Copolymers for rapid prototyping

• US 6,143,852 A
• Filed: 10/14/1999
• Issued: 11/07/2000
• Est. Priority Date: 10/23/1998
• Status: Expired due to Fees

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Podszun, Wolfgang, Harrison, David Bryan
• Primary Examiner(s): PEZZUTO, HELEN LEE
• Application Number:
  US09/418,298
• Time in Patent Office: 390 Days
• Field of Search: 526/319, 526/328, 526/328.5
• US Class Current: 526/328.5
• CPC Class Codes: B29C 41/003 characterised by the choice of material
• CPC Class Codes: C08F 220/14 Methyl esters , e.g. methyl (meth)acrylate

Abstract

This invention relates to spherical methyl methacrylate copolymers with an average particle size of 6 to 50 μm and a narrow particle size distribution, and to a method of producing them. The invention further relates to the use of these spherical copolymers for the production of 3-D models by laser sintering.

Claims

1. Spherical methyl methacrylate copolymers, the structural units of which includes

a) 90 to 50 percent of methyl methacrylate, and

b) 10 to 50 percent of at least one C_2-10 -alkyl methacrylate,

said percent, both occurrences, being relative to the weight of said copolymer, said copolymer being in the form of substantially spherical pellets having a volume average particle size of 6 to 50 microns, and a breadth of the particle size distribution of less than 2.0.

2. The spherical methyl methacrylate copolymers according to claim 1, wherein said a) is present in an amount of 90 to 60 percent and said b) is present in an amount of 10 to 40 percent.

3. The spherical methyl methacrylate copolymers according to claim 1, wherein said a) is present in an amount of 80 to 60 percent and said b) is present in an amount of 20 to 40 percent.

4. The spherical methyl methacrylate copolymers according to claim 1, wherein said breadth of the particle size distribution is less than 1.5.

5. A method of using the copolymer of claim 1 in producing a 3-D model comprising laser sintering.

6. The spherical methacrylate copolymer of claim 1 prepared by polymerizing by dispersion in a solvent and in the presence of an initiator a monomer mixture containing a) 90 to 50 percent of methyl methacrylate, and b) 10 to 50 percent of at least one C_2-10 -alkyl methacrylate, said percent, both occurrences being relative to the weight of said mixture.