Method of applying a powder coating to a length of a lignocellulosic material

• US 6,146,710 A
• Filed: 11/30/1998
• Issued: 11/14/2000
• Est. Priority Date: 05/29/1996
• Status: Expired due to Fees

• Current Assignee: Windsor Technologies Incorporated
• Original Assignee: Windsor Technologies Incorporated
• Inventors: Symons, Michael Windsor
• Primary Examiner(s): PARKER, FREDERICK JOHN
• Application Number:
  US09/194,401
• Time in Patent Office: 715 Days
• Field of Search: 427/470, 427/475, 427/485, 427/411, 427/412-2, 427/408, 427/493, 427/185
• US Class Current: 427/470
• CPC Class Codes: B05D 1/045 on non-conductive substrates
• CPC Class Codes: B05D 1/06 Applying particulate materials
• CPC Class Codes: B05D 1/24 Applying particulate materials
• CPC Class Codes: B05D 2401/32 applied as powders
• CPC Class Codes: B05D 3/005 Pretreatment for allowing a non-conductive substrate to be electrostatically coated
• CPC Class Codes: B05D 7/08 using synthetic lacquers or varnishes
• CPC Class Codes: B27K 3/15 Impregnating involving polymerisation including use of polymer-containing impregnating agents macromolecular compounds derived from lignocellulosic materials C08H; compositions of lignin-containing materials C08L97/02
• CPC Class Codes: D21H 17/08 Isocyanates
• CPC Class Codes: D21H 17/15 Polycarboxylic acids, e.g. maleic acid
• CPC Class Codes: D21H 19/24 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: D21H 19/28 Polyesters
• CPC Class Codes: D21H 23/30 Pretreatment of the paper D21H23/70, D21H23/76 take precedence
• CPC Class Codes: D21H 23/64 the material being non-fluent at the moment of transfer, e.g. in form of preformed, at least partially hardened coating

Abstract

A method of applying a powder coating to a length of a lignocellulosic material. The method comprises impregnating the length of lignocellulosic material with an impregnating composition (i) a dicarboxylic anhydride or a tricarboxylic anhydride dissolved in non-aqueous solvent; (ii) an isocyanate thermosetting resin dissolved in a non-aqueous solvent; or (iii) a combination of (i) or (ii). Any excess impregnating composition is then removed from the lignocellulosic material. Non-aqueous solvent is also removed and the impregnated lignocellulosic material is placed in either an electrostatic field or in a fluidized bed and a powder coating composition is applied thereto so that the powder coating composition adheres to the lignocellulosic material. The impregnated and coated lignocellulosic material is then subjected to elevated temperatures to polymerise and/or cross-link the resin and cure the powder coating composition to form a powder coating. The length of lignocellulosic material may be a sheet of paper, wood or wood veneer. A typical solvent is dichloromethane or liquid carbon dioxide.

Claims

1. A method of applying a powder coating to a length of a lignocellulosic material includes the steps of:

(a) impregnating the length of lignocellulosic material with an impregnating composition comprising either;

(i) a dicarboxylic anhydride or a tricarboxylic anhydride dissolved in a suitable non-aqueous solvent;

or

(ii) an isocyanate thermosetting resin dissolved in a suitable non-aqueous solvent;

or

(iii) a combination of a dicarboxylic anhydride eor a tricarboxylic anhydride and an isocyanate thermo-setting resin dissolved in a suitable non-aqueous solvent;

(b) if necessary removing from the impregnated length of lignocellullosic material any excess of the impregnating composition;

(c) removing the non-aqueous solvent;

(d) placing the impregnated length of lignocellulosic material in an electrostatic field or in a fluidized bed and applying a powder coating composition thereto so that the powder coating composition adheres thereto; and

(e) then subjecting the length of impregnated and coated lignocellulosic material to elevated temperatures to polymerise and/or cross-link the resin of step (a) in the length of lignocellulosic material and to cure the powder coating composition to form a powder coating.

2. A method according to claim 1 wherein the length of lignocellulosic material is selected from the group consisting of a sheet of paper, a length of peeled or sliced wood veneer, a length of laminated wood, and a length of chip board.

3. A method according to claim 1 or claim 2 wherein the impregnating composition comprises:

(iii) a combination of a dicarboxylic anhydride or a tricarboxylic anhydride and an isocyanate thermosetting resin dissolved in a suitable non-aqueous solvent.

4. A method according to claim 1 wherein the dicarboxylic anhydride is selected from the group consisting of maleic anhydride, phthalic anhydride, succinic anhydride and tetrahydrophthalic anhydride, and the tricarboxylic anhydride is trimellitic anhydride.

5. A method according to claim 1 wherein the suitable non-aqueous solvent for the anhydride and the suitable non-aqueous solvent for the isocyanate thermosetting resin art selected from the group consisting of methyl acetate, ethyl acetate, methylethyl ketone, benzene, trichloroethylene and dichloromethane.

6. A method according to claim 5 wherein the solvent is dichloromethane.

7. A method according to claim 1 wherein the suitable non-aqueous solvent for the anhydride and/or the suitable non-aqueous solvent for the isocyanate thermosetting resin is liquid carbon dioxide.

8. A method according to claim 1 wherein the impregnating composition contains from 0.25% to 30% inclusive of the anhydride by weight of the impregnating composition.

9. A method according to claim 1 wherein the impregnating composition contains the isocyanate thermosetting resin in an amount of 1.5% to 60% inclusive of the isocyanate thermosetting resin by weight of the impregnating composition.

10. A method according claim 1 wherein the powder coating composition is selected from the group consisting of polyurethanes, epoxy polyesters and polyesters.

11. A method according to claim 1 wherein in step (e) the length of lignocellulosic material is passed through a space heater in which the temperature of the length of lignocellulosic material is raised to a level above 140°

C.

12. A method according to claim 11 wherein the temperature of the length of lignocellulosic material is raised to a level above 185°

C.

13. A method according to claim 1 wherein in step (e) the length of lignocellulosic material is passed through a space heater in the presence of ultra-violet light.