Textured, matte-finish, low adhesion coatings

• US 6,129,971 A
• Filed: 03/13/1998
• Issued: 10/10/2000
• Est. Priority Date: 05/06/1997
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Anderson, Scott D., Capecchi, John T., Brandt, Patricia J. A.
• Primary Examiner(s): Watkins, III, William P.
• Application Number:
  US09/039,103
• Time in Patent Office: 942 Days
• Field of Search: 428/141, 428/42.2, 428/42.3, 428/41.8, 428/352, 428/355 N, 428/913, 427/253, 427/257, 427/280, 427/372.2, 427/384
• US Class Current: 428/141
• CPC Class Codes: A61L 15/26 Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof A61L15/225 takes precedence
• CPC Class Codes: A61L 15/58 Adhesives
• CPC Class Codes: C08L 77/08 from polyamines and polymerised unsaturated fatty acids
• CPC Class Codes: C09J 2477/005 in the release coating
• CPC Class Codes: C09J 7/403 characterised by the structure of the release feature
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/1476 Release layer
• CPC Class Codes: Y10T 428/149 Sectional layer removable
• CPC Class Codes: Y10T 428/1495 Adhesive is on removable layer
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
• CPC Class Codes: Y10T 428/2839 with release or antistick coating
• CPC Class Codes: Y10T 428/2896 including nitrogen containing condensation polymer [e.g., polyurethane, polyisocyanate, etc.]

Abstract

An article comprising a substrate, and a textured, matte-finish, low adhesion backsize coating on one surface of the substrate, wherein the coating comprises polyvinyl carbamate having nitrogen-bonded hydrocarbon side chains which provide terminal alkyl groups more than five carbons in length.

Claims

1. An article comprising:

a) a substrate; and

b) a textured, matte-finish, low adhesion backsize coating on one surface of the substrate, wherein the coating comprises a phase-separated polyvinyl carbamate having nitrogen-bonded hydrocarbon side chains which provide terminal alkyl groups more than five carbons in length.

2. The article of claim 1 wherein the backsize coating has a 60°

gloss reading of no greater than about 40.

3. The article of claim 2 wherein the backsize coating has a 60°

gloss reading of no greater than about 30.

4. The article of claim 3 wherein the backsize coating has a 60°

gloss reading of about 5 to about 15.

5. The article of claim 1 wherein the backsize coating has a coefficient of friction that is less than that of the uncoated substrate.

6. The article of claim 5 wherein the substrate comprises polyurethane and the coefficient of friction of the backsize coating is no greater than about 0.4.

7. The article of claim 1 wherein the backsize coating has a surface roughness that is greater than that of the uncoated substrate.

8. The article of claim 1 wherein the polyvinyl carbamate comprises at least about 50 mole percent nitrogen-bonded hydrocarbon side chains.

9. The article of claim 1 wherein the alkyl groups are at least 14 carbons in length.

10. The article of claim 1 further comprising a pressure sensitive adhesive coated on an opposite surface of the substrate.

11. The article of claim 1 wherein the coating further comprises a release modifying material.

12. The article of claim 11 wherein the release modifying material is formed in the presence of the polyvinyl carbamate.

13. The article of claim 11 wherein the release modifying material is selected from the group of an organopolysiloxane urea, an organopolysiloxane diamine, a silicone resin, a silicone acrylate, and a fluoropolymer.

14. The article of claim 1 which is a wound dressing.

15. The article of claim 1 which is a target strip.

16. The article of claim 1 wherein the coating further comprises a durability enhancing polymer.

17. The article of claim 16 wherein the durability enhancing polymer is selected from the group of polyvinyl butyral, polyethyloxazoline, and combinations thereof.

18. An article comprising:

a) a substrate; and

b) a textured, matte-finish, low adhesion backsize coating on one surface of the substrate, wherein the coating is formed from a composition comprising polyvinyl carbamate having nitrogen-bonded hydrocarbon side chains which provide terminal alkyl groups more than five carbons in length;

wherein the gloss of the backsize coating is less than that of the uncoated substrate and less than that of the substrate coated with the same coating composition that is not textured; and

further wherein the coating is formed from a composition comprising a solvent system comprising at least one good solvent for the polyvinyl carbamate and at least one poor solvent for the polyvinyl carbamate in a ratio sufficient to cause precipitation of the polymer upon evaporation of the solvent system.

19. The article of claim 18 wherein the backsize coating has a 60°

gloss reading of no greater than about 40.

20. The article of claim 19 wherein the backsize coating has a coefficient of friction less than that of the uncoated substrate.

21. The article of claim 20 wherein the backsize coating has a surface roughness greater than that of the uncoated substrate.

22. The article of claim 18 further comprising a pressure sensitive adhesive coated on an opposite surface of the substrate.

23. The article of claim 18 wherein the backsize coating is formed from a composition further comprising a release modifying material.

24. The article of claim 23 wherein the release modifying material is selected from the group of an organopolysiloxane urea, an organopolysiloxane diamine, a silicone resin, a silicone acrylate, and a fluoropolymer.

25. The article of claim 18 which is a wound dressing.

26. The article of claim 18 which is a target strip on an object.

27. The article of claim 18 wherein the coating further comprises a durability enhancing polymer.

28. The article of claim 27 wherein the durability enhancing polymer is selected from the group of polyvinyl butyral, polyethyloxazoline, and combinations thereof.

29. A method of preparing an article comprising a substrate on which is coated a textured, matte-finish, low adhesion backsize coating on one surface of the substrate, the method comprising coating a composition comprising polyvinyl carbamate having nitrogen-bonded hydrocarbon side chains which provide terminal alkyl groups more than five carbons in length and a solvent system comprising at least one good solvent for the polyvinyl carbamate and at least one poor solvent for the polyvinyl carbamate in a ratio sufficient to cause precipitation of the polymer upon evaporation of the solvent system.

30. The method of claim 29 wherein the good solvent is an aromatic solvent, an alkane, or mixtures thereof.

31. The method of claim 29 wherein the poor solvent is an alcohol.

32. The method of claim 29 wherein the solvent system comprises an aromatic solvent, an alkane, and a lower alcohol.

33. The method of claim 32 wherein the solvent system comprises xylene, heptane, and 2-propanol.

34. The method of claim 33 wherein the 2-propanol is present in an amount of at least about 50 weight percent, based on the total weight of the solvent system.

35. The method of claim 29 wherein the composition further comprises a release modifying material.

36. The method of claim 35 wherein the release modifying material is selected from the group of an organopolysiloxane urea, an organopolysiloxane diamine, a silicone resin, a silicone acrylate, and a fluoropolymer.

37. The method of claim 36 wherein the release modifying material is formed in the presence of the polyvinyl carbamate.

38. The method of claim 29 wherein the coating further comprises a durability enhancing polymer.

39. The method of claim 38 wherein durability enhancing the polymer is selected from the group of polyvinyl butyral, polyethyloxazoline, and combinations thereof.

40. The method of claim 29 wherein the gloss and coefficient of friction of the backsize coating is less than that of the uncoated substrate and less than that of the substrate coated with the same coating composition that is not textured.

41. The method of claim 40 wherein the backsize coating has a 60°

gloss reading of no greater than about 40.

42. A method of preparing an article comprising a substrate on which is coated a textured, matte-finish, low adhesion backsize coating on one surface of the substrate, the method comprising coating a composition comprising a low adhesion backsize polymer and a solvent system comprising a mixture of solvents in a ratio sufficient to cause precipitation of the polymer upon evaporation of the solvent system.

43. An article comprising:

a) a substrate; and

b) a non-particle loaded, non-embossed, and non-mechanically roughened, textured, matte-finish, low adhesion backsize coating on one surface of the substrate, wherein the coating comprises polyvinyl carbamate having nitrogen-bonded hydrocarbon side chains which provide terminal alkyl groups more than five carbons in length.