System and method for photocatalytic treatment of contaminated media

• US 6,136,203 A
• Filed: 09/03/1998
• Issued: 10/24/2000
• Est. Priority Date: 09/10/1997
• Status: Expired due to Term

• Current Assignee: Purifics Environmental Technologies Incorporated
• Original Assignee: Purifics Environmental Technologies Incorporated
• Inventors: Butters, Brian E., Powell, Anthony Leonard
• Primary Examiner(s): Barry, Chester T.
• Application Number:
  US09/146,987
• Time in Patent Office: 782 Days
• Field of Search: 210/747, 210/748, 210/759, 210/763, 210/765, 210/743, 422/186.3, 204/157.15, 204/157.3
• US Class Current: 210/743
• CPC Class Codes: B01D 2255/802 Photocatalytic
• CPC Class Codes: B01D 53/14 by absorption
• CPC Class Codes: B01D 53/86 Catalytic processes
• CPC Class Codes: B01D 53/8668 Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
• CPC Class Codes: B09C 1/02 Extraction using liquids, e.g. washing, leaching , flotation
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/325 Irradiation devices or lamp constructions
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 2103/18 from the purification of gaseous effluents
• CPC Class Codes: C02F 2305/10 Photocatalysts

Abstract

A system for treating contaminated media is provided. In the process, contaminants are removed from the media using a photocatalytic process operating in an aqueous phase.

Claims

1. A system for treating contaminated media comprising:

a converter configured to transfer contaminants from contaminated media into a solvent, the converter comprising;

a first adsorbent system configured to operate in a first mode in which contaminants are removed from a gas and a second mode in which steam is the solvent that is used to remove contaminants from the first adsorbent system;

a second adsorbent system configured to operate in a first mode in which contaminants are removed from the gas and a second mode in which steam is the solvent that is used to remove contaminants from the second adsorbent system; and

wherein the first adsorbent system operates in the first mode when the second adsorbent system operates in the second mode, and the first adsorbent system operates in the second mode when the second adsorbent system operates in the first mode;

a photocatalytic system coupled to the converter, the photocatalytic system operable to cause the contaminants in the solvent to undergo a photocatalytic reaction; and

a condenser coupled to the first adsorbent system and the second adsorbent system, the condenser operable to condense the steam and any contaminants that are carried by the steam.

2. The system of claim 1 wherein the pH of the solvent may be regulated so that foulants may be substantially precluded from adhering to the surfaces of photocatalyst particles included in the photocatalytic system.

3. The system of claim 1 wherein the solvent is liquid water.

4. The system of claim 1 wherein the solvent is steam.

5. The system of claim 1 wherein the contaminated media is air.

6. The system of claim 1 wherein the contaminated media is a liquid.

7. The system of claim 1 wherein the contaminated media is a solid.

8. The system of claim 7 wherein the solid is soil.

9. The system of claim 1 wherein the converter and the photocatalytic system are contained within a single vessel.

10. The system of claim 1 wherein the converter is a gas scrubber system.

11. The system of claim 1 wherein the converter is an adsorbent system.

12. The system of claim 11 wherein the adsorbent system is an activated carbon bed system.

13. The system of claim 1 further comprising a third adsorbent system that is used to remove contaminants from a gas if all contaminants from the gas have not been removed by either the first adsorbent system or the second adsorbent system.

14. The system of claim 1 further comprising:

a condenser coupled to the first adsorbent system and the second adsorbent system, the condenser operable to condense the steam and any contaminants that are carried by the steam into a condensate; and

a contaminant removal system coupled to the condenser, the contaminant removal system operable to draw off contaminants that are not dissolved in the condensate.

15. The system of claim 14 wherein the contaminant removal system is a decanter.

16. The system of claim 1 wherein the converter further comprises:

a tank for holding the liquid media;

a gas injection system coupled to the tank, the gas injection system operable to inject gas into the tank;

a gas discharge coupled to the tank; and

a liquid circulation system coupled to the tank, the liquid circulation system operable to remove liquid bearing contaminants from the tank and transfer the liquid to the photocatalytic system, and to transfer processed liquid from the photocatalytic system to the tank.

17. The system of claim 16 wherein the liquid circulation system is further operable to inject the processed liquid into the tank through one or more nozzles so as to create an aerosol, and to remove liquid from a gravity collection point where the aerosol accumulates to form the liquid bearing contaminants.

18. The system of claim 1 wherein the photocatalytic system further comprises a photocatalytic slurry.

19. The system of claim 1 further comprising one or more additional converters coupled in series to the converter such that the contaminated gas flows in series through each converter in order to reduce the level of contaminants in the gas with each converter stage.

20. The system of claim 1 wherein the first adsorbent system and the second adsorbent system further comprise activated carbon.