Low temperature integrated via and trench fill process and apparatus

• US 6,139,697 A
• Filed: 01/31/1997
• Issued: 10/31/2000
• Est. Priority Date: 01/31/1997
• Status: Expired due to Fees

• Current Assignee: Applied Materials Incorporated
• Original Assignee: Applied Materials Incorporated
• Inventors: Chen, Liang-Yuh, Guo, Ted, Mosely, Roderick Craig, Tao, Rong, Chen, Fusen
• Primary Examiner(s): Nguyen, Nam
• Assistant Examiner(s): VerSteeg, Steven H.
• Application Number:
  US08/792,292
• Time in Patent Office: 1,369 Days
• Field of Search: 204/192.12, 204/192.15, 204/192.17, 204/192.22, 204/192.23, 204/192.25, 427/250, 427/252, 427/566, 427/584
• US Class Current: 204/192.15
• CPC Class Codes: H01L 21/2855 by physical means, e.g. sputtering, evaporation H01L21/28518 - H01L21/28537 and H01L21/28568 take precedence
• CPC Class Codes: H01L 21/28556 by chemical means, e.g. CVD, LPCVD, PECVD, laser CVD H01L21/28518 - H01L21/28537 and H01L21/28568 take precedence
• CPC Class Codes: H01L 21/76877 Filling of holes, grooves or trenches, e.g. vias, with conductive material

Abstract

The present invention relates generally to an improved process for providing complete via fill on a substrate and planarization of metal layers to form continuous, void-free contacts or vias in sub-half micron applications. In one aspect of the invention, a refractory layer is deposited onto a substrate having high aspect ratio contacts or vias formed thereon. A CVD metal layer, such as CVD Al or CVD Cu, is then deposited onto the refractory layer at low temperatures to provide a conformal wetting layer for a PVD Cu. Next, a PVD Cu is deposited onto the previously formed CVD Cu layer at a temperature below that of the melting point temperature of the metal. The resulting CVD/PVD Cu layer is substantially void-free. The metallization process is preferably carried out in an integrated processing system that includes both a PVD and CVD processing chamber so that once the substrate is introduced into a vacuum environment, the metallization of the vias and contacts occurs without the formation of an oxide layer over the CVD Cu layer. The via fill process of the present invention is also successful with air-exposure between the CVD Cu and PVD Cu steps.

Claims

1. A method of forming a feature on a substrate, comprising:

a) depositing a barrier layer over the surfaces of an aperture, the barrier layer having a thickness of between about 5 and about 700 Angstroms;

b) chemical vapor depositing copper over the surface of the barrier layer without capping the aperture, the chemical vapor deposited copper having a thickness of between about 200 Angstroms and about 1 micron;

c) physical vapor depositing copper over the chemical vapor deposited copper at a temperature below about 660°

C. so that the physical vapor deposited copper and chemical vapor deposited copper substantially fill the aperture.

2. The method of claim 1, wherein the barrier layer has a thickness of between about 100 and about 200 Angstroms.

3. The method of claim 1, wherein the physical vapor deposition comprises the physical vapor deposition of copper at a temperature below about 400°

C.

4. The method of claim 1, further comprising performing the method sequentially in an integrated processing system with a common vacuum mainframe.

5. The method of claim 1, further comprising performing the method in separate chambers.

6. The method of claim 1, wherein the barrier layer is selected from the group consisting essentially of tungsten (W), niobium (Nb), aluminum silicates, tantalum (Ta), tantalum nitride (TaN), titanium nitride (TiN), physical vapor deposition Ti/N₂ -stuffed, TiSiN, WSiN, or a combination thereof.

7. The method of claim 1, further comprising:

(d) exposing the substrate to oxygen between chemical vapor depositing the copper and physical vapor depositing the copper.

8. The method of claim 1, wherein the physical vapor deposited copper includes a dopant therein, the method further comprising annealing the physical vapor deposited copper at a temperature of between about 250°

C. and about 450°

C.

9. The method of claim 1, wherein physical vapor depositing comprises sputtering.

10. A process for filling an aperture on a substrate, comprising:

a) forming a thin first layer over the surfaces of an aperture;

b) forming a thin conformal chemical vapor deposited copper layer over the first layer without substantially capping the aperture; and

c) forming a physical vapor deposited copper layer over the chemical vapor deposited copper layer, wherein the physical vapor deposited copper is deposited at a temperature less than about 660°

C.

11. The process of claim 10 wherein the first layer is deposited using a physical vapor deposition process.

12. The process of claim 10 wherein the first layer has a thickness less than about 2000 Angstroms.

13. The process of claim 10 wherein the first layer comprises tantalum.

14. The process of claim 10 wherein the first layer is selected from the group consisting essentially of tungsten (W), niobium (Nb), aluminum silicates, tantalum (Ta), tantalum nitride (TaN), titanium nitride (TiN), physical vapor deposition Ti/N₂ -stuffed, TiSiN, WSiN, or a combination thereof.

15. The process of claim 10 wherein the physical vapor deposited copper layer is deposited at a temperature less than about 400°

C.

16. The process of claim 10 wherein the chemical vapor deposited copper layer is deposited at a temperature below about 400°

C.

17. The process of claim 10 wherein the chemical vapor deposited copper and physical vapor deposited copper layers intermix to form an intermixed copper layer.

18. The process of claim 10, wherein forming the physical vapor deposited copper layer comprises sputtering the copper layer.