Flax shives reinforced thermoplastic resin composition

• US 6,133,348 A
• Filed: 08/02/1999
• Issued: 10/17/2000
• Est. Priority Date: 04/22/1998
• Status: Expired due to Fees

• Current Assignee: Cargill, Inc. (Agricultural Services Division)
• Original Assignee: Cargill, Inc. (Agricultural Services Division)
• Inventors: Kolla, Francis A., Balatinecz, John J.
• Primary Examiner(s): Szekely, Peter A.
• Application Number:
  US09/364,890
• Time in Patent Office: 442 Days
• Field of Search: 524/9, 524/35
• US Class Current: 524/9
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N

Abstract

The present invention is directed to flax shives reinforced thermoplastic compositions and a method for reinforcing thermoplastic resins. The present invention provides a use for flax shives, which is the portion left over after processing plant materials to separate plant fibers (bast fibers) from the shives.

Claims

1. A reinforced thermoplastic resin composition comprising:

a thermoplastic resin; and

from about 10 to about 80 weight percent flax shives, based on the weight of the composition, the flax shives having not more than about 30 weight % bast fibers, the bast fibers having a mean fiber length of less than about 2 mm, and the flax shives having a mean particle size of not more than about 10 mesh.

2. The composition of claim 1 wherein the reinforced thermoplastic resin composition has a tensile strength of at least about 3,000 psi, a tensile modulus of at least about 150×

10³ psi, a flexural strength of at least about 5,000 psi, and a flexural modulus of at least about 200×

10³ psi.

3. The composition of claim 1 wherein the thermoplastic resin has a melting point of at least about 140°

C., a density of not more than about 1.5g/cm³, and a weight average molecular weight in the range of from about 100,000 to about 800,000.

4. The composition of claim 3 wherein the thermoplastic resin is selected from the group consisting of polypropylene, polyethylene, polyvinyl chloride, styrene, acrylonitrile, acrylonitrile-styrene, acrylonitrile-butadiene-styrene, and mixtures thereof.

5. The composition of claim 1 wherein the composition further comprises a processing aid selected from the group consisting of maleated polypropylene, maleated polyethylene, functionalized polyolefins, and mixtures thereof.

6. A method for reinforcing a thermoplastic resin composition comprising:

blending from about 10 to about 80 weight percent flax shives, based on the weight of the composition, with a thermoplastic resin, the flax shives having not more than about 30 weight % bast fibers, the bast fibers having a mean fiber length of less than about 2 mm, the flax shives having a mean particle size of not more than about 10 mesh.

7. The method of claim 6 wherein the method is effective for providing a reinforced thermoplastic resin composition with a tensile strength of at least about 3,000 psi, a tensile modulus of at least about 150×

10³ psi, a flexural strength of at least about 5,000 psi, and a flexural modulus of at least about 200×

10³ psi.

8. The method of claim 6 wherein the blending of shives with thermoplastic resin is effective for melting the thermoplastic resin and completely dispersing the flax fiber in the resin.

9. The method of claim 6 wherein the thermoplastic resin has a melting point of at least about 140°

C., a density of not more than about 1.5 g/cm³, and a weight average molecular weight in the range of from about 100,000 to about 800,000.

10. The method of claim 6 wherein the thermoplastic resin is selected from the group consisting of polypropylene, polyethylene, polyvinyl chloride, styrene, acrylonitrile, acrylonitrile-styrene, acrylonitrile-butadiene-styrene, and mixtures thereof.

11. The method of claim 6 wherein a processing aid selected from the group consisting of maleated polypropylene, maleated polyethylenes, functionalized polyolefin and mixtures thereof, is added during blending.

12. A reinforced thermoplastic resin composition comprising:

a thermoplastic resin; and

from about 10 to about 80 weight percent flax shives, based on the weight of the composition, the flax shives having not more than about 10 weight % bast fibers, the bast fibers having a mean fiber length of less than about 2 mm, and the flax shives having a mean particle size of not more than about 10 mesh.

13. The composition of claim 12 wherein the reinforced thermoplastic resin has a tensile strength of at least about 3,000 psi, a tensile modulus of at least about 150×

10³ psi, a flexural strength of at least about 5,000 psi, and a flexural modulus of at least about 200×

10³ psi.

14. The composition of claim 12 wherein the thermoplastic resin has a melting point of at least about 140°

C., a density of not more than about 1.5g/cm³, and a weight average molecular weight in the range of from about 100,000 to about 800,000.

15. The composition of claim 14 wherein the thermoplastic resin is selected from the group consisting of polypropylene, polyethylene, polyvinyl chloride, styrene, acrylonitrile, acrylonitrile-styrene, acrylonitrile-butadiene-styrene, and mixtures thereof.

16. The composition of claim 12 wherein the composition further comprises a processing aid selected from the group consisting of maleated polypropylene, maleated polyethylene, a functionalized polyolefin, and mixtures thereof.

17. The composition of claim 12 wherein the flax shives include not more than about 5 weight percent bast fibers.

18. The composition of claim 12 wherein the flax shives have a mean particle size of from about 10 to about 100 mesh.

19. The composition of claim 17 wherein the flax shives have a mean particle size of from about 10 to about 100 mesh.