Gas absorption

• US 6,139,605 A
• Filed: 08/10/1999
• Issued: 10/31/2000
• Est. Priority Date: 02/11/1997
• Status: Expired due to Fees

• Current Assignee: Johnson Matthey PLC
• Original Assignee: Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Inventors: Towler, Gavin Paul, Shethna, Hiren Krishnakant, Carnell, Peter John Herbert, Willis, Edwin Stephen
• Primary Examiner(s): SMITH, DUANE
• Application Number:
  US09/371,292
• Time in Patent Office: 448 Days
• Field of Search: 95/235, 95/236, 95/181, 95/183, 95/178, 95/179, 95/180, 95/186, 95/187, 95/191, 95/193, 95/194, 95/204, 95/207, 95/209, 95/163, 95/164, 95/167, 95/169
• US Class Current: 95/164
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1456 Removing acid components

Abstract

A double-loop process for the removal of specified gas or gases from a process gas by absorption with a liquid absorbent for said specified gas or gases wherein the process gas is contacted counter-currently in a first absorption stage with semi-lean absorbent liquid and then in a second absorption stage with lean absorbent liquid to give a sweet process gas and the absorbed gases are stripped from the laden absorbent liquid in a first stage giving a semi-lean absorbent liquid. Part of the semi-lean absorbent is recycled to the first absorption stage while the remainder is subjected to further stripping by counter-current contact with an auxiliary gas that has a concentration of the specified gas or gases that is lower than the concentration of the specified gas or gases in the process gas to give the lean absorbent liquid which is recycled to the second absorption stage. The auxiliary gas, which is especially a part stream of the sweet process gas, may be recycled, after use for stripping, to the process gas upstream of the first absorption stage. The process may be integrated with a glycol drying stage with regeneration of the wet glycol by stripping with the part stream of the sweet process gas before the latter is used for stripping the semi-lean absorbent liquid.

Claims

1. A double-loop process for the removal of at least one specified gas from a process gas comprising:

a) in a first absorption stage, contacting a stream of process gas counter-currently with a stream of an absorbent liquid that is capable of selectively absorbing the specified gas from the process gas whereby the specified is absorbed from said process gas to give a stream of partially sweetened process gas having a decreased concentration of said specified and a stream of loaded absorbent liquid;

b) in a second absorption stage, contacting said partially sweetened process gas counter-currently with a stream of lean absorbent liquid whereby a further amount of said specified gas is absorbed from the partially sweetened process gas to give a sweet process gas having a further decreased concentration of said specified gas and a stream of partially loaded absorbent liquid;

c) subjecting the loaded absorbent liquid stream from step a) to partial regeneration by counter-current contact of said loaded absorbent liquid with vapour obtained by vaporising absorbent liquid whereby the specified gas is stripped from said loaded absorbent liquid to give a semi-lean absorbent liquid stream;

d) using partially loaded absorbent liquid from step b) as part of the absorbent liquid stream employed in step a) and part of the semi-lean absorbent liquid from step c) as the rest of the absorbent liquid stream employed in step a);

e) subjecting the remainder of said semi-lean absorbent liquid stream from step c) to a further regeneration stage by counter-current contact of said part of the semi-lean absorbent liquid stream with an auxiliary gas stream that is part of the sweet process gas or is a gas used in the production of the process gas, said auxiliary gas having a concentration of the specified gas that is lower than the concentration of the specified gas in the process gas, thereby producing a stream of lean absorbent liquid and a gas stream containing the specified gas stripped from said semi-lean absorbent liquid; and

f) recycling lean absorbent liquid from step e) to step b).

2. A process according to claim 1 wherein the auxiliary gas is 0.01 to 5% of said sweet process gas.

3. A process according to claim 1 wherein 70 to 99% of the semi-lean absorbent liquid from the partial regeneration stage is used as absorbent liquid in the first absorption stage.

4. A process according to claim 1 wherein the auxiliary gas is recycled, after use in the further regeneration stage, to the process gas upstream of the first absorption stage.

5. A process according to claim 1 wherein the partial regeneration of the loaded absorbent liquid is effected by:

a) feeding the loaded absorbent liquid to the upper part of a stripping column wherein it is stripped by counter-current contact with vapour obtained by vaporising part of the absorbent liquid;

b) taking vapour containing the stripped gases from the top of the column and cooling it to condense liquid therefrom;

c) returning the condensed liquid to the upper part of the column to a location above the location of the feed of the loaded absorbent liquid to the column;

d) withdrawing liquid from the upper part of the column, from a location below the location of the return of condensed liquid but above the location of the feed of loaded absorbent liquid;

e) returning the withdrawn liquid to the lower end of the column at a location below the location of the feed of the loaded absorbent liquid; and

f) withdrawing semi-lean absorbent liquid from the lower end of the column.

6. A process according to claim 1 wherein the further regeneration of the semi-lean absorbent liquid is effected by:

a) feeding the semi-lean absorbent liquid to the upper part of a stripping column wherein it is stripped by counter-current contact with the auxiliary gas supplied to the lower part of the column;

b) taking a gas containing the stripped gases from the top of the column and cooling it to condense liquid therefrom;

c) returning the condensed liquid to the upper part of the column to a location above the location of the feed of the semi-lean absorbent liquid to the column;

d) withdrawing liquid from the upper part of the column, from a location below the location of the return of condensed liquid but above the location of the feed of semi-lean absorbent liquid;

e) returning the withdrawn liquid to the lower end of the column at a location below the location of the feed of the semi-lean absorbent liquid; and

f) withdrawing lean absorbent liquid from the lower end of the column.

7. A process according to claim 6 wherein the column is provided at its lower end with a reboiler to which liquid is fed from the column and the liquid withdrawn from the upper part of the column is returned to the lower end of the column to a location not below the location from which liquid is fed to the reboiler.

8. A process according to claim 1 wherein the further regeneration of the part of the semi-lean absorbent liquid with auxiliary gas is effected in a column provided with a reboiler, and heat required for said reboiler is provided by heat exchange with the remainder of the semi-lean absorbent liquid before the latter is recycled to the first absorption stage.

9. A process according to claim 1 wherein the absorption stages are effected at elevated pressure and part of the sweet process gas is reduced in pressure from the pressure of the absorption stage by passage through a throttle thereby effecting cooling of that part of the sweet process gas to give a stream of cooled sweet gas, said lean absorbent liquid is cooled by direct or indirect heat exchange with the stream of cooled sweet gas before said lean absorbent liquid is returned to the second absorption stage, and said stream of cooled sweet gas is used as the auxiliary gas.

10. A process according to claim 1 wherein the sweet process gas is dried by counter-current contact with a dry glycol stream thereby giving a stream of dry sweet process gas and a stream of wet glycol, the stream of wet glycol is stripped with a part stream of sweet process gas thereby giving a stream of regenerated glycol which is recycled as said dry glycol stream, and, after use for stripping the wet glycol, the part stream of sweet process gas is used as the auxiliary gas.

11. A process according to claim 1 wherein the auxiliary gas is a part stream of the sweet process gas and the sweet process gas is passed through one or more beds of a particulate adsorbent capable of removing impurities in said sweet process gas before or after taking the part stream used as the auxiliary gas.

12. A process according to claim 1 wherein the further regeneration of the semi-lean absorbent liquid is effected at a pressure substantially equal to the pressure of the process gas and part of the auxiliary gas containing the gas stripped from the semi-lean absorbent liquid is recycled, together with fresh auxiliary gas, to the further regeneration stage while the remainder of the auxiliary gas containing the gas stripped from the semi-lean absorbent liquid is recycled to the process gas stream upstream of the first absorption stage, and, before said recycle to the further regeneration stage, said part of the auxiliary gas containing the gas stripped from the semi-lean absorbent liquid is passed through a bed of adsorbent particles effective to adsorb at least some of the gas stripped from the semi-lean absorbent liquid.

13. A process according to claim 1 wherein hydrogen sulphide is absorbed from the process gas by the absorbent liquid and, after use for stripping the semi-lean absorbent liquid, at least part of the gas containing hydrogen sulphide stripped from the semi-lean absorbent liquid is scrubbed with an alkaline aqueous hypochlorite solution to scrub hydrogen sulphide from said gas, and said hypochlorite solution containing hydrogen sulphide scrubbed from said gas is passed through a bed of a particulate catalyst effective to decompose said hypochlorite and to oxidise said hydrogen sulphide and then recycled to said scrubbing step.

14. A process according to claim 13 wherein the scrubbed gas, together with a fresh quantity of auxiliary gas, is used for stripping the semi-lean absorbent liquid.

15. A process according to claim 13 wherein the auxiliary gas is sweet process gas and the scrubbed gas is compressed and added to the remainder of the sweet process gas and the compressed scrubbed gas, or the sweet process gas after addition of the scrubbed gas, is passed through a bed of particles of an adsorbent material effective to adsorb chloride from the gas.