Catalyst for catalytic oxidation use

• US 6,133,184 A
• Filed: 10/02/1998
• Issued: 10/17/2000
• Est. Priority Date: 10/03/1997
• Status: Expired due to Term

• Current Assignee: Nippon Shokubai Company Limited
• Original Assignee: Nippon Shokubai Company Limited
• Inventors: Okuno, Masaaki, Kiyooka, Yasushi
• Primary Examiner(s): DENTZ, BERNARD I
• Application Number:
  US09/165,134
• Time in Patent Office: 746 Days
• Field of Search: 549/248, 549/239, 549/257, 558/309, 558/327, 502/63
• US Class Current: 502/63
• CPC Class Codes: B01J 23/22 Vanadium
• CPC Class Codes: B01J 23/28 Molybdenum
• CPC Class Codes: B01J 23/30 Tungsten
• CPC Class Codes: B01J 27/224 Silicon carbide

Abstract

A carrier containing silicon carbide, inorganic bonding component, and at least one oxide selected from the group consisting of a niobium oxide, an antimony oxide, and a tungsten oxide carries at least one oxide selected from the group consisting of a vanadium oxide and a molybdenum oxide as catalytically active component. An inexpensive catalyst for catalytic oxidation use can be thus offered that does not change its properties over a period of time, that boasts stable catalytic activity over a period of time, and that is suitable for, e.g., manufacture of an acid anhydride and a nitrile compound by conducting a catalytic gas-phase oxidation reaction (partial oxidation reaction) on a hydrocarbon.

Claims

1. A catalyst for catalytic oxidation use, comprising:

a carrier containing silicon carbide, an inorganic bonding component, and at least one oxide selected from the group consisting of a niobium oxide, an antimony oxide, and a tungsten oxide; and

at least one oxide selected from the group consisting of a vanadium oxide and a molybdenum oxide as catalytically active component carried by the carrier.

2. The catalyst for catalytic oxidation use as defined in claim 1,

wherein the inorganic bonding component is at least one inorganic material selected from the group consisting of silicon dioxide and mullite.

3. The catalyst for catalytic oxidation use as defined in claim 1,

wherein the carrier contains at least one 0.1 weight parts to 2 weight parts oxide selected from the group consisting of a niobium oxide, an antimony oxide, and a tungsten oxide, with the total amount of the silicon carbide and the inorganic bonding component taken to be 100 weight parts.

4. The catalyst for catalytic oxidation use as defined in claim 1,

wherein the carrier contains 70 weight percent to 95 weight percent silicon carbide, 20 weight percent to 3 weight percent silicon dioxide as inorganic bonding component, and 10 weight percent to 2 weight percent mullite as inorganic bonding component, with the total amount of the silicon carbide and the inorganic bonding component taken to be 100 weight percent.

5. The catalyst for catalytic oxidation use as defined in claim 1,

wherein the carrier contains a 0.5 weight percent or less alkaline metal and alkaline earth metal in total amount, and has a porosity of 16% to 35% and a specific surface area of not less than 0.02m² /g and not more than 0.3m² /g.

6. The catalyst for catalytic oxidation use as defined in claim 1, comprising:

vanadium pentoxide as the vanadium oxide as the catalytically active component;

anatase-type titanium dioxide; and

at least one element selected from the group consisting of alkali metal elements, rare earth elements, sulfur, phosphorus, antimony, niobium, and boron;

wherein the catalyst for catalytic oxidation use is used for manufacturing phthalic anhydride from o-xylene and/or naphthalene.

7. The catalyst for catalytic oxidation use as defined in claim 1, comprising:

vanadium pentoxide as the vanadium oxide and molybdenum trioxide as a molybdenum oxide as the catalytically active component;

phosphorus pentoxide; and

at least one element selected from the group consisting of alkali metal elements, alkaline earth metal elements, and thallium;

wherein the catalyst for catalytic oxidation use is used for manufacturing maleic anhydride from benzene.

8. The catalyst for catalytic oxidation use as defined in claim 1, comprising:

vanadium pentoxide as the vanadium oxide as the catalytically active component;

phosphorus;

molybdenum and/or tungsten;

at least one element selected from the group consisting of antimony, silver, boron, chromium, cerium, niobium, and sulfur;

at least one element selected from the group consisting of alkali metal elements, alkaline earth metal elements, and thallium; and

at least one oxide selected from the group consisting of a titanium oxide, a zirconium oxide, and a tin oxide,

wherein the catalyst for catalytic oxidation use is used for manufacturing pyromellitic anhydride from 1,2,4,5-tetralkyl benzene.

9. The catalyst for catalytic oxidation use as defined in claim 1, comprising:

vanadium pentoxide as the vanadium oxide, and at least one oxide selected from the group consisting of titanium dioxide, silicon dioxide, alumina, diatom earth, a double oxide containing titanium and silicon, a double oxide containing titanium and zirconium, and a triple oxide containing titanium, silicon, and zirconium as the catalytically active component; and

at least one element selected from the group consisting of molybdenum, tungsten, chromium, antimony, bismuth, phosphorus, niobium, iron, cobalt, nickel, manganese, and copper,

wherein the catalyst for catalytic oxidation use is used for manufacturing an aromatic nitrile or a heterocyclic nitrile from an alkyl-substituted aromatic hydrocarbon or an alkyl-substituted heterocyclic compound.

10. A method of manufacturing phthalic anhydride from o-xylene and/or naphthalene, comprising the step of using a catalyst for catalytic oxidation, the catalyst at least including:

a carrier containing silicon carbide, an inorganic bonding component, and at least one oxide selected from the group consisting of a niobium oxide, an antimony oxide, and a tungsten oxide; and

a component carried by the carrier, at least including;

at least one oxide selected from the group consisting of a vanadium pentoxide and a molybdenum oxide as the catalytically active component;

anatase-type titanium dioxide; and

at least one element selected from the group consisting of alkali metal elements, rare earth elements, sulfur, phosphorus, antimony, niobium, and boron.

11. A method of manufacturing maleic anhydride from benzene, comprising the step of using a catalyst for catalytic oxidation, the catalyst at least including:

a carrier containing silicon carbide, an inorganic bonding component, and at least one oxide selected from the group consisting of a niobium oxide, an antimony oxide, and a tungsten oxide; and

a component carried by the carrier, at least including;

at least one oxide selected form the group consisting of a vanadium pentoxide and a molybdenum trioxide as the catalytically active component carried by the carrier;

phosphorus pentoxide; and

at least one element selected from the group consisting of alkali metal elements, alkaline earth metal elements, and thallium.

12. A method of manufacturing pyromellitic anhydride from 1,2,4,5-tetralkyl benzene comprising the step of using a catalyst for catalytic oxidation, the catalyst at least including:

a carrier containing silicon carbide, an inorganic bonding component, and at least one oxide selected from the group consisting of a niobium oxide, an antimony oxide, and a tungsten oxide; and

a component carried by the carrier, at least including;

at least one oxide selected from the group consisting of a vanadium pentoxide and a molybdenum oxide as the catalytically active component carried by the carrier;

phosphorus;

molybdenum and/or tungsten;

at least one element selected form the group consisting of antimony, silver, boron, chromium, cerium, niobium, and sulfur;

at least one element selected from the group consisting of alkali metal elements, alkaline earth metal elements, and thallium; and

at least one oxide selected from the group consisting of a titanium oxide, a zirconium oxide, and a tin oxide.

13. A method of manufacturing an aromatic nitrite or a heterocyclic nitrite from an alkyl-substituted aromatic hydrocarbon or an alkyl-substituted heterocyclic compound by ammoxidation, comprising the step of using a catalyst for catalytic oxidation to manufacture an aromatic nitrile or a heterocyclic nitrile from an alkyl-substituted aromatic hydrocarbon or an alkyl-substituted heterocyclic compound, the catalyst at least including:

a carrier containing silicon carbide, an inorganic bonding component, and at least one oxide selected from the group consisting of a niobium oxide, an antimony oxide, and a tungsten oxide; and

a component carried by the carrier, at least including;

at least one oxide selected from the group consisting of vanadium pentoxide, and at least one oxide selected from the group consisting of titanium dioxide, silicon dioxide, alumina, diatom earth, a double oxide containing titanium and silicon and a double oxide containing titanium and zirconium, and a triple oxide containing titanium, silicon, and zirconium, as the catalytically active component; and

at least one element selected from the group consisting of molybdenum, tungsten, chromium, antimony, bismuth, phosphorus, niobium, iron, cobalt, nickel, manganese, and copper.