Anti-reflection film and display device having the same

• US 6,129,980 A
• Filed: 07/13/1998
• Issued: 10/10/2000
• Est. Priority Date: 07/11/1997
• Status: Expired due to Term

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Tsukada, Yoshihisa, Yamanouchi, Junichi, Yasuda, Tomokazu
• Primary Examiner(s): Nakarani, D. S.
• Application Number:
  US09/114,139
• Time in Patent Office: 820 Days
• Field of Search: 428/327, 428/421, 428/447, 428/448, 428/451, 313/479, 349/137
• US Class Current: 428/327
• CPC Class Codes: G02B 1/111 using layers comprising organic materials
• CPC Class Codes: Y10T 428/254 Polymeric or resinous material
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/31667 Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product

Abstract

An anti-reflection film has a low refractive index layer and a high refractive index layer. The low refractive index layer is formed by coating a composition comprising (a) a hydrolysis product or a partial condensation product of an organosilane and (c) a vinyl resin. The organosilane is represented by the formula of R¹ Si(OR²)₃ in which R¹ is an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms, and R² is an alkyl group having 1 to 5 carbon atoms or an acyl group having 1 to 4 carbon atoms. The vinyl resin has at least one silyl group substituted with a hydrolyzable group or hydroxyl.

Claims

1. An anti-reflection film having a first layer and a second layer, wherein the first layer has a higher refractive index than the second layer, and wherein the second layer is formed by coating a composition comprising:

(a) a hydrolysis product or a partial condensation product of an organosilane represented by the formula of R¹ Si(OR²)₃ in which R¹ is an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms, and R² is an alkyl group having 1 to 5 carbon atoms or an acyl group having 1 to 4 carbon atoms; and

(b) a vinyl resin having at least one silyl group substituted with a hydrolyzable group or hydroxyl in an amount of 2 to 300 weight parts.

2. The anti-reflection film as defined in claim 1, wherein R¹ in the formula of R¹ Si(OR²)₃ is a fluorine-substituted alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkenyl group having 2 to 10 carbon atoms or a fluorine-substituted aryl group having 6 to 10 carbon atoms.

3. The anti-reflection film as defined in claim 1, wherein the vinyl resin contains a fluorine atom.

4. The anti-reflection film as defined in claim 1, wherein the composition further comprises (c) a hydrolysis product or a partial condensation product of a diorganosilane represented by the formula of R¹₂ Si(OR²)₂ in which R¹ is an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms, and R² is an alkyl group having 1 to 5 carbon atoms or an acyl group having 1 to 4 carbon atoms.

5. The anti-reflection film as defined in claim 4, wherein R¹ in the formula of R¹₂ Si(OR²)₂ is a fluorine-substituted alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkenyl group having 2 to 10 carbon atoms or a fluorine-substituted aryl group having 6 to 10 carbon atoms.

6. The anti-reflection film as defined in claim 1, wherein the composition further comprises (d) particles of a fluorine-containing polymer having a mean particle size of 5 to 200 nm.

7. The anti-reflection film as defined in claim 1, wherein the composition further comprises (e) at least one metal-chelate compound comprising a central metal which is selected from the group consisting of Zr, Ti or Al, an alcohol ligand represented by the formula of R³ OH in which R³ is an alkyl group having 1 to 6 carbon atoms and a diketone ligand represented by the formula of R⁴ COCH₂ COR⁵ in which R⁴ is an alkyl group having 1 to 6 carbon atoms, and R⁵ is an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 16 carbon atoms.

8. The anti-reflection film as defined in claim 7, wherein the composition further comprises (g) a β

-diketone or a β

-ketoester represented by the formula of R⁴ COCH₂ COR⁵ in which R⁴ is an alkyl group having 1 to 6 carbon atoms, R⁵ is an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 16 carbon atoms.

9. The anti-reflection film as defined in claim 1, wherein the composition further comprises (f) an organic solvent selected from the group consisting of an alcohol, an aromatic hydrocarbon, an ether, a ketone and an ester.

10. The anti-reflection film as defined in claim 1, wherein the composition comprises (a) the hydrolysis product or a partial condensation product of the organosilane in an amount of 100 weight parts in terms of the organosilane and (b) the vinyl resin in an amount of 2 to 300 weight parts.

11. The anti-reflection film as defined in claim 1, wherein the second layer comprises an organic silane polymer having a network structure formed by coating the composition.

12. The anti-reflection film as defined in claim 1, wherein the anti-reflection film further has a third layer, the first layer is arranged between the third layer and the second layer, the layers have such refractive indexes that the refractive index of the third layer is between the refractive index of the second layer and the refractive index of the first layer.

13. The anti-reflection film as defined in claim 12, wherein the third layer has a refractive index of from 1.5 to 1.7.

14. A display device having a display surface covered with the anti-reflection film defined in claim 1, wherein the first layer is arranged between the display surface and the second layer.

15. The anti-reflection film as defined in claim 1, wherein the first layer has a refractive index of greater than 1.70.

16. The anti-reflection film as defined in claim 15, wherein the second layer has a refractive index of at least 0.1 less than the first layer.

17. The anti-reflection film as defined in claim 1, wherein the second layer has a refractive index of at least 0.1 less than the first layer.