Measuring equipment for isolating a plurality of probes contacting a sample

• US 6,119,508 A
• Filed: 01/27/1998
• Issued: 09/19/2000
• Est. Priority Date: 01/31/1997
• Status: Expired due to Term

• Current Assignee: Horiba Limited
• Original Assignee: Horiba Limited
• Inventors: Mori, Takeshi, Tarui, Yoshihiro
• Primary Examiner(s): LARKIN, DANIEL SEAN
• Application Number:
  US09/014,236
• Time in Patent Office: 966 Days
• Field of Search: 73/53.01, 324/438, 324/439
• US Class Current: 73/53.01
• CPC Class Codes: G01N 27/4166 measuring a particular property of an electrolyte

Abstract

Measuring equipment, such as a portable pH meter system, can include a plurality of probes for measuring different properties of a sample with each of the probes contacting the sample simultaneously. A reference source line connected to an appropriate reference source can be connected to each probe, while a signal line connected to each probe can provide a measurement signal. A switch assembly is provided for each of the probes in order to isolate the respective probes from each other to prevent any interference when measuring the sample.

Claims

1. Measuring equipment for measuring a plurality of properties of a sample with separate probes contacting the sample simultaneously, comprising:

a plurality of probes;

a reference source line connected to each probe;

a signal line connected to each probe for providing a measurement signal; and

a first switch assembly connected to a first reference source line and a first signal line to isolate one of said plurality of probes from generating any interference while measuring the sample.

2. The measuring equipment of claim 1 wherein the first switch assembly includes a first switch connected to the first reference source line and a second switch connected to the first signal line and the first and second switches are opened to prevent a probe of said plurality of probes connected to the first signal line and the first reference source line from interfering with said other probe'"'"'s measurements.

3. The measuring equipment of claim 2 wherein another of said plurality of probes include a second switch assembly including a third switch connected to a second reference source line, the third switch is closed to connect the second reference source line when the said other probe is measuring and is open to disconnect the second reference source line to prevent interference.

4. The measuring equipment of claim 3 wherein another of said plurality of probes include a third switch assembly including a fourth switch and a fifth switch connected to an operational amplifier and the operational amplifier is connected to a third reference source line.

5. The measuring equipment of claim 4 wherein a common reference source is connected to each reference source line.

6. The measuring equipment of claim 4 wherein the first switch assembly is connected to a dissolved oxygen probe, the second switch assembly is connected to a pH probe and the third switch assembly is connected to a conductivity probe.

7. The measuring equipment of claim 6 wherein the measuring equipment is of a dimension to be hand-carried by the user.

8. The measuring equipment of claim 1 wherein the first switch assembly includes a pair of switches and an operational amplifier connected to the first reference source line.

9. The measuring equipment of claim 8 wherein another of said plurality of probes include a second switch assembly including a third switch connected to a second reference source line, the third switch is closed to connect the second reference source line when the said other probe is measuring and is open to disconnect the second reference source line to prevent interference with said remaining plurality of probes.

10. The measuring equipment of claim 9 wherein said plurality of probes includes a dissolved oxygen probe.

11. The measuring equipment of claim 9 wherein said plurality of probes includes a pH probe and a conductivity probe.

12. Measuring equipment for measuring pH and dissolved oxygen, comprising:

a pH probe for providing a pH measurement signal;

a dissolved oxygen probe for providing a measurement dissolved oxygen signal, the pH probe and dissolved oxygen probe have a configuration for simultaneously contacting a sample;

a first reference source;

a first reference source line connecting the pH probe to the first reference source;

a second reference source;

a second reference source line connecting the dissolved oxygen probe to the second reference source;

means for processing the pH signal and dissolved oxygen signal to provide respectively a measurement of pH and dissolved oxygen;

a first switch assembly connected to the first reference source line;

a second switch assembly connected to the second reference source line; and

means for controlling the first and second switch assemblies to isolate the pH probe and the dissolved oxygen probe during their consecutive measurements to prevent interference in providing their measurement signals.

13. Apparatus for measuring dissolved oxygen and pH in a sample, comprising:

a dissolved oxygen probe (1) and a pH probe (8) for immersion in the same sample;

means for isolating the dissolved oxygen probe from a reference potential (7) during measurement with the pH probe, characterized by

means (12) for isolating the pH probe from the reference potential during measurement with the dissolved oxygen probe; and

means (4,

     6) for short-circuiting electrodes of the dissolved oxygen probe during measurement with the pH probe.

14. The apparatus as in claim 13, comprising additionally:

a conductivity probe (21) for measuring the conductivity of the same sample;

means (22) for connecting the conductivity probe to a conductivity-voltage converter (24);

means (23) for connecting the conductivity probe to a reference potential (7), and

switching means (25, 26, 27,

     28) for isolating the conductivity probe from the reference potential during measurement with the pH probe, whereby the switching means is constituted by a non-inverting type operational amplifier (27) and first and second switches (26,

     28), the reference potential is connected to a non-inverting input of the operational amplifier (27b), the connecting means (23) is connected to the output of the operational amplifier via the first switch (26) and to an inverting input (27b) of the operational amplifier via the second switch (28), and the two switches (26,

     28) open and close simultaneously.

15. An apparatus for measuring conductivity and pH of a sample, comprising a conductivity probe (21) and a pH probe (8) for immersion in the same sample characterized by:

means (22) for connecting the conductivity probe to a conductivity-voltage converter (24);

means (23) for connecting the conductivity probe to a reference potential (7), and

switching means (25,26,27,28) for isolating the conductivity probe from the reference potential during measurement with the pH probe, whereby the switching means is constituted by a non-inverting type operational amplifier (27) and first and second switches (26,28), the reference potential is connected to a non-inverting input of the operational amplifier (27b), the connecting means (23) is connected to the output of the operational amplifier via the first switch (26) and to an inverting input (27b) of the operational amplifier via the second switch (28), and the two switches (26,28) open and close simultaneously.

16. An apparatus for measuring a conductivity of and a dissolved oxygen in a sample, comprising a conductivity probe (21) and a dissolved oxygen probe (1) for immersion in the same sample characterized by:

means (23) for connecting the conductivity probe to a conductivity-voltage converter (24);

means (23) for connecting the conductivity probe to a reference potential (7);

a first switching means (25,26,27,28) for isolating the conductivity probe from the reference potential during measurement with the dissolved oxygen probe, whereby the first switching means is constituted by a non-inverting type operational amplifier (27) and first and second switches (26,28), and the reference potential is connected to a non-inverting input of the operational amplifier (27b), the connecting means (23) is connected to the output of the operational amplifier via the first switch (26) and to an inverting input (27b) of the operational amplifier via the second switch (28), and the two switches (26,28) open and close simultaneously, and a second switching means (4,6) for isolating the dissolved oxygen probe and short-circuiting its electrodes during measurement with the conductivity probe.