System for recovering carbon dioxide from a lean feed

• US 6,146,603 A
• Filed: 06/10/1999
• Issued: 11/14/2000
• Est. Priority Date: 06/10/1999
• Status: Expired due to Term

• Current Assignee: Praxair Technology Incorporated (Linde Plc)
• Original Assignee: Praxair Technology Incorporated (Linde Plc)
• Inventors: Chakravarti, Shrikar, Gupta, Amitabh
• Primary Examiner(s): Dunn, Tom
• Assistant Examiner(s): DI MAURO, PETER T
• Application Number:
  US09/329,278
• Time in Patent Office: 523 Days
• Field of Search: 423/228, 423/229, 422/168, 96/202, 96/234
• US Class Current: 423/228
• CPC Class Codes: B01D 53/1418 Recovery of products
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A system for recovering absorbate such as carbon dioxide using an alkanolamine absorbent fluid, wherein the loaded absorbent is heated in a two step heating procedure prior to the separation of the absorbate from the absorbent, and wherein the loaded absorbent is deoxygenated after the first heating step and prior to the second heating step.

Claims

1. A method for recovering carbon dioxide from a lean feed comprising:

(A) providing a lean feed comprising oxygen and carbon dioxide in mass transfer contact with absorbent comprising at least one alkanolamine, and passing oxygen and carbon dioxide from the lean feed into the absorbent to obtain carbon dioxide loaded absorbent containing dissolved oxygen;

(B) heating the carbon dioxide loaded absorbent to obtain heated carbon dioxide loaded absorbent;

(C) removing at least some of the dissolved oxygen from the carbon dioxide loaded absorbent to obtain oxygen depleted carbon dioxide loaded absorbent; and

(D) further heating the oxygen depleted carbon dioxide loaded absorbent and thereafter recovering carbon dioxide from the absorbent.

2. The method of claim 1 wherein dissolved oxygen is removed from the carbon dioxide loaded absorbent by reducing the pressure of the carbon dioxide loaded absorbent and flashing off dissolved oxygen.

3. The method of claim 1 wherein dissolved oxygen is removed from the carbon dioxide loaded absorbent by stripping oxygen from the carbon dioxide loaded absorbent into oxygen scavenging gas.

4. Apparatus for recovering absorbate from an oxygen-containing feed comprising.

(A) an absorption column, means for passing a feed comprising oxygen and absorbate into the lower portion of the absorption column, and means for passing absorbent comprising at least one alkanolamine into the upper portion of the absorption column;

(B) a first heat exchanger, an oxygen separator, means for passing fluid from the lower portion of the absorption column to the first heat exchanger, and means for passing fluid from the first heat exchanger to the oxygen separator;

(C) a second heat exchanger and means for passing fluid from the oxygen separator to the second heat exchanger; and

(D) an absorbate recovery system, means for passing fluid from the second heat exchanger to the absorbate recovery system, and means for recovering absorbate from the absorbate recovery system.

5. The apparatus of claim 4 wherein the oxygen separator comprises a flash tank and a vacuum pump.

6. The apparatus of claim 4 wherein the oxygen separator comprises a stripping device.

7. A method for recovering absorbate from an oxygen-containing feed comprising:

(A) providing a feed comprising oxygen and absorbate in mass transfer contact with absorbent comprising at least one alkanolamine, and passing oxygen and absorbate from the feed into the absorbent to obtain absorbate loaded absorbent containing dissolved oxygen;

(B) heating the absorbate loaded absorbent to obtain heated absorbate loaded absorbent;

(C) removing at least some of the dissolved oxygen from the absorbate loaded absorbent to obtain oxygen depleted absorbate loaded absorbent; and

(D) further heating the oxygen depleted absorbate loaded absorbent and thereafter recovering absorbate from the absorbent.

8. The method of claim 7 wherein dissolved oxygen is removed from the absorbate loaded absorbent by reducing the pressure of the absorbate loaded absorbent and flashing off dissolved oxygen.

9. The method of claim 7 wherein dissolved oxygen is removed from the absorbate loaded absorbent by stripping oxygen from the absorbate loaded absorbent into oxygen scavenging gas.

10. The method of claim 7 wherein the absorbate comprises hydrogen sulfide.