Superabsorbent polymers having anti-caking characteristics

• US 6,124,391 A
• Filed: 08/18/1998
• Issued: 09/26/2000
• Est. Priority Date: 08/18/1998
• Status: Expired due to Term

• Current Assignee: Evonik Degussa GmbH (Rag-Stiftung)
• Original Assignee: Stockhausen GmbH & Company Kg (Rag-Stiftung)
• Inventors: Jones, Heather S., Kaiser, Thomas A., Molen, Ronald L., Deaton, Peter A., Hsu, Whei-Neen, Sun, Fang, Messner, Bernfried A.
• Primary Examiner(s): SANDERS, KRIELLION ANTIONETTE
• Application Number:
  US09/135,844
• Time in Patent Office: 770 Days
• Field of Search: 524/447, 523/223
• US Class Current: 524/447
• CPC Class Codes: A61L 15/18 containing inorganic materials
• CPC Class Codes: A61L 15/60 Liquid-swellable gel-forming materials, e.g. super-absorbents
• CPC Class Codes: C08J 2300/14 Water soluble or water swellable polymers, e.g. aqueous gels
• CPC Class Codes: C08J 3/212 and solid additives
• CPC Class Codes: C08L 101/14 the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels

Abstract

A particulate material composition of superabsorbent polymer particles, wherein less than about 60% by weight of the superabsorbent polymer particles will pass through a U.S. Standard 50 mesh sieve. The composition has anti-caking properties and also reduced dusting. The composition can be produced by mixing the superabsorbent polymer particles with an inorganic powder, such as clay.

Claims

1. A particulate material composition comprising an inorganic powder intermixed with particles of superabsorbent polymer, said polymer particles being of such size that less than about 60% of said polymer particles, by weight, will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings, and wherein the composition exhibits anti-caking characteristics in that more than about 90% of the composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 3 hours at about 36±

3°

C. and about 77±

3% relative humidity.

2. The composition of claim 1, wherein less than about 50% of said polymer particles by weight will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings.

3. The composition of claim 2, wherein less than about 40% of said polymer particles by weight will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings.

4. The composition of claim 1, wherein said inorganic powder is selected from the group consisting of clays.

5. The composition of claim 4, wherein said clay is a kaolin clay.

6. The composition of claim 1, wherein said inorganic powder comprises inorganic powder particles of less than about 5 micrometers in average size.

7. The composition of claim 6, wherein said inorganic powder particles are of less than about 3 micrometers in average size.

8. The composition of claim 7, wherein said inorganic powder particles are of less than about 0.8 micrometer in average size.

9. The composition of claim 1, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.2% to about 10% by weight of said polymer particles.

10. The composition of claim 9, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.5% to about 7% by weight of said polymer particles.

11. The composition of claim 10, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.9% to about 5.5% by weight of said polymer particles.

12. The composition of claim 1, wherein said polymer is selected from the group consisting of hydrolyzed starch-acrylonitrile graft copolymers, starch-acrylic acid graft copolymers, saponified vinyl acetate-acrylic ester copolymers, hydrolyzed acrylonitrile copolymers, hydrolyzed acrylamide copolymers, acrylamido-methylpropane-sulfonic acid terpolymers, acrylic acid polymers, methacrylic acid polymers, network cross-linked products of any of the foregoing, and combinations thereof.

13. The composition of claim 1, wherein at least a portion of said polymer particles is surface cross-linked.

14. The composition of claim 1, wherein the composition exhibits anti-caking characteristics in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 6 hours at about 36±

3°

C. and about 77±

3% relative humidity.

15. The composition of claim 14, wherein the composition exhibits anti-caking characteristics in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 15 hours at about 36±

3°

C. and about 77±

3% relative humidity.

16. The composition of claim 15, wherein the composition exhibits anti-caking characteristics in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 24 hours at about 36±

3°

C. and about 77±

3% relative humidity.

17. The composition of claim 1, wherein the composition exhibits dust reduction characteristics.

18. An absorbent article comprising a particulate material composition of an inorganic powder intermixed with particles of superabsorbent polymer, said polymer particles being of such size that less than about 60% of said polymer particles, by weight, will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings, and wherein the particulate material composition, prior to incorporation into the article, exhibits anti-caking characteristics in that more than about 90% of the composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 3 hours at about 36±

3°

C. and about 77±

3% relative humidity.

19. The absorbent article of claim 18, wherein less than about 50% of said polymer particles by weight, will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings.

20. The absorbent article of claim 19, wherein less than about 40% of said polymer particles, by weight, will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings.

21. The absorbent article of claim 18, wherein said inorganic powder is selected from the group consisting of clays.

22. The absorbent article of claim 21, wherein said clay is a kaolin clay.

23. The absorbent article of claim 18, wherein said inorganic powder comprises inorganic powder particles of less than about 5 micrometers in average size.

24. The absorbent article of claim 23, wherein said inorganic powder particles are of less than about 3 micrometers in average size.

25. The absorbent article of claim 24, wherein said inorganic powder particles are of less than about 0.8 micrometer in average size.

26. The absorbent article of claim 18, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.2% to about 10% by weight of said polymer particles.

27. The absorbent article of claim 26, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.5% to about 7% by weight of said polymer particles.

28. The absorbent article of claim 18, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.9% to about 5.5% by weight of said polymer particles.

29. The absorbent article of claim 18, wherein said polymer is selected from the group consisting of hydrolyzed starch-acrylonitrile graft copolymers, starch-acrylic acid graft copolymers, saponified vinyl acetate-acrylic ester copolymers, hydrolyzed acrylonitrile copolymers, hydrolyzed acrylamide copolymers, acrylamido-methylpropane-sulfonic acid terpolymers, acrylic acid polymers, methacrylic acid polymers, network cross-linked products of any of the foregoing, and combinations thereof.

30. The absorbent article of claim 18, wherein at least a portion of said polymer particles is surface cross-linked.

31. The absorbent article of claim 18, wherein the particulate material composition, prior to incorporation into the article, exhibits anti-caking characteristics in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 6 hours at about 36±

3°

C. and about 77±

3% relative humidity.

32. The absorbent article of claim 31, wherein the particulate material composition, prior to incorporation into the article, exhibits anti-caking characteristics in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 15 hours at about 36±

3°

C. and about 77±

3% relative humidity.

33. The absorbent article of claim 32, wherein the particulate material composition, prior to incorporation into the article, exhibits anti-caking characteristics in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 24 hours at about 36±

3°

C. and about 77±

3% relative humidity.

34. The absorbent article of claim 18, wherein the particulate material composition, prior to incorporation into the article, exhibits dust reduction characteristics.

35. A method for providing anti-caking characteristics to particles of superabsorbent polymer, said method comprising:

(A) providing superabsorbent polymer particles of such size that less than about 60% of the polymer particles, by weight, will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings;

(B) mixing an inorganic powder with the polymer particles in an amount of between about 0.2% to about 10% by weight of the polymer particles, to create a particulate material composition; and

(C) achieving anti-caking characteristics in that more than about 90% of the composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 3 hours at about 36±

3°

C. and about 77±

3% relative humidity.

36. The method of claim 35, wherein less than about 50% of said polymer particles by weight will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings.

37. The method of claim 36, wherein less than about 40% of said polymer particles by weight will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings.

38. The method of claim 35, wherein said inorganic powder is selected from the group consisting of clays.

39. The method of claim 38, wherein said clay is a kaolin clay.

40. The method of claim 35, wherein said inorganic powder comprises inorganic powder particles of less than about 5 micrometers in average size.

41. The method of claim 40, wherein said inorganic powder particles are of less than about 3 micrometers in average size.

42. The method of claim 41, wherein said inorganic powder particles are of less than about 0.8 micrometer in average size.

43. The method of claim 35, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.5% to about 7% by weight of said polymer particles.

44. The method of claim 43, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.9% to about 5.5% by weight of said polymer particles.

45. The method of claim 35, wherein anti-caking characteristics are achieved in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 6 hours at about 36±

3°

C. and about 77±

3% relative humidity.

46. The method of claim 45, wherein anti-caking characteristics are achieved in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 15 hours at about 36±

3°

C. and about 77±

3% relative humidity.

47. The method of claim 46, wherein anti-caking characteristics are achieved in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 24 hours at about 36±

3°

C. and about 77±

3% relative humidity.

48. The method of claim 35, wherein the polymer is selected from the group consisting of hydrolyzed starch-acrylonitrile graft copolymers, starch-acrylic acid graft copolymers, saponified vinyl acetate-acrylic ester copolymers, hydrolyzed acrylonitrile copolymers, hydrolyzed acrylamide copolymers, acrylamido-methylpropane-sulfonic acid terpolymers, acrylic acid polymers, methacrylic acid polymers, network cross-linked products of any of the foregoing, and combinations thereof.

49. The method of claim 35, wherein at least a portion of said polymer particles is surface cross-linked.

50. The method of claim 35, further including achieving dust reduction characteristics for the composition particles.

51. A method for providing anti-caking characteristics to a particulate material composition in an absorbent article, said method comprising:

(A) providing superabsorbent polymer particles of such size that less than about 60% of the polymer particles, by weight, will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings;

(B) mixing an inorganic powder with the polymer particles in an amount of between about 0.2% to about 10% by weight of the polymer particles, to create the particulate material composition;

(C) achieving anti-caking characteristics in that more than about 90% of the composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 3 hours at about 36±

3°

C. and about 77±

3% relative humidity; and

(D) forming an absorbent article from the particulate material composition of step (C).

52. The method of claim 51, wherein less than about 50% of said polymer particles, by weight, will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings.

53. The method of claim 52, wherein less than about 40% of the polymer particles, by weight, will pass through a U.S. Standard 50 mesh sieve with 300 micrometer openings.

54. The method of claim 52, wherein the inorganic powder is selected from the group consisting of clays.

55. The method of claim 54, wherein said clay is a kaolin clay.

56. The method of claim 51, wherein said inorganic powder comprises inorganic powder particles of less than about 5 micrometers in average size.

57. The method of claim 56, wherein said inorganic powder particles are of less than about 3 micrometers in average size.

58. The method of claim 57, wherein said inorganic powder particles are of less than about 0.8 micrometer in average size.

59. The method of claim 51, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.5% to about 7% by weight of said polymer particles.

60. The composition of claim 59, wherein said inorganic powder is mixed with said polymer particles in an amount of between about 0.9% to about 5.5% by weight of said polymer particles.

61. The method of claim 51, wherein anti-caking characteristics are achieved in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 6 hours at about 36±

3°

C. and about 77±

3% relative humidity.

62. The method of claim 61, wherein anti-caking characteristics are achieved in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 15 hours at about 36±

3°

C. and about 77±

3% relative humidity.

63. The method of claim 62, wherein anti caking characteristics are achieved in that more than about 90% of said composition particles, by weight, will pass through a U.S. Standard 12 mesh sieve with 1700 micrometer openings after at least about 24 hours at about 36±

3°

C. and about 77±

3% relative humidity.

64. The method of claim 51, wherein the polymer is selected from the group consisting of hydrolyzed starch-acrylonitrile graft copolymers, starch-acrylic acid graft copolymers, saponified vinyl acetate-acrylic ester copolymers, hydrolyzed acrylonitrile copolymers, hydrolyzed acrylamide copolymers, acrylamido-methylpropane-sulfonic acid terpolymers, acrylic acid polymers, methacrylic acid polymers, network cross-linked products of any of the foregoing, and combinations thereof.

65. The method of claim 51, wherein at least a portion of said polymer particles is surface cross-linked.

66. The method of claim 51, wherein step (D) includes forming the absorbent article by mixing the particulate material composition with a fibrous component.

67. The method of claim 51, further including achieving dust reduction characteristics for the composition particles.