Fabrication of electrochromic device with plastic substrates

• US 6,136,161 A
• Filed: 11/12/1993
• Issued: 10/24/2000
• Est. Priority Date: 11/12/1993
• Status: Expired due to Term

• Current Assignee: PPG Industries Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Rukavina, Thomas G., Yu, Phillip C., Backfisch, David L., Slobodnik, John B.
• Primary Examiner(s): NGUYEN, NAM X
• Application Number:
  US08/152,338
• Time in Patent Office: 2,538 Days
• Field of Search: 204/192.15, 204/192.26, 204/192.29, 427/126.3, 427/162, 427/164, 427/165, 427/166
• US Class Current: 204/192.29
• CPC Class Codes: C23C 14/08 Oxides C23C14/10 takes precedence
• CPC Class Codes: C23C 14/083 of refractory metals or yttrium
• CPC Class Codes: C23C 14/5826 Treatment with charged particles C23C14/582 takes precedence
• CPC Class Codes: G02F 1/133305 Flexible substrates, e.g. plastics, organic film
• CPC Class Codes: G02F 1/15245 based on iridium oxide or hydroxide
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 2001/1502 complementary cell

Abstract

A method for fabricating an electrochromic device having organic polymer substrates is described. Each substrate has a surface coated with an organic polymer primer coating onto which is deposited an electroconductive metal oxide film. An electrochromic material is deposited on one electroconductive film and a complementary electrochromic material is deposited on the other electroconductive film. The resultant two substrates are aligned with the electrochromic materials facing one another. A preformed sheet of an ion-conducting polymer is disposed between those electrochromic layers and the resulting sandwich autoclaved.

Claims

1. A method for fabricating an electrochromic article comprising the steps of:

(a) depositing an organic polymer primer coating on a surface of each of two organic polymer substrates,

(b) depositing an electroconductive metal oxide film on each of the primer coatings deposited on said organic polymer substrates,

(c) depositing a film of an electrochromic material on one of the electroconductive metal oxide films deposited in step (b),

(d) depositing a film of a complementary electrochromic material on the other electroconductive metal oxide film deposited in step (b),

(e) assembling the organic polymer substrates of steps (c) and (d) in spaced relationship with the electrochromic and complementary electrochromic films in a facing relationship,

(f) disposing a preformed sheet of ion-conducting polymer between and in contact with the electrochromic and complementary electrochromic films, and

(g) applying heat and pressure to laminate said sheet to said electrochromic films.

2. The method of claim 1 wherein said electroconductive metal oxide film is selected from the group consisting of the oxides of tin, indium and mixtures thereof.

3. The method of claim 2 wherein the electroconductive metal oxide film is tin-doped indium oxide, the weight ratio of indium to tin being about 90:

10.

4. The method of claim 2 wherein the electroconductive metal oxide film has a thickness of from about 2000 to 4000 Angstroms.

5. The method of claim 1 wherein the electrochromic film is tungsten oxide.

6. The method of claim 5 wherein the tungsten oxide film has a thickness of from about 3000 to 5000 Angstroms.

7. The method of claim 1 wherein the primer is a polymer of acrylic acid and a substituted acrylate selected from the group consisting of hydroxyethylacrylate, cyanoethylacrylate and methylmethacrylate.

8. The method of claim 7 wherein the primer is a polymer of acrylic acid and methylmethacrylate wherein the mole ratio of acrylic acid and methylmethacrylate is from 3:

1 to 1;

3.

9. The method of claim 7 wherein the primer is a polymer of acrylic acid, cyanoethylacrylate and methylmethacrylate.

10. The method of claim 7 wherein the primer has a thickness of from about 0.01 to about 0.50 microns.

11. The method of claim 1 wherein the complementary electrochromic material is iridium oxide.

12. The method of claim 11 wherein the complementary electrochromic material has a thickness of from about 300 to about 800 Angstroms.

13. The method of claim 1 wherein the ion-conducting polymer is a copolymer of 2-acrylamido-2-methylpropane sulfonic acid and dimethylacrylamide.

14. The method of claim 1 wherein the ion-conducting polymer is a proton-conducting polymer.

15. The method of claim 1 wherein the assembled electrochromic article is placed in an autoclave bag and the bag evacuated before applying heat and pressure to laminate the sheet of ion-conducting polymer to the electrochromic films.

16. The method of claim 1 wherein the electroconductive metal oxide film is selected from the group consisting of the oxides of tin, indium and mixtures thereof, the electrochromic film is tungsten oxide;

the complementary electrochromic film is iridium oxide and the ion-conducting polymer is a proton-conducting polymer.

17. The method of claim 16 wherein the electroconductive metal oxide film has a thickness of from about 2000 to 4000 Angstroms;

the tungsten oxide film has a thickness of from about 3000 to 5000 Angstroms; and

the complementary electrochromic film has a thickness of from about 300 to 800 Angstroms.

18. The method of claim 16 wherein the primer is a polymer of acrylic acid and a substituted acrylate selected from the group consisting of hydroxyethylacrylate, cyanoethylacrylate and methylmethacrylate;

and has a thickness of from about 0.01 to 0.50 microns.

19. The method of claim 18 wherein the ion-conducting polymer is a copolymer of 2-acrylamido-2-methylpropane sulfonic acid and dimethylacrylamide.