Solvent-based pen inks

• US 6,149,721 A
• Filed: 02/03/1999
• Issued: 11/21/2000
• Est. Priority Date: 02/03/1999
• Status: Expired due to Term

• Current Assignee: Berol Corp (Newell Brands Inc.)
• Original Assignee: Gillette Company (The Procter & Gamble Company)
• Inventors: Wang, Yichun, Hopson, Russell E.
• Primary Examiner(s): KLEMANSKI, HELENE G
• Application Number:
  US09/244,538
• Time in Patent Office: 657 Days
• Field of Search: 106/31.32, 106/31.58
• US Class Current: 106/31.32
• CPC Class Codes: C09D 11/16 Writing inks
• CPC Class Codes: C09D 11/18 specially adapted for ball-point writing instruments

Abstract

Solvent-based pen inks are provided. The inks include an acid dye and a solvent system that includes an oxa acid solvent, the oxa acid solvent functioning as the primary solvent for the acid dye. Preferred inks are eradicable, and include an acid dye that decolorizes if contacted with a decolorizing compound.

Claims

1. An eradicable ink comprising an acid dye that decolorizes if contacted with a decolorizing compound, and a solvent system comprising an oxa acid solvent in a sufficient quantity to dissolve the acid dye.

2. The eradicable ink of claim 1 wherein said oxa acid is the primary solvent for the acid dye.

3. The ink of claim 1 wherein said oxa acid solvent is selected from the group consisting of oxa acid solvents having the following general formulas:

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4. The ink of claim 1 wherein said solvent system comprises a blend of oxa acid solvents.

5. The ink of claim 4 wherein said blend comprises a blend of a mono-acid and a di-acid.

6. The ink of claim 5 wherein said blend comprises a blend of a 3,6,9-trioxaundecanedioic acid with a 3,6,9-trioxaundecanonic acid.

7. The ink of claim 1 wherein said acid dye is a sulfonated dye salt.

8. The ink of claim 1 wherein said ink contains less than 25% of the acid dye.

9. The ink of claim 1 wherein said ink contains less than 20% of the acid dye.

10. The ink of claim 1 wherein the solvent system includes at least 40% of the oxa acid solvent.

11. The ink of claim 10 wherein the solvent system includes at least 50% of the oxa acid solvent.

12. The ink of claim 1 further comprsing a thickener.

13. The ink of claim 1 further comprising an elastomer.

14. The ink of claim 1 wherein said oxa acid has a terminal acetonic or proprionic end group.

15. A solvent based pen ink, comprising an acid dye and a solvent system that includes an oxa acid solvent in a sufficient quantity to dissolve the acid dye.

16. The ink of claim 15 wherein said acid dye is a direct dye.

17. The ink of claim 15 wherein said acid dye is a carboxylated or sulfonated salt.

18. An eradicator system comprising:

(a) an eradicable ink comprising an acid dye that decolorizes if contacted with a decolorizing compound, and a solvent comprising an oxa acid solvent; and

(b) an eradictor fluid comprising a compound selected to cause said acid dye to change color.

19. The eradicator system of claim 18 further comprising a write-over ink comprising a dye selected to allow said write-over ink to form a permanent marking over an area covered by said eradicator fluid.

20. The eradicator system of claim 18 wherein said write-over ink includes a solvent system that comprises an oxa acid solvent.

21. A method of changing the color of an ink mark, comprising

applying an ink to a substrate to provide an ink mark, said ink comprising a solvent system comprising an oxa acid solvent, and an acid dye that changes color if contacted with a chemical agent, dissolved in said solvent, and

applying said chemical agent to said ink mark to cause said acid dye to change color.