Catalytic air cathode for air-metal batteries

• US 6,127,061 A
• Filed: 01/26/1999
• Issued: 10/03/2000
• Est. Priority Date: 01/26/1999
• Status: Expired due to Fees

• Current Assignee: High-Density Energy Incorporated
• Original Assignee: High-Density Energy Incorporated
• Inventors: Lou, Chou-Lui, Shun, You-Keung
• Primary Examiner(s): Bell, Bruce F.
• Application Number:
  US09/238,008
• Time in Patent Office: 616 Days
• Field of Search: 429/42, 429/40, 429/44, 429/27, 429/12, 429/59, 429/133, 429/162, 429/163, 429/164, 429/165, 204/282, 204/283, 204/290 R
• US Class Current: 429/406
• CPC Class Codes: H01M 10/4214 Arrangements for moving electrodes or electrolyte
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 2004/8689 Positive electrodes
• CPC Class Codes: H01M 4/96 Carbon-based electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An air cathode for use in an electrochemical cell or battery having an air permeable and water impermeable layer, an electrically conductive middle layer and a catalytic layer comprising a mixture of carbon particles, particulate materials, having a high surface area, metal hydroxides, and hydrophobic particles.

Claims

1. A cathode for use in an electrochemical cell comprising:

an air permeable and water-impermeable portion;

a catalytic portion comprising a mixture of carbon particles, particulate material having a high surface area, a metal hydroxide, and hydrophobic particles; and

an electrically conductive structure located between said air permeable and water impermeable portion and said catalytic portion, said electrically conductive structure defining sufficient passages to allow air to flow therethrough.

2. The cathode of claim 1 wherein said air permeable and water impermeable portion is a mixture of carbon particles and hydrophobic particles.

3. The cathode of claim 2 wherein said hydrophobic particles are polymers selected from the group consisting of PTFE (polytetrafluoroethylene), polyethylene, polypropylene, and polystyrene.

4. The cathode of claim 2 wherein said carbon particles are selected from the group of carbon fibers and graphite.

5. The cathode of claim 2 wherein said mixture of carbon particles and hydrophobic particles is between about 50:

1 and about 3;

1.

6. The cathode of claim 5 wherein said mixture ratio is between about 9:

1 and 6;

1.

7. The cathode of claim 5 wherein said carbon particles are graphite particles and the hydrophobic particles are PTFE bonded together with epoxy.

8. The cathode of claim 1 wherein said particulate material having a high surface area is selected from the group consisting of activated carbon, molecular sieves, and zeolite.

9. The cathode of claim 1 wherein said metal hydroxides are selected from the group consisting essentially of nickel hydroxide, cobalt hydroxide, iron hydroxide, cerium hydroxide, manganese hydroxide, lanthanum hydroxide, and chromium hydroxide.

10. The cathode of claim 1 wherein said electric conductive structure is a honeycomb structure made from a conductive metal.

11. The cathode of claim 1 wherein said electrically conductive structure is a mesh made from a conductive metal.

12. The cathode of claim 1 wherein said air permeable, water permeable portion is a layer bonded to one side of said electrically conductive structure and said catalytic portion is a layer bonded to the other side of said electrically conductive structure.

13. A metal-air battery comprising:

a cathode comprising an air permeable and water impermeable portion, a catalytic layer comprising a mixture of carbon particles, particulate material having a high surface area, a metal hydroxide and hydrophobic particles, and an electrically conductive structure located between said air permeable and water permeable portion and said catalytic portion, said electrically conductive structure defining sufficient passages to allow air or oxygen to flow therethrough;

a metal anode;

an electrolyte in contact with said cathode and said anode; and

a liquid impervious case to support said cathode, said anode and said electrolyte.

14. The metal-air battery of claim 13 wherein said air permeable and water impermeable portion of said air cathode is mixture of carbon particles and hydrophobic particles.

15. The metal-air battery of claim 14 wherein said mixture of carbon particles and hydrophobic particles is between about 50:

1 and about 3;

1.

16. The metal-air battery of claim 15 wherein said mixture ratio is between about 9:

1 and about 6;

1.

17. The cathode of claim 15 wherein said carbon particles are graphite particles and said hydrophobic particles are PTFE particles bonded together with epoxy.

18. The metal air battery of claim 13 wherein said electrolyte is about 25% to about 50% potassium hydroxide solution.

19. The metal air battery of claim 13 wherein said anode is a metal selected from the group consisting of zinc, iron, cadmium, copper, and aluminum.

20. The metal-air battery of claim 13 wherein said anode is made of zinc.

21. The metal air battery of claim 13 wherein said hydrophobic particles are polymers selected from the group consisting of PTFE (polytetrafluoroethylene), polyethylene, polypropylene, and polystyrene.

22. The metal air battery of claim 13 wherein said carbon particles are selected from the group of carbon fibers and graphite.

23. The metal air battery of claim 13 wherein said particulate material having a high surface area is selected from the group consisting of activated carbon, molecular sieves, and zeolite.

24. The metal air battery of claim 13 wherein said metal hydroxides are selected from the group consisting of nickel hydroxide, cobalt hydroxide, iron hydroxide, cerium hydroxide, manganese hydroxide, lanthanum hydroxide, and chromium hydroxide.

25. The metal air battery of claim 13 wherein said electrically conductive structure is mesh made from a conductive metal.

26. The metal air battery of claim 13 wherein said electric conductive structure is a honeycomb structure made from conductive metal.

27. The metal-air battery of claim 13 and further comprising an inert auxiliary electrode positioned within said case so as to be in contact with said electrolyte, said auxiliary electrode serving as the cathode for recharging said battery.

28. The metal air battery of claim 27 wherein said auxiliary electrode is made of carbon fibers.

29. The metal-air battery of claim 27 and further comprising a power source connected between said metal anode and said inert auxiliary electrode for recharging said metal-air battery.

30. The metal air battery of claim 27 and further comprising apparatus connected so as to move said metal anode to obtain even growth of metal on said anode during recharging.

31. The metal-air battery of claim 30 wherein said apparatus is a motor connected to rotate said anode.

32. The metal-air battery of claim 30 wherein said anode is a metal selected from the group consisting of zinc, iron, cadmium, copper, and aluminum.

33. The metal-air battery of claim 30 wherein said anode is zinc.

34. An electrochemical cell for providing electrical power comprising:

a metal anode;

a cathode structure comprising an air permeable and water impermeable portion, a catalytic portion comprising a mixture of carbon particles, particulate material having a high surface area, a metal hydroxide, and hydrophobic particles, said cathode structure oriented such that the catalytic portion faces said metal anode, and an electrically conductive structure defining sufficient passages to allow air to flow therethrough; and

an electrolyte in contact with said cathode and said anode.

35. The electrochemical cell of claim 34 wherein said cathode structure is a substantially spherical structure enclosing said metal anode.

36. The electrochemical cell of claim 35 wherein said plurality of cathodes completely surround said metal anode.

37. The electrochemical cell of claim 34 wherein said cathode structure is a plurality of cathodes facing said metal anode.

38. The electrochemical cell of claim 34 wherein said air permeable and water impermeable portion of said air cathode is mixture of carbon particles and hydrophobic particles.

39. The electrochemical cell of claim 38 wherein said mixture of carbon particles and hydrophobic particles is between about 50:

1 and about 3;

1.

40. The electrochemical cell of claim 39 wherein said mixture ratio is between about 9:

1 and about 6;

1.

41. The electrochemical cell of claim 39 wherein said carbon particles are graphite particles and said hydrophobic particles are PTFE particles bonded together with epoxy.

42. The electrochemical cell of claim 34 and further comprising an inert auxiliary electrode positioned so as to be in contact with said electrolyte, said auxiliary electrode serving as the cathode for recharging said cell.

43. The electrochemical cell of claim 42 wherein said auxiliary electrode is made of carbon fibers.

44. The electrochemical cell of claim 43 said electrochemical cell comprising a power source connected between said metal anode and said inert auxiliary electrode for recharging said metal-air battery.

45. The electrochemical cell of claim 44 wherein said apparatus is a motor connected to rotate said anode.

46. The electrochemical cell of claim 43 further comprising apparatus connected so as to move said metal anode to obtain even growth of metal on said anode during recharging.

47. The electrochemical cell of claim 46 wherein said anode is a metal selected from the group consisting of zinc, iron, cadmium, copper, and aluminum.

48. The electrochemical cell of claim 46 wherein said anode is zinc.

49. A cathode for use in an electrochemical cell comprising:

an air permeable and water-impermeable layer comprising a mixture of carbon particles and PTFE particles having a mixture ration of between about 9;

1 and 6;

1;

a conductive metal mesh bonded on one side to said air permeable layer; and

a catalytic layer bonded to the other side of said metal mesh comprising a mixture of about 5 parts graphite particles, about 2 parts of a particulate matter having a high surface area, about 4 parts of wet metal hydroxide, and about 0.2 parts of hydrophobic particles.

50. The cathode of claim 49 wherein said carbon particles are graphite particles.

51. The cathode of claim 49 wherein said carbon particles and said PTFE particles are bonded together with epoxy and the mixture ratio of carbon particles to PTFE particles is about 6:

1.

52. A metal-air battery comprising:

a cathode comprising an air permeable and water impermeable layer comprising a matrix of about 6 parts graphite particles and about 1 parts PTFE particles bonded together with epoxy, a conductive metal mesh bonded on one side to said air permeable, water impermeable layer and a catalytic layer bonded to the other side of said metal mesh comprising a mixture of about 5 parts graphite particles, about 2 parts of a particulate mater having a high surface area and about 4 parts of a wet metal hydroxide, and about 0.2 parts of PTFE particles;

a metal anode selected from the group consists of zinc, iron, cadmium, copper, and aluminum;

an electrolyte in contact with said cathode and said anode; and

a liquid impervious case to support said cathode, said anode and said electrolyte.

53. The metal air battery of claim 52 and further comprising an inert auxiliary electrode positioned within said case so as to be in contact with said electrolyte, said auxiliary electrode serving as the cathode for recharging said battery.

54. The metal-air battery of claim 53 wherein said auxiliary electrode is made of carbon fibers.

55. The metal-air battery of claim 53 and further comprising a power source connected between said metal anode and said inert auxiliary electrode for recharging said metal-air battery.

56. The metal-air battery of claim 53 and further comprising apparatus connected so as to move said metal anode to obtain even growth of metal on said anode during recharging.

57. The metal-air battery of claim 56 wherein said apparatus is a motor connected to rotate said anode.

58. The metal-air battery of claim 56 wherein said anode is a metal selected from the group consisting of zinc, iron, cadmium, copper, and aluminum.

59. The metal-air battery of claim 56 wherein said anode is zinc.