Shell-less hollow fiber membrane fluid contactor

• US 6,149,817 A
• Filed: 03/08/1999
• Issued: 11/21/2000
• Est. Priority Date: 03/08/1999
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: Celgard LLC (Asahi Kasei Corporation)
• Inventors: Peterson, Paul A., Wiesler, Frederick E., Runkle, Charles James, Sengupta, Amitava
• Primary Examiner(s): FORTUNA, ANA M
• Application Number:
  US09/265,064
• Time in Patent Office: 624 Days
• Field of Search: 210/650, 210/500.23, 210/321.78, 210/321.79, 210/321.8, 210/321.87, 210/321.88, 210/321.89, 210/644, 210/640
• US Class Current: 210/644
• CPC Class Codes: B01D 19/0031 by filtration
• CPC Class Codes: B01D 2313/10 Specific supply elements
• CPC Class Codes: B01D 53/22 by diffusion manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00
• CPC Class Codes: B01D 61/28 Apparatus therefor
• CPC Class Codes: B01D 63/02 Hollow fibre modules
• CPC Class Codes: B01D 63/043 with separate tube sheets

Abstract

A shell-less fluid contactor and a process for transferring a fluid component between a shell-side fluid and a lumen-side fluid. The shell-side fluid is introduced through a fluid distribution tube and discharged from the tube into contact with a surrounding bundle of microporous hollow fiber membranes. A fluid component is transferred by diffusion, through the walls of the hollow fiber membranes, from the shell-side fluid to the lumen-side fluid. Multiple contactors can be combined into an assembly for multi-stage processing of fluids.

Claims

1. A process for transferring a fluid component between a shell-side fluid and a lumen-side fluid, said process comprising:

(a) introducing a shell-side fluid into a fluid distribution element of a shell-less fluid contactor;

(b) introducing a lumen-side fluid into a lumen of at least one hollow fiber membrane external of the fluid distribution element; and

(c) discharging the shell-side fluid from the fluid distribution element into contact with the at least one hollow fiber membrane to effect diffusion of a fluid component between the shell-side fluid and the lumen-side fluid.

2. The process of claim 1, wherein the fluid distribution element comprises a fluid distribution tube having a plurality of openings extending generally radially outwardly from a hollow interior of the tube, and wherein a plurality of said hollow fiber membranes are provided to form a fiber bundle surrounding the plurality of openings of the fluid distribution tube, and wherein the step of discharging the shell-side fluid comprises discharging shell-side fluid from the plurality of openings of the fluid distribution tube into contact with the fiber bundle.

3. The process of claim 1, further comprising collecting shell-side fluid from the shell-less fluid contactor and transferring the collected shell-side fluid to a second fluid contactor for further processing.

4. The process of claim 1, wherein the fluid component is transferred from the shell-side fluid to the lumen-side fluid.

5. A shell-less fluid contactor comprising:

(a) a fluid distribution element comprising at least one inlet for receiving a shell-side fluid, and at least one outlet for discharging the shell-side fluid;

(b) at least one hollow fiber membrane being adapted for diffusion, said membrane having an internal surface defining a lumen and an external surface exposed to contact with the shell-side fluid, each said at least one hollow fiber membrane further comprising a first port in fluid communication with said lumen; and

(c) a barrier for separating the first port of each said at least one hollow fiber membrane from the shell-side fluid.

6. The fluid contactor of claim 5, wherein at least a portion of the external surface of each said at least one hollow fiber membrane extends adjacent the at least one outlet of said fluid distribution element.

7. The fluid contactor of claim 5, wherein said fluid distribution element comprises a tube having an open first end forming the at least one inlet, and a perforated wall section forming the at least one outlet.

8. The fluid contactor of claim 7, wherein said fluid distribution tube is substantially rigid.

9. The fluid contactor of claim 7, comprising a plurality of said hollow fiber membranes forming a fiber bundle, said fiber bundle surrounding at least a portion of the perforated wall section.

10. The fluid contactor of claim 9, wherein said barrier comprises a first tube sheet in sealing contact with the external surface of a first end of each hollow fiber membrane.

11. The fluid contactor of claim 10, wherein said first tube sheet is mounted in sealing engagement with the fluid distribution tube between the first end of the fluid distribution tube and the perforated wall section, and wherein a first end of each hollow fiber membrane extends through the first tube sheet in sealing engagement therewith, whereby the first port of each hollow fiber membrane is opposite the first tube sheet from the perforated wall section of the fluid distribution tube.

12. The fluid contactor of claim 11, further comprising a first end cap in sealing engagement with the first tube sheet to form a first chamber open to fluid communication with the first port of each hollow fiber membrane.

13. The fluid contactor of claim 12, comprising a second tube sheet mounted adjacent a second end of the fluid distribution tube in sealing contact with the external surface of a second end of each hollow fiber membrane, whereby a second port of each hollow fiber membrane is opposite the second tube sheet from the perforated wall section of the fluid distribution tube, said fluid contactor further comprising a second end cap in sealing engagement with the second tube sheet to form a second chamber open to fluid communication with a second port of each hollow fiber membrane.

14. The fluid contactor of claim 10, further comprising a second tube sheet in sealing contact with the external surface of a second end of each hollow fiber membrane.

15. The fluid contactor of claim 10, wherein second ends of each hollow fiber membrane opposite the first end are closed.

16. The fluid contactor of claim 15, further comprising a closure block mounted adjacent a second end of the fluid distribution tube, said closure block engaging and closing the second ends of each hollow fiber membrane.

17. The fluid contactor of claim 7, further comprising a bag filter within the fluid distribution tube.

18. An assembly for fluid processing, said assembly comprising:

(a) a first stage means comprising at least one shell-less fluid contactor being adapted for diffusion;

(b) a second stage means comprising at least one fluid contactor being adapted for diffusion; and

(c) collection and transfer means for collecting shell-side fluid discharged from one of the first stage or the second stage, and transferring the collected shell-side fluid to the other of the first or second stage.

19. The assembly of claim 18, wherein each said at least one shell-less fluid contactor of the first stage comprises:

(i) a fluid distribution tube having at least one inlet for receiving a shell-side fluid, and at least one outlet for discharging the shell-side fluid;

(ii) at least one hollow fiber membrane comprising a microporous wall, said microporous wall having an internal surface defining a lumen and an external surface exposed to contact with the shell-side fluid, each hollow fiber membrane further comprising a first port in fluid communication with said lumen; and

(iii) a barrier for separating the first port of each said at least one hollow fiber membrane from the shell-side fluid.

20. The assembly of claim 18, wherein said collection and transfer means comprises a portion of a conduit for an effluent process stream.