Absorbent resin composition and method for production thereof

• US 6,133,193 A
• Filed: 07/23/1997
• Issued: 10/17/2000
• Est. Priority Date: 10/26/1994
• Status: Expired due to Term

• Current Assignee: Nippon Shokubai Company Limited
• Original Assignee: Nippon Shokubai Company Limited
• Inventors: Kajikawa, Katsuhiro, Nakamura, Masatoshi, Hatsuda, Takumi
• Primary Examiner(s): Wu, David W.
• Assistant Examiner(s): HARLAN, ROBERT D
• Application Number:
  US08/836,088
• Time in Patent Office: 1,182 Days
• Field of Search: 528/272, 528/274, 528/486, 502/402, 526/240, 526/317.1, 526/318.1, 428/402
• US Class Current: 502/402
• CPC Class Codes: B29B 2009/125 Micropellets, microgranules, microparticles
• CPC Class Codes: B29B 2009/166 Deforming granules to give a special form, e.g. spheroidizing, rounding
• CPC Class Codes: B29B 9/06 in the form of filamentary material, e.g. combined with extrusion
• CPC Class Codes: B29B 9/12 characterised by structure or composition
• CPC Class Codes: B29B 9/16 Auxiliary treatment of granules
• CPC Class Codes: B29K 2995/0092 hydrophilic
• CPC Class Codes: C08J 2300/14 Water soluble or water swellable polymers, e.g. aqueous gels
• CPC Class Codes: C08J 3/12 Powdering or granulating
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]

Abstract

An absorbent resin composition which shows high speed of absorption, excels in fluid permeability, and enjoys a high absorption capacity under load comprises primary particles of an absorbent resin and granulated particles of an absorbent resin having an average particle size smaller than the average particle size of the primary particles. An absorbent article contains the composition. The absorbent resin composition is produced by a method which comprises a step of producing granulated particles by granulating particles of absorbent resin having an average particle size in the range of 10 to 100 μm and a step of mixing the resultant granulated particles of the absorbent resin with the primary particles of an absorbent resin having an average particle size in the range of 150 to 800 μm. The granulated particles of an absorbent resin is produced by a method which comprises mixing the particles of absorbent resin with a granulating agent and extruding the resultant mixture through an extrusion granulating device provided with a spherical perforated plate.

Claims

1. An absorbent resin composition comprising primary particles of absorbent resin and granulated particles obtained by granulating an absorbent resin having an average particle size smaller than that of said primary particles by using at least one granulating agent selected from the group consisting of water, a polyhydric alcohol, an amino group-containing compound, an amide group-containing compound, and a carboxyl group-containing compound.

2. An absorbent resin composition according to claim 1, wherein said primary particles of absorbent resin have an average particle size in the range of 150 to 800 μ

m and said granulated particles of absorbent resin are obtained by granulating particles of absorbent resin having an average particle size in the range of 10 to 100 μ

mm.

3. An absorbent resin composition according to claim 1, wherein said primary particles of absorbent resin have an average particle size 2.5 to 10 times that of particles of absorbent resin from which said granulated particles of absorbent resin are obtained by granulation.

4. An absorbent resin composition according to any of claims 1 to 3, wherein said granulated particles of absorbent resin have an average particle size in the range of 150 to 800 μ

m.

5. An absorbent resin composition according to any of claims 1 to 4, wherein said granulated particles of absorbent resin have an average particle size larger than that of said primary particles of absorbent resin.

6. An absorbent resin composition according to any of claims 1 to 5, wherein said granulated particles of absorbent resin have an average particle size 1.1 to 5 times that of said primary particles of absorbent resin.

7. An absorbent resin composition according to any of claims 1 to 6, wherein the amount of said granulated particles of absorbent resin is in the range of 5 to 100 parts by weight based on 100 parts by weight of said primary particles of absorbent resin.

8. An absorbent resin composition according to any of claims 1 to 7, wherein said granulated particles of absorbent resin have an apparent gel expansion ratio of at least 10%.

9. An absorbent resin composition according to any of claims 1 to 8, wherein said granulated particles of absorbent resin are obtained by granulating particles of absorbent resin with a polycationic compound and/or a polyhydric alcohol.

10. An absorbent resin composition according to claim 1, wherein said granulated particles of absorbent resin have an aspect ratio (major size/minor size) of not less than 1.5.

11. An absorbent resin composition according to claim 1, wherein said granulated particles of absorbent resin are obtained by mixing particles of absorbent resin with a granulating agent and extruding the resultant mixture through an extrusion granulating device provided with a spherical perforated plate.

12. An absorbent resin composition according to claim 2, wherein said primary particles of absorbent resin have an average particle size 2.5 to 10 times that of particles of absorbent resin from which said granulated particles of absorbent resin are obtained by granulation.

13. An absorbent resin composition according to claim 4, wherein said granulated particles of absorbent resin have an average particle size larger than that of said primary particles of absorbent resin.

14. An absorbent resin composition according to claim 4, wherein said granulated particles of absorbent resin have an average particle size 1.1 to 5 times that of said primary particles of absorbent resin.

15. An absorbent resin composition according to claim 5, wherein said granulated particles of absorbent resin have an average particle size 1.1 to 5 times that of said primary particles of absorbent resin.

16. An absorbent resin composition according to claim 4, wherein the amount of said granulated particles of absorbent resin is in the range of 5 to 100 parts by weight based on 100 parts by weight of said primary particles of absorbent resin.

17. An absorbent resin composition according to claim 5, wherein the amount of said granulated particles of absorbent resin is in the range of 5 to 100 parts by weight based on 100 parts by weight of said primary particles of absorbent resin.

18. An absorbent resin composition according to claim 4, wherein said granulated particles of absorbent resin have an apparent gel expansion ration of at least 10%.

19. An absorbent resin composition according to claim 5, wherein said granulated particles of absorbent resin have an apparent gel expansion ration of at least 10%.

20. An absorbent resin composition according to claim 4, wherein said granulated particles of absorbent resin are obtained by granulating particles of absorbent resin with a polycationic compound and/or a polyhydric alcohol.

21. An absorbent resin composition according to claim 5, wherein said granulated particles of absorbent resin are obtained by granulating particles of absorbent resin with a polycationic compound and/or a polyhydric alcohol.

23. An absorbent resin composition according to claim 1, wherein said particles of absorbent resin to be used for the granulated particles of absorbent resin are obtained by classifying said primary particles of absorbent resin.

24. An absorbent resin composition according to claim 1, which is obtained by mixing said primary particles of absorbent resin and said granulated particles of absorbent resin.

22. An absorbent resin composition comprising primary particles of absorbent resin and granulated particles of absorbent resin, said granulated particles having been obtained by granulating particles of absorbent resin having an average particle size smaller than that of said primary particles, the amount of said granulated particles being in the range of 5 to 100 parts by weight based on 100 parts by weight of said primary particles of absorbent resin.