Electrochemical sensor for the detection of hydrogen chloride

• US 6,129,824 A
• Filed: 05/27/1999
• Issued: 10/10/2000
• Est. Priority Date: 07/02/1997
• Status: Expired due to Term

• Current Assignee: Mine Safety Appliances Co LLC (MSA Safety, Inc.)
• Original Assignee: Mine Safety Appliances Company (MSA Safety, Inc.)
• Inventors: Rollick, Kelly P., Dorisio Deininger, Debra J.
• Primary Examiner(s): TUNG, TA HSUNG
• Application Number:
  US09/320,932
• Time in Patent Office: 502 Days
• Field of Search: 204/412, 204/415, 204/431, 204/432, 205/778.5, 205/779, 205/779.5, 205/780
• US Class Current: 204/412
• CPC Class Codes: G01N 27/4045 for gases other than oxygen

Abstract

The present invention provides an electrochemical sensor for the detection of hydrogen chloride. In general, the electrochemical sensor comprises a housing having disposed therein a working electrode, a reference electrode and a counter electrode. The electrochemically active surface of the working electrode preferably comprises a gold film having a thickness of approximately 1000 to 3000 Å. Electrical connection is maintained between the working electrode and the counter electrode via an electrolyte present within the housing. The electrochemical gas sensor preferably further comprises circuitry for maintaining the working electrode at a potential in the range of approximately 1025 to approximately 1400 mV versus the normal hydrogen electrode. The present invention also provides a method of using such a sensor to detect hydrogen chloride.

Claims

1. An electrochemical sensor for the detection of hydrogen chloride, comprising:

a housing, the housing having disposed therein a working electrode, a reference electrode and a counter electrode, the electrochemically active surface of the working electrode comprising a gold film having a thickness in the range of approximately 1000 Å

to approximately 3000 Å

, the gold film of the working electrode having been exposed to an atmosphere containing hydrogen sulfide of a sufficient concentration for a sufficient length of time to decrease a sensitivity of the working electrode to hydrogen sulfide by at least approximately 50 percent, the electrochemical sensor further comprising an electrolyte present within the housing maintaining electrical connection between the working electrode and the counter electrode; and

circuitry maintaining the working electrode at a potential in the range of approximately 1025 mV to approximately 1400 mV versus the normal hydrogen electrode.

2. The electrochemical sensor of claim 1 wherein the circuitry maintains the working electrode at a potential in the range of approximately 1050 mV to approximately 1350 mV versus the normal hydrogen electrode.

3. The electrochemical sensor of claim 1 wherein the circuitry maintains the working electrode at a potential in the range of approximately 1100 mV to approximately 1200 mV versus the normal hydrogen electrode.

4. The electrochemical sensor of claim 1 wherein the thickness of the gold film is in the range of approximately 1900 Å

to approximately 2800 Å

.

5. The electrochemical sensor of claim 1 wherein the gold film is sputter coated over a porous membrane.

6. The electrochemical sensor of claim 1 wherein the electrochemically active surface of the counter electrode comprises platinum.

7. The electrochemical sensor of claim 1 wherein the electrochemically active surface of the reference electrode comprises platinum.

8. The electrochemical sensor of claim 1 wherein the electrochemically active surfaces of both the reference electrode and the counter electrode comprise platinum.

9. The electrochemical sensor of claim 1 wherein the electrolyte comprises sulfuric acid.

10. The electrochemical sensor of claim 1 wherein the sensitivity of the working electrode to hydrogen sulfide has been decreased by at least approximately 50 percent.

11. An electrochemical sensor for the detection of hydrogen chloride, comprising:

a housing, the housing having disposed therein a working electrode, a reference electrode and a counter electrode, the electrochemically active surface of the working electrode comprising a gold film having a thickness in the range of approximately 1000 Å

to approximately 3000 Å and

having been exposed to an atmosphere containing hydrogen sulfide of a sufficient concentration for a sufficient length of time to render it generally at least as sensitive to hydrogen chloride as to hydrogen sulfide, the electrochemical sensor further comprising an electrolyte present within the housing maintaining electrical connection between the working electrode and the counter electrode; and

circuitry maintaining the working electrode at a potential in the range of approximately 1025 mV to approximately 1400 mV versus the normal hydrogen electrode.

12. The electrochemical sensor of claim 11 wherein the circuitry maintains the working electrode at a potential in the range of approximately 1050 mV to approximately 1350 mV versus the normal hydrogen electrode.

13. The electrochemical sensor of claim 11 wherein the circuitry maintains the working electrode at a potential in the range of approximately 1100 mV to approximately 1200 mV versus the normal hydrogen electrode.

14. The electrochemical sensor of claim 11 wherein the thickness of the gold film is in the range of approximately 1900 Å

to approximately 2800 Å

.

15. The electrochemical sensor of claim 11 wherein the gold film is sputter coated over a porous membrane.

16. The electrochemical sensor of claim 11 wherein the electrochemically active surface of the counter electrode comprises platinum.

17. The electrochemical sensor of claim 11 wherein the electrochemically active surface of the reference electrode comprises platinum.

18. The electrochemical sensor of claim 11 wherein the electrochemically active surfaces of both the reference electrode and the counter electrode comprise platinum.

19. The electrochemical sensor of claim 11 wherein the electrolyte comprises sulfuric acid.