Burn rate-enhanced basic copper nitrate-containing gas generant compositions and methods

• US 6,143,102 A
• Filed: 05/06/1999
• Issued: 11/07/2000
• Est. Priority Date: 05/06/1999
• Status: Active Grant

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Original Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Inventors: Taylor, Robert D., Mendenhall, Ivan V., Parkinson, David W., Barnes, Michael W.
• Primary Examiner(s): Jordan, Charles T.
• Assistant Examiner(s): Baker, Aileen J.
• Application Number:
  US09/306,304
• Time in Patent Office: 551 Days
• Field of Search: 149/45, 149/61, 149/109.6
• US Class Current: 149/45
• CPC Class Codes: C06B 23/007 Ballistic modifiers, burning rate catalysts, burning rate depressing agents, e.g. for gas generating
• CPC Class Codes: C06B 41/00 Compositions containing a nitrated metallo-organic compound
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Basic copper nitrate-containing gas generant compositions and associated methods are provided for producing or resulting in increased burn rates via the inclusion of an effective amount of one or more metal (e.g., Al, Ti, Zn, Mg and/or Zr) oxide additives.

Claims

1. A gas generant composition having an increased burn rate, said composition comprising:

a fuel component,

a basic copper nitrate oxidizer component therefor, and

a burn rate enhancing amount of a metal oxide additive component selected from the group consisting of Al₂ O₃, TiO₂, ZnO, MgO and ZrO₂.

2. The gas generant composition of claim 1 wherein said metal oxide additive comprises ZnO.

3. The gas generant composition of claim 1 wherein said metal oxide additive comprises MgO.

4. The gas generant composition of claim 1 wherein said metal oxide additive comprises Al₂ O₃.

5. The gas generant composition of claim 1 wherein said metal oxide burn rate enhancing additive component is present in a relative amount of about 0.5 to about 5 composition weight percent.

6. The gas generant composition of claim 1 wherein said fuel component comprises guanidine nitrate.

7. The gas generant composition of claim 6 wherein said fuel component additionally comprises a copper complex material.

8. The gas generant composition of claim 7 wherein said copper complex material comprises a cupric nitrate ligand of the formula:

Cu(L)₂ (NO₃)₂ ;

where L is a ligand selected from the group consisting of ethylenediamine, biuret, ethanol amine and mixtures thereof.

9. The gas generant composition of claim 1 wherein said fuel component is present in a relative amount of about 30 to about 60 composition weight percent.

10. The gas generant composition of claim 1 wherein said basic copper nitrate oxidizer component is present in a relative amount of about 40 to about 65 composition weight percent.

11. The gas generant composition of claim 1 additionally comprising a silica slag formation additive in sufficient amount wherein upon ignition of the gas generant composition, the gas generant composition forms a more cohesive intact mass of solid combustion products as compared to a similar composition without the inclusion of said silica slag formation additive.

12. The gas generant composition of claim 11 wherein said silica slag formation additive is present in a relative amount of about 0.5 to about 5 composition weight percent.

13. A method for making a gas generant formulation having an increased burn rate, the gas generant formulation containing a fuel and a basic copper nitrate oxidizer, said method comprising:

including about 0.5 to about 5 weight percent of at least one metal oxide selected from the group consisting of Al₂ O₃, TiO₂, ZnO, MgO and ZrO₂ in the gas generant formulation.

14. The method of claim 13 wherein the metal oxide comprises ZnO.

15. The method of claim 13 wherein the metal oxide comprises MgO.

16. The method of claim 13 wherein the metal oxide comprises Al₂ O₃.

17. The method of claim 16 wherein Al₂ O₃ is included in a relative amount of about 2 to about 4 composition weight percent.

18. The method of claim 13 wherein the gas generant formulation also has improved slag formation characteristics, the method also comprising the step of:

including about 0.5 to about 5 composition weight percent of SiO₂ in the gas generant formulation.

19. An ignitable gas generant composition having enhanced burn rate and slag formation characteristics, said composition comprising:

about 30 to about 60 weight percent of a gas generating fuel component comprising guanidine nitrate,

about 40 to about 65 weight percent of a basic copper nitrate oxidizer,

a burn rate enhancing amount of a metal oxide selected from the group consisting of TiO₂, ZnO, MgO and ZrO₂ and

a slag formation enhancing amount of SiO₂.

20. The composition of claim 19 wherein:

the burn rate enhancing amount of the metal oxide is in the range of about 0.5 to about 5 weight percent of the composition and

the slag formation enhancing amount of SiO₂ is in the range of about 0.5 to about 5 weight percent of the composition.

21. The composition of claim 19 wherein the metal oxide is ZnO.

22. The composition of claim 19 wherein the metal oxide is MgO.

23. An ignitable gas generant composition having enhanced burn rate and slag formation characteristics, said composition comprising:

about 30 to about 60 weight percent of a gas generating fuel component comprising guanidine nitrate,

about 40 to about 65 weight percent of a basic copper nitrate oxidizer,

a burn rate enhancing amount of Al₂ O₃ and

a slag formation enhancing amount of SiO₂.

24. The composition of claim 23 wherein:

the burn rate enhancing amount of Al₂ O₃ is in the range of about 0.5 to about 5 weight percent of the composition and

the slag formation enhancing amount of SiO₂ is in the range of about 0.5 to about 5 weight percent of the composition.