Herbicidal compositions of polyoxyalkylene alkylamine surfactants having reduced eye irritation

• US 6,121,199 A
• Filed: 05/26/1999
• Issued: 09/19/2000
• Est. Priority Date: 08/09/1990
• Status: Expired due to Term

• Current Assignee: Monsanto Technology LLC (Bayer AG)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Berger, Paul D., Jimenez, Antonio M.
• Primary Examiner(s): CLARDY, S
• Application Number:
  US09/320,356
• Time in Patent Office: 482 Days
• Field of Search: 504/206
• US Class Current: 504/206
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 25/32 Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
• CPC Class Codes: A01N 57/20 containing acyclic or cycloaliphatic radicals
• CPC Class Codes: C09K 23/017 Mixtures of compounds
• CPC Class Codes: C09K 23/16 Amines or polyamines
• CPC Class Codes: Y10S 516/05 Organic amine, amide, or n-base containing
• CPC Class Codes: Y10S 516/07 Organic amine, amide, or n-base containing
• CPC Class Codes: Y10S 516/916 The compound contains repeating -OCnH2n-, i.e. repeating unsubstituted oxyalkylene

Abstract

There are provided compositions of certain polyoxyalkylene alkylamine surfactants having eye irritation reduced by the addition of an effective amount of a sulfated polyoxyalkylene alkylphenol alcohol sulfate, polyoxyalkylene alcohol sulfate, mono- or dialcohol phosphate mono- or di-(polyoxyalkylene alcohol) phosphate, polyoxyalkylene alkylphenol carboxylate or polyoxyalkylene alcohol carboxylate surfactant. Also provided are pesticidal, particularly herbicidal, compositions comprising polyoxyalkylene alkylamine surfactants having eye irritation reduced by addition of these eye irritation reducing compounds.

Claims

1. An aqueous concentrate herbicidal composition comprising

(a) about 5% to about 50% by weight of a water soluble salt of glyphosate;

(b) an amine surfactant component consisting of (i) one or more compounds having the chemical structure ##STR8## wherein x is a number from 7 to about 19, n₁ and n₂ are numbers independently selected from 1 to about 30, the average sum of n₁ and n₂ is 2 or greater, and R₁ and R₂ are C₂ -C₄ alkylene radicals; and

(ii) one or more glycols selected from ethylene glycol, propylene glycol, polyethylene glycol and polypropylene glycol in an amount of zero to about 30% by weight of the amine surfactant component;

said amine surfactant component being in an amount sufficient to cause unacceptable eye irritation;

(c) an effective eye irritation reducing amount of a phosphate surfactant component consisting of a phosphate monoester or mixture of phosphate monoesters having the chemical structure ##STR9## where R⁷ is C₈ -C₂₀ alkyl or C₈ -C₂₀ alkylphenyl, R is C₂ -C₄ alkylene, and m is a number from zero to about 60;

alone or in combination with a phosphate diester or mixture of phosphate diesters having the chemical structure ##STR10## where R⁷, R and m are as defined immediately above; and

(d) water in an amount sufficient to provide a stable aqueous solution of the salt of glyphosate in presence of the amine and phosphate surfactant components.

2. The composition of claim 1 wherein the water soluble salt of glyphosate is selected from the trimethylsulfonium, ammonium, isopropylamine, sodium and potassium salts.

3. The composition of claim 1 wherein the water soluble salt of glyphosate is present in an amount of about 35% to about 45% by weight.

4. The composition of claim 1 wherein, in the amine surfactant component, R₁ and R₂ are each ethylene and the average sum of n₁ and n₂ is about 4 to about 20.

5. The composition of claim 1 wherein the amine surfactant component comprises polyoxyethylene tallowamine having about 8 to about 13 moles of ethylene oxide.

6. The composition of claim 1 wherein, in the phosphate surfactant component, R¹ is nonylphenol and m is about 4.

7. The composition of claim 1 wherein the phosphate monoester or monoesters are present in an amount that exceeds the amount of the phosphate diester or diesters.

8. The composition of claim 1 wherein the amine surfactant component and the phosphate surfactant component are present in a total surfactant amount of about 5% to about 25% by weight.

9. The composition of claim 1 wherein the amine surfactant component and the phosphate surfactant component are present in a total surfactant amount such that the weight ratio of glyphosate, expressed as acid equivalent, to total surfactant is about 1:

1 to about 5;

1.

10. The composition of claim 1 wherein the weight ratio of the amine surfactant component to the phosphate surfactant component is about 60:

40 to about 85;

15.

11. The composition of claim 1 wherein the weight ratio of the amine surfactant component to the phosphate surfactant component is about 70:

30 to about 85;

15.

12. The composition of claim 1 wherein the weight ratio of the amine surfactant component to the phosphate surfactant component is about 80:

20 to about 85;

15.

13. The composition of claim 1 wherein (a) the amine surfactant component comprises polyoxyethylene tallowamine having about 8 to about 13 moles of ethylene oxide, (b) in the phosphate surfactant component, R¹ is nonylphenol and m is about 4, and (c) the phosphate monoester is present in an amount that exceeds the amount of the phosphate diester.

14. A method of controlling vegetation comprising diluting a composition of claim 1 in a suitable amount of water to form a sprayable composition, and spraying a herbicidally effective amount of the sprayable composition on foliage of the vegetation.