Ultraviolet-based, large-area scanning system for photothermal processing of composite structures

• US 6,149,856 A
• Filed: 11/13/1998
• Issued: 11/21/2000
• Est. Priority Date: 11/13/1998
• Status: Expired due to Fees

• Current Assignee: Anvik Corporation
• Original Assignee: Anvik Corporation
• Inventors: Zemel, Marc I., Dunn, Thomas J.
• Primary Examiner(s): Berman, Susan W.
• Application Number:
  US09/191,819
• Time in Patent Office: 739 Days
• Field of Search: 430/269, 430/270.1, 522/2, 522/1, 250/492.1, 250/493.1, 250/494.1, 250/495.1, 250/504 R, 250/505.1, 428/411.1, 425/174, 425/174.4, 264/401
• US Class Current: 264/401
• CPC Class Codes: B29C 2035/0827 using UV radiation
• CPC Class Codes: B29C 2037/903 by means of a computer
• CPC Class Codes: B29C 2791/001 Shaping in several steps
• CPC Class Codes: B29C 35/0227 using pressure vessels, e.g. autoclaves, vulcanising pans B29C35/065 takes precedence
• CPC Class Codes: B29C 35/0288 Controlling heating or curing of polymers during moulding, e.g. by measuring temperatures or properties of the polymer and regulating the process controlling or regulating chemical, physical or physico- chemical processes in general B01J19/0006
• CPC Class Codes: B29C 35/08 by wave energy or particle radiation B29C64/00, B29C71/04 take precedence
• CPC Class Codes: B29C 53/58 helically
• CPC Class Codes: B29K 2105/08 of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
• CPC Class Codes: B29K 2105/243 Partially cured
• CPC Class Codes: B29L 2023/22 Tubes or pipes, i.e. rigid bent tubes not for use as pipe couplings B29L2023/004
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]

Abstract

In making thermoset and photo-set polymer-matrix composite parts, curing is the key process step that transforms the molecular structure of the composite material, stabilizing it in the desired shape. This curing system applies carefully controlled ultraviolet (UV) radiation dosages, appropriately distributed over the entire surface of the composite part, thereby rapidly curing the material while enabling direct monitoring and control of the curing energy. Previous photo-curing methods have applied generalized radiation to a part with conventional UV lamps. We provide great benefits in cure depth, speed and process control by precisely controlling all parameters of UV dosage, by computed control, by markings on the part, or by dynamic feedback control from embedded sensors or non-contact sensors. This system can apply greater radiation dose to areas of increased quantities of resin, such as support ribs, and lesser radiation dose to areas of decreased quantities of resin. This method can be enhanced by using differing resins which respond to differing wavelengths, and also by controlled changes of radiation field size or duration. This curing system also enables temporary joining of parts by sufficient partial or controlled-area photo-setting, which may also be integrated with lay-up or winding operations. As a result, these partially cured parts can be handled safely through later stages of the manufacturing process, such as final photo-setting or baking operation in an oven or autoclave.

Claims

1. A system for curing a plastic three-dimensional solid composite part (110, 112) characterized by:

a) an illumination source module (101) which produces a high-powered radiation beam;

b) a beam processing module (103) arranged to accept the beam output of said illumination source module (101) and deliver as its output a set of one or more sub-beams, each sub-beam of said set having a pre-determined numerical aperture, having a homogenizer (105) arranged to accept said beam output and forward a shaped, uniformized beam, having condenser means (106) arranged to accept the shaped, uniformized sub-beam output of said homogenizer (105) and to reconfigure the sub-beam output into a set of at least one operational sub-beam of predetermined characteristics;

c) a translation stage subsystem (99) for presenting a pattern of photo-curing radiation to different segments of said composite part (110,

     112) for photocuring, and

d) control means (100) to control said translation stage subsystem to control said beam processing module, to provide a pattern selectively to each one of a plurality of individual segments of said composite part (110,

     112).

2. A system for curing a photo-curable composite part (110, 112), having a subsystem (99) for presenting different segments of said composite part (110, 112) for photocuring, characterized by:

a) an illumination source module (101) which produces a high-powered radiation beam;

b) a beam processing module (103) arranged to accept the beam output of said illumination source module (101) and deliver as its output a set of one or more sub-beams, each sub-beam of said set having a pre-determined numerical aperture, having a homogenizer (105) arranged to accept said beam output and forward a shaped, uniformized beam, having condenser means (106) arranged to accept the shaped, uniformized sub-beam output of said homogenizer (105) and to reconfigure the sub-beam output into a set of at least one operational sub-beam of predetermined characteristics;

c) a translation stage subsystem (99) for presenting a pattern of photocuring radiation to different segments of said composite part (110,

     112) for photocuring;

d) control means (100) to control said translation stage subsystem to control said beam processing module, to provide a pattern selectively to each one of a plurality of individual segments of said composite part (110,

     112); and

e) means (113) for completing a photo-setting reaction of said composite part (110,

     112).

3. A system according to claim 2, wherein said convection means (113) encompasses said beam processing module (103) and said composite part (110, 112), establishing an arrangement in which said convection means (113) provides a safety enclosure for said beam processing module (103) and said composite part (110, 112).

4. A system according to claim 2, wherein said convection means (113) encompasses said composite part (110, 112), establishing a safety enclosure for the output of said beam processing module (103) and said composite part (110, 112), and serves to partially cure said composite part (110, 112) so that final curing can be performed by said set of radiation sub-beams.

5. A system according to claim 2, wherein said convection means (113) encompasses said composite part (110, 112), establishing a safety enclosure for the output of said beam processing module (103) and said composite part (110, 112), allowing partial curing of said composite part (110, 112) by said set of radiation sub-beams, followed by final curing by said convection means (113).

6. A system according to claim 5, wherein said set of radiation sub-beams accomplishes selective curing of said composite part (110, 112) as a temporary stabilization measure.

7. A system according to claim 5, wherein said set of radiation sub-beams accomplishes selective curing of said composite part (110, 112) by providing incremental curing of areas requiring increased cure.

8. A system according to claim 2, wherein said control means (100) provides for variable UV doses at varying areas of said composite part (110, 112).

9. A system according to claim 2, wherein said control means (100) provides selective UV doses at varying areas of said composite part (110, 112), with optimal seamlessness as a result of overlapping polygonal scans.

10. A system according to claim 2, wherein said control means (100) provides for variable object field size to vary the UV dose at varying areas of said composite part (110, 112).

11. A system according to claim 2, wherein said control means (100) provides for variable repetition rate, variable pulse energy, or variable wavelength of the illumination source to vary the UV dose at varying areas of said composite part (110, 112).

12. A system according to claim 2, wherein said control means (100) provides for variable scanning speed of translation stage subsystem (99) to vary the UV dose at varying areas of said composite part (110, 112).

13. A system according to claim 2, wherein said control means (100) causes said beam processing module (103) to provide complementary overlapping polygonal scans of said composite part (110, 112).

14. A system according to claim 2, wherein said beam processing module (103) is equipped to split the beam output into plural sub-beams wherein each beam illuminates said composite part (110, 112) and wherein said control means (100) is arranged to provide appropriate dosages which are equalized.

15. A system according to claim 2, wherein said beam processing module (103) is equipped to split the beam output into plural sub-beams wherein each beam illuminates said composite part (110, 112) and wherein said control means (100) is arranged to provide appropriate dosages which are not equalized.

16. A system according to claim 2, wherein said beam-processing module (103) includes said homogenizer (105) and said condenser means (106), integrated with web supply means (117-S) to provide a set of operational sub-beams controlled for scanning a region of said composite part (110, 112) as it is being laid up by incrementation of web (117), to perform partial or complete curing for stabilization during lay-up of said composite part (110, 112).

17. A method of initiating photo-curing reactions in a composite part (110, 112), characterized by the following steps:

(step

     1) Allocating an illumination source module (101) having sufficient power to irradiate said composite part over a polygonal area;

(step

     2) Arranging a beam processing module (103) to accept the beam output of said illumination source module (101) and forward a set of one or more subbeams, each with the selected numerical aperture;

(step

     3) Arranging a homogenizer (105) to accept the sub-beam output of said beam processing module (103) and forward a set of shaped, uniformized sub-beams;

(step

     4) Arranging condenser means (106) to accept the sub-beam output of said homogenizer (105) and to reconfigure the sub-beam output into a set of one or more sub-beams of predetermined characteristics, which expose an increment of said composite part (110,

     112) to initiate selective photo-curing; and

(step

     5) Activating said illumination source module to initiate photo-curing reactions.

18. A method of initiating photo-curing reactions in a composite part according to claim 17, said composite part having an optimum dose profile, wherein the UV dose delivered by said set of sub-beams is computer-controlled to achieve a customized dose profile optimized for said composite part (110, 112).

19. A method of initiating photo-curing reactions in a composite part according to claim 17, said composite part having an optimum dose profile which may differ from location to location within said composite part, wherein the UV dose delivered by said set of sub-beams is computer-controlled in response to feedback from feedback sensors (115, 116) responding to the dynamic condition of said composite part (110, 112) to achieve a customized dose profile optimized for said composite part (110, 112).

20. A method of initiating photo-curing reactions in a part according to claim 19, wherein said feedback sensors (115, 116) respond to changes of measurable physical phenomena related to condition of cure.

21. A method of initiating photo-curing reactions in a composite part (110, 112) according to claim 17, wherein the UV dose delivered by said set of sub-beams is computer-controlled by varying the illumination source repetition rate or pulse energy to achieve a customized dose profile optimized for said composite part (110, 112).

22. A method of initiating photo-curing reactions in a composite part according to claim 17, wherein the UV dose delivered by said set of sub-beams is computer-controlled by varying the scanning speed of said translation stage (99) to achieve a customized dose profile optimized for said composite part (110, 112).

23. A method of initiating photo-curing reactions in a composite part according to claim 17, wherein the UV dose delivered by said set of sub-beams is computer-controlled by varying the object field size to achieve a customized dose profile optimized for said composite part (110, 112).

24. A method of controlling the initiation of photo-curing reactions in a composite part (110, 112) according to claim 17, wherein the UV dose delivered by said set of sub-beams is determined through a simultaneous scan of said composite part (110, 112) for feedback generated from a set of sensors (115) included within said composite part (110, 112), each indicative of the instantaneous condition of photo-curable resins at the related position of said composite part (110, 112).

25. A method of controlling the initiation of photo-curing reactions in a composite part (110, 112) according to claim 17, wherein the UV dose delivered by said set of sub-beams is determined through a simultaneous scan of said composite part (110, 112) and feedback generated from a sensor (115, 116) sensitive to a parameter of photo-curable resin at a position on said composite part (110, 112).

26. A method of controlling the initiation of photo-curing reactions in a composite part (110, 112) according to claim 17, wherein the UV dose delivered by said set of sub-beams is determined by a computer model of the photo-curing dosage requirements across said composite part (110, 112).

27. A method of controlling the initiation of photo-curing reactions in a composite part (110, 112) according to claim 26, characterized by said composite part (110, 112) having externally-applied markings (123) describing the distribution of photo-curable resin across said composite part (110, 112).

29. A composite part (110, 112), with a non-uniform distribution of photo-curable resins at varying positions in its body, made by the process of claim 17 with a varying UV dose consistent with varying resin distribution in said composite part (110, 112).

30. A composite part (110, 112) with a non-uniform distribution of photo-curable resins at varying positions in its body, made by the process of claim 26 with a varying UV dose consistent with varying resin distribution, wherein said composite part (110, 112) with cure variations determined by a computer model of radiation requirements for curing each increment of said composite part (110, 112).

31. A composite part (110, 112) with a non-uniform distribution of photo-curable resins at varying positions in its body, made by the process of claim 27 with a varying UV dose consistent with varying resin distribution, wherein said composite part (110, 112) has cure variations determined by external markings on the surface of said composite part (110, 112).

32. A composite part (110, 112) with a non-uniform distribution of photo-curable resins at varying positions in its body, made by the process of claim 25 with a varying UV dose consistent with varying resin distribution, wherein said composite part (110, 112) the UV dose delivered by said set of sub-beams is determined through a simultaneous scan of said composite part (110, 112) and feedback generated from a sensor (115, 116) sensitive to a parameter of photo-curable resin at a position on said composite part (110-112).

33. A composite part (110, 112) with a non-uniform distribution of photo-curable resins at varying positions in its body, made by the process of claim 17 with a varying UV dose consistent with varying resin distribution, wherein the UV dose delivered by each beam of said set of sub-beams may differ.

28. A method of initiating photo-curing reactions in a three-dimensional composite part built up in incremental layers by selective illumination characterized by

step 1 providing a set of first, second . . . nth specific photo-initiators having different sensitivities to first, second . . . nth specific wavelengths of ultraviolet radiation,

step 2 exposing said first photo-initiator with said first wavelength ultraviolet radiation at selected positions at specific times during the process;

step 3 exposing said second photo-initiator with said second wavelength ultraviolet-radiation at selected positions at specific times during the process; and

step n exposing said nth photo-initiator with said nth wavelength ultraviolet-radiation at selected positions at specific times during the process,

whereby said three-dimensional composite part is built up in incremental layers by selective illumination.