Process for the preparation of photosensitive body surface coating material

• US 6,149,979 A
• Filed: 03/18/1998
• Issued: 11/21/2000
• Est. Priority Date: 03/19/1997
• Status: Expired due to Term

• Current Assignee: Dow Corning Toray Company Limited (Dow, Inc.)
• Original Assignee: Dow Corning Toray Company Limited (Dow, Inc.)
• Inventors: Kobayashi, Hideki, Kushibiki, Nobuo, Masatomi, Toru, Takeuchi, Kikuko
• Primary Examiner(s): DAWSON, ROBERT A
• Application Number:
  US09/040,888
• Time in Patent Office: 979 Days
• Field of Search: 528/42, 524/588, 524/847, 524/858, 524/859, 427/387
• US Class Current: 427/387
• CPC Class Codes: G03G 5/14773 Polycondensates comprising silicon atoms in the main chain

Abstract

A process for the preparation of a photosensitive body surface coating material comprises hydrolytically condensing an alkoxysilane in a mixed solvent comprising an alcohol and water in the presence of finely divided silica. A polysiloxane resin is produced by heat curing the silane after its hydrolytic condensation. The polysiloxane resin has the formula: R¹ SiO_3/2, and R¹ comprises fluorohydrocarbon groups. The photosensitive body surface coating material is not detrimental to the functionality required of the electrophotographic photosensitive bodies, has superior optical uniformity, has low surface energy, and has superior surface hardness.

Claims

1. A process for the preparation of a photosensitive body surface coating material, the process comprising:

i) forming a polysiloxane and coating the polysiloxane on a substrate, wherein the polysiloxane is formed by hydrolytic condensation of a silane in the presence of a mixed solvent comprising alcohol and water in the presence of finely divided silica;

wherein the silane has a formula R² Si(OR³)₃, wherein each R² is selected from the group consisting of fluorohydrocarbon groups of 3 to 12 carbon atoms, saturated hydrocarbon groups of 1 to 18 carbon atoms, saturated hydrocarbon groups of 1 to 18 carbon atoms having oxygen atoms, and aromatic hydrocarbon groups of 6 to 18 carbon atoms; and

R³ is a straight-chain saturated hydrocarbon group of 1 to 8 carbon atoms; and

ii) heat curing the polysiloxane to form a polysiloxane resin of formula R¹ SiO_3/2, wherein each R¹ is selected from the group consisting of fluorohydrocarbon groups of 3 to 12 carbon atoms, saturated hydrocarbon groups of 1 to 18 carbon atoms, saturated hydrocarbon groups of 1 to 18 carbon atoms having oxygen atoms, and aromatic hydrocarbon groups of 6 to 18 carbon atoms; and

with the proviso that not less than 1 mol % and not more than 80 mol % of all the R¹ groups are fluorohydrocarbon groups; and

wherein the polysiloxane is selected such that, after heat curing, the polysiloxane resin has a water contact angle of not less than 95°

.

2. The process of claim 1, wherein the fluorohydrocarbon groups for R² are perfluorocarbon groups bonded to silicon atoms through ethylene groups, wherein the perfluorocarbon groups are selected from the group consisting of perfluoromethyl, perfluoroethyl, perfluoropropyl, perfluorobutyl, perfluoroamyl, perfluorohexyl, perfluoroheptyl, and perfluoroctyl.

3. The process of claim 1, wherein the amount of finely divided silica is 1 to 200 parts by weight, per 100 parts by weight of the polysiloxane resin.

4. The process of claim 3, wherein the amount of finely divided silica is 10 to 100 parts by weight.

5. The process of claim 1, wherein the finely divided silica has an average primary particle diameter of not more than 100 nm.

6. The process of claim 5, wherein the average primary particle diameter is not more than 50 nm.

7. The process of claim 1, wherein hydrolytically condensing the silane is accelerated by adding a catalyst.

8. The process of claim 7, wherein the catalyst is selected from the group consisting of organic acids and organic acid esters.

9. The process of claim 1, wherein the polysiloxane contains 0.1 to 4 weight % excess hydroxyl and hydrolyzable groups.

10. The process of claim 1, wherein a catalyst is added when curing the polysiloxane.

11. The process of claim 10, wherein the catalyst is selected from the group consisting of dimethylamine acetate, ethanolamine acetate, dimethyl aniline formate, tetraethylammonium benzoate, sodium acetate, sodium propionate, sodium formate, benzyltrimethylammonium acetate, dibutyltin dilaurate.

12. The process of claim 1, wherein the photosensitive body surface coating material is a photosensitive drum coating material.

13. The process of claim 1, wherein the photosensitive body surface coating material further comprises a leveling agent.

14. The process of claim 13, wherein the leveling agent is a polyester-modified silicone.

15. The process of claim 1, wherein the silane comprises one or more alkoxysilanes selected from the group consisting of 3,3,4,4,5,5,6,6,6-nonafluorohexyltrimethoxysilane and perfluoroctylethyltriethoxysilane.

16. The process of claim 1, wherein the finely divided silica is colloidal silica dispersed in a lower alcohol.