Reversible inorganic electrochromic solution device

• US 6,122,092 A
• Filed: 05/20/1999
• Issued: 09/19/2000
• Est. Priority Date: 05/20/1999
• Status: Expired due to Fees

• Current Assignee: Rutgers University
• Original Assignee: Telcordia Technologies Incorporated (Telefonaktiebolaget LM Ericsson)
• Inventors: DuPasquier, Aurelien, Tarascon, Jean-Marie
• Primary Examiner(s): Ben, Loha
• Application Number:
  US09/317,079
• Time in Patent Office: 488 Days
• Field of Search: 359/265, 359/266, 359/267, 359/269, 359/271, 359/272, 359/273, 359/270, 204/418, 252/586, 252/582
• US Class Current: 359/272
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: G02F 1/1506 caused by electrodeposition, e.g. electrolytic deposition of an inorganic material on or close to an electrode

Abstract

An electrochromic device (10) of reversible light-transmissivity comprises a pair of spaced-apart window plate members (11, 13) bearing electrically-conductive surface layers (12, 14) and containing an electrochromotropic electrolyte solution in the intervening space (16). The electrolyte comprises an aqueous inorganic solution of a silver salt and may further comprise a salt of a transition metal. The electrolyte solutions are responsive to varying applied voltages by transitioning between solution phases of varying light-transmissivity which, depending upon solution composition, may be persistent or passively reversible.

Claims

1. A reversible electrochromic device comprising a pair of spaced-apart electrode members, at least one of which is significantly light-transmissive, and a body of electrochromotropic electrolyte contained therebetween, said electrolyte body being responsive with differing degrees of light transmissivity upon the application of differing levels of electrical voltage across said electrode members characterized in that

said electrolyte comprises an aqueous inorganic solution of a composition of silver salt capable of responding to application of each of at least two different voltages by reversibly transitioning between respective solution phases exhibiting different degrees of light transmissivity.

2. An electrochromic device according to claim 1 wherein said electrolyte comprises an ammoniacal solution of silver nitrate.

3. An electrochromic device according to claim 1 wherein said electrolyte comprises an acidic solution of silver nitrate and at least one transition metal salt.

4. An electrochromic device according to claim 3 wherein said transition metal salt is selected from the group consisting of cobalt and nickel.

5. An electrochromic device according to claim 3 wherein said transition metal salt is selected from the group consisting of nitrates of cobalt and nickel.

6. An electrochromic device according to claim 3 wherein said silver nitrate and said at least one transition metal salt are in a molar ratio of about 1:

1 to 10;

1.