Expired due to Fees

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Kizaki, Hiroaki, Yamamoto, Akira, Yamaya, Masaaki, Furuya, Masahiro
• Primary Examiner(s): YOON, TAE H
• Application Number:
  US09/332,124
• Time in Patent Office: 449 Days
• Field of Search: 524/506, 524/588, 524/862, 524/865, 524/860, 524/866, 528/32, 528/33, 427/387, 428/446
• US Class Current: 524/865
• CPC Class Codes: C08F 283/122 on to saturated polysiloxanes containing hydrolysable groups, e.g. alkoxy-, thio-, hydroxy-
• CPC Class Codes: C08G 77/16 to hydroxyl groups
• CPC Class Codes: C08L 33/12 Homopolymers or copolymers of methyl methacrylate
• CPC Class Codes: C09D 183/04 Polysiloxanes

Abstract

A silicone resin-containing emulsion composition is prepared by emulsion polymerizing a solution containing a water-insoluble silanol group-bearing silicone resin and a radical polymerizable vinyl monomer and substantially free of an organic solvent. The emulsion may further contain a film-forming assistant having a boiling point of at least 100° C. and soluble or uniformly dispersible in water. The emulsion can be coated and cured into a film having mar resistance, weather resistance, and chemical resistance.

Claims

1. A silicone resin-containing emulsion composition comprising an emulsion polymerized product obtained from a solution containing as the main components:

(1) 100 parts by weight of a water-insoluble silanol group-bearing silicone resin of the following average compositional formula (1);

space="preserve" listing-type="equation">R.sup.1.sub.m R.sup.2.sub.n Si(OH).sub.p (OX).sub.q O.sub.(4-m-n-p-q)/2(

     1)

wherein R¹ is an unsubstituted monovalent hydrocarbon group, R² is a monovalent hydrocarbon group substituted by (i) a halogen atom, (ii) an epoxy functional group, (iii) a (meth)acryl functional group, (iv) an amino functional group, (v) a sulfur-containing functional group, (vi) an alkyl ether functional group, (vii) a (polyoxyalkylene)alkyl ether group, (viii) a carboxyl, sulfonyl or other anionic group or (ix) a quaternary ammonium salt structure-containing group, OX is a hydrolyzable group where X is a monovalent hydrocarbon group, letters m, n, p and q are numbers satisfying 0.5≦

m≦

1.8, 0≦

n≦

1.0, 0<

p≦

1.5, 0≦

q≦

0.5, 0.5≦

m+n≦

1.8, and 0<

p+q≦

1.5, and

(2) 10 to 1,000 parts by weight of a radical polymerizable vinyl monomer containing 0.01 to 10 mol % of a hydrolyzable silane having a vinyl polymerizable functional group represented by the following formula (2);

##STR20## wherein R¹ and X are as defined above, R³ is hydrogen or methyl, R⁴ is a divalent organic group, and letter r is equal to 0, 1 or 2,

said solution being substantially free of an organic solvent having a boiling point of less than 100°

C., an organic solvent which is insoluble or not uniformly dispersed in water, and an aromatic organic solvent.

2. The composition of claim 1 wherein the amount of the organic solvent is 0 to 5 parts by weight per 100 parts by weight of components (1) and (2) combined.

3. The composition of claim 1 wherein the content p of the silanol group per silicon atom is 0.05 to 0.8.

4. The composition of claim 1 wherein in the water-insoluble silanol group-bearing silicone resin, the content of methyl in all the organic substituent groups (R¹ +R²) is at least 80 mol %.

5. The composition of claim 1 further comprising at least one pigment selected from the group consisting of an extender pigment, a coloring pigment and a corrosion-preventing pigment.

6. The composition of claim 1 further comprising a water-dispersible organic resin, a water-soluble organic resin or a mixture thereof.

7. An article having formed thereon a cured film of the composition of claim 1.

9. A silicone resin-containing emulsion composition comprising

(A) an emulsion polymerized product according to claim 1, and

(C) a compound containing a IA group and/or IIA group metal.

10. The composition of claim 9 wherein 0.001 to 20 parts by weight of the compound containing a IA group and/or IIA group metal (C) is present per 100 parts by weight of components (1) and (2) combined and the pH of the composition is in a range of 8 to 12.

11. The composition of claim 9 wherein the compound (C) is an inorganic salt.

12. The composition of claim 10 wherein the compound (C) contains Li, Na, K or Cs.

13. The composition of claim 12 wherein the compound (C) is selected from the group consisting of sodium carbonate, potassium carbonate, sodium bicarbonate and potassium bicarbonate.

14. An article having formed thereon a cured film of the composition of claim 9.

15. A method of preparing an article comprising the steps of:

forming a film of the composition of claim 9 on a substrate, and

curing the film at room temperature.

16. The composition of claim 1, wherein the substituent for the R² group in formula (1) is a trifluoropropyl, perfluorobutylethyl, perfluorooctylethyl, 3-chloropropyl, 2-(chloromethylphenyl)ethyl, 3-glycidyloxypropyl, 2-(3,4-epoxycyclohexyl)ethyl, 5,6-epoxyhexyl, 9,10-epoxydecyl, 3-(meth)acryloxypropyl, (meth)acryloxymethyl, 11-(meth)acryloxyundecyl, 3-aminopropyl, N-(2-aminoethyl)-aminopropyl, 3-(N-phenylamino)propyl, 3-dibutylamino-propyl, 3-mercaptopropyl, 2-(4-mercaptomethylphenyl)ethyl, polyoxyethylenoxypropyl, 3-hydroxycarbonylpropyl, or 3-tributylammoniumpropyl group.

17. The composition of claim 1, wherein the composition has a total amount of organic solvent with a boiling point of less than 100°

C., organic solvent which is insoluble or not uniformly dispersed in water and aromatic organic solvent, of 0 to 2 parts by weight per 100 parts by weight of the silanol group-bearing silicone resin and radical polymerizable vinyl monomer combined.

8. An article having formed thereon a cured film of a composition comprising as main components:

(A) an emulsion polymerized product obtained from a solution containing (1) 100 parts by weight of a water-insoluble silanol group-bearing silicone resin of the following average compositional formula (1);

space="preserve" listing-type="equation">R.sup.1.sub.m R.sup.2.sub.n Si(OH).sub.p (OX).sub.q O.sub.(4-m-n-p-q)/2(

     1)

wherein R¹ is an unsubstituted monovalent hydrocarbon group, R² is a monovalent hydrocarbon group substituted by (i) a halogen atom, (ii) an epoxy functional group, (iii) a (meth)acryl functional group, (iv) an amino functional group, (v) a sulfur-containing functional group, (vi) an alkyl ether functional group, (vii) a (polyoxyalkylene)alkyl ether group, (viii) a carboxyl, sulfonyl or other anionic group or (ix) a quaternary ammonium salt structure-containing group, OX is a hydrolyzable group where X is a monovalent hydrocarbon group, letters m, n, p and q are numbers satisfying 0.5≦

m <

1.8, 0≦

n≦

1.0, 0<

p≦

1.5, 0≦

q≦

0.5, 0.5≦

m+n≦

1.8, and 0<

p+q≦

1.5, and (2) 10 to 1,000 parts by weight of a radical polymerizable vinyl monomer containing 0.01 to 10 mol % of a hydrolyzable silane having a vinyl polymerizable functional group represented by the following formula (2);

##STR21## wherein R¹ and X are as defined above, R³ is hydrogen or methyl, R⁴ is a divalent organic group, and letter r is equal to 0, 1 or 2, and

(B) a film-forming assistant having a boiling point of at least 100°

C. and soluble or uniformly dispersible in water.