Multilayer film having a continuous and disperse phase

• US 6,141,149 A
• Filed: 01/19/2000
• Issued: 10/31/2000
• Est. Priority Date: 02/29/1996
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Weber, Michael F., Ouderkirk, Andrew J., Nevitt, Timothy J., Stover, Carl A., Allen, Richard C., Majumdar, Biswaroop, Carlson, Lockwood W., Kotz, Arthur L.
• Primary Examiner(s): Spyrou, Cassandra
• Assistant Examiner(s): Juba, Jr., John
• Application Number:
  US09/487,074
• Time in Patent Office: 286 Days
• Field of Search: 359/494, 359/500, 359/483, 359/485, 359/490, 359/491, 359/492, 359/495, 359/900
• US Class Current: 359/489.13
• CPC Class Codes: G02B 5/3008 comprising dielectric particles, e.g. birefringent crystals embedded in a matrix
• CPC Class Codes: G02B 5/305 including organic materials, e.g. polymeric layers
• CPC Class Codes: Y10S 359/90 Methods

Abstract

An optical film is provided which comprises a disperse phase of polymeric particles disposed within a continuous birefringent matrix. The film is oriented, typically by stretching, in one or more directions. The size and shape of the disperse phase particles, the volume fraction of the disperse phase, the film thickness, and the amount of orientation are chosen to attain a desired degree of diffuse reflection and total transmission of electromagnetic radiation of a desired wavelength in the resulting film.

Claims

1. A method for making a polarizer, comprising the steps of:

creating a blend of first and second diverse thermoplastic polymers, wherein said first thermoplastic polymer is present as a continuous phase and is capable of undergoing strain-induced birefringence, and wherein said second thermoplastic polymer is present as a disperse phase; and

orienting the blend in at least one direction such that the first thermoplastic polymer develops a birefringence of at least about 0.05.

2. The method of claim 1, wherein the blend is oriented such that it has a diffuse reflectivity of at least 30% over essentially all wavelengths of visible light.

3. The method of claim 1, wherein the blend is stretched to a stretch ratio of at least about 2.

4. The method of claim 1, wherein the blend is stretched to a stretch ratio of at least about 4.

5. The method of claim 1, wherein the blend is stretched to a stretch ratio of at least about 6.

6. The method of claim 1, wherein the blend is stretched in a first direction to a stretch ratio k, wherein the blend is stretched in a second direction to a stretch ratio m, and wherein k>

m.

7. The method of claim 1, wherein the blend is stretched in a first in-plane direction to a stretch ratio of at least 2, and wherein the film is unconstrained in a second in-plane direction.

8. The method of claim 7, wherein the second in-plane direction is orthogonal to the first in-plane direction.

9. A method for making a polarizer, comprising the steps of:

creating a blend of first and second diverse thermoplastic polymers, wherein the first thermoplastic polymer is present as a continuous phase and is capable of undergoing strain-induced birefringence, and wherein the second thermoplastic polymer is present in the blend as a disperse phase which is essentially randomly distributed throughout the continuous phase;

extruding the blend into a film; and

stretching the film in at least one direction such that the first thermoplastic polymer develops a birefringence of at least about 0.05.

10. The method of claim 9, wherein the first thermoplastic polymer is a polyester.

11. The method of claim 9, wherein both first and second thermoplastic polymers are polyesters.

12. The method of claim 9, wherein the film is oriented by stretching it in a first in-plane direction while leaving the film unconstrained in a second in-plane direction.

13. The method of claim 12, wherein said second in-plane direction is orthogonal to said first in-plane direction.

14. The method of claim 9, wherein the blend further comprises a compatibilizer.

15. The method of claim 9, wherein the continuous phase has a lower melting temperature than the disperse phase, and wherein the blend is created by embedding particles of the disperse phase within a molten matrix of the continuous phase at a temperature below the melting point of the disperse phase.

16. The method of claim 9, wherein the film is coextruded with at least one skin layer.

17. The method of claim 16, wherein the at least one skin layer contains a UV-blocking material.

18. The method of claim 9, wherein the film is asymmetrically and biaxially stretched.

19. The method of claim 9, wherein the blend contains a third diverse polymer which is present in the blend as a second disperse phase.

20. The method of claim 9, wherein the blend is extruded as a first layer in a film having an alternating layer sequence which has at least one other layer.