Coated exterior mirror housing for vehicles

• US 6,150,014 A
• Filed: 07/06/1999
• Issued: 11/21/2000
• Est. Priority Date: 07/15/1996
• Status: Expired due to Fees

• Current Assignee: Donnelly Corporation (Magna International Incorporated)
• Original Assignee: Donnelly Corporation (Magna International Incorporated)
• Inventors: Chu, Tun-Jen, O'Farrell, Desmond J.
• Primary Examiner(s): Le, H. Thi
• Application Number:
  US09/348,083
• Time in Patent Office: 504 Days
• Field of Search: 428/323, 428/328, 428/324, 428/335, 428/412, 428/480, 428/912.2, 428/918
• US Class Current: 428/324
• CPC Class Codes: B29C 41/08 Coating a former, core or other substrate by spraying or fluidisation, e.g. spraying powder spray-up of reinforcing fibres B29C70/305
• CPC Class Codes: B29C 41/20 incorporating preformed parts or layers, e.g. moulding inserts or for coating articles
• CPC Class Codes: B29K 2105/16 Fillers
• CPC Class Codes: B29K 2995/0022 Bright, glossy or shiny surface
• CPC Class Codes: B29K 2995/003 Reflective
• CPC Class Codes: B29K 2995/0055 Resistive to light
• CPC Class Codes: B29L 2031/768 Protective equipment B29L2031/4821 takes precedence
• CPC Class Codes: B60R 1/06 mounted on vehicle exterior B60R1/025, B60R1/08 take precedence
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/251 Mica
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof
• CPC Class Codes: Y10T 428/264 Up to 3 mils
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Abstract

A coated housing for exterior rearview mirrors for vehicles provides increased gloss and depth of color in appearance, and enhanced resistance to scratching, surface crazing and ultraviolet radiation degradation. The housing is preferably molded from a resinous plastic material in a predetermined color and has a generally transparent polymeric material such as clear urethane or acrylic applied in a thin coating to the unpainted housing. The generally transparent coating may include a tint or particles of metal or mica to enhance the molded housing color and/or appearance. Optionally, adhesion of the coating to the housing may be increased by mixing an adhesion promoting agent in said resinous plastic material prior to molding, or by treating the housing surface after molding and prior to application of the coating. An ultraviolet radiation absorbing, blocking, screening material may be included in the generally transparent polymeric material. A method for making the coated exterior rearview mirror housing is also disclosed.

Claims

1. A coated housing for exterior rearview mirrors for vehicles comprising:

a molded housing having an outside surface and an inside surface, said outside surface being exposed and visible from the vehicle exterior, said housing being adapted to house a reflective rearview mirror element when mounted on a vehicle, said housing being molded from a resinous plastic material of a predetermined color and being unpainted; and

a coating of transparent polymeric material on at least a portion of said outside housing surface, said transparent polymeric material having a refractive index from about 1.35 to about 1.67 measured at the sodium D line and at 20°

C., and having incorporated therein at least one ultraviolet radiation absorbing, blocking or screening additive to resist ultraviolet radiation degradation of said resinous plastic material of said housing, whereby said coated outside housing surface portion of said exterior rearview mirror has at least one of enhanced scratch resistance, enhanced resistance to surface crazing, increased resistance to ultraviolet radiation degradation, increased gloss and increased depth of color in appearance as compared to said housing when uncoated with said coating.

2. The coated housing of claim 1 wherein said coating has a thickness in the range of between about 25 to 50 microns.

3. The coated housing of claim 2 wherein said resinous plastic material of said housing is selected from the group consisting of polycarbonate/polyethylene terephthalate blend, acrylonitrile butadiene styrene copolymer, acrylonitrile/styrene/acrylate, and nylon.

4. The coated housing of claim 2 wherein said resinous plastic material includes a plurality of particles mixed therein prior to molding, said particles being visible in said outside surface after molding such that the metallic appearance of said coated housing is enhanced.

5. The coated housing of claim 2 wherein said resinous plastic material includes an adhesion promoting agent mixed therein prior to molding of said housing, said agent providing increased adhesion of said transparent coating to said housing.

6. The coated housing of claim 2 wherein said exterior surface of said housing is treated after molding but before application of said transparent polymeric coating to enhance adhesion of said coating to said outside surface.

7. The coated housing of claim 1 wherein said resinous plastic material includes an adhesion promoting agent mixed therein prior to molding of said housing, said agent providing increased adhesion of said transparent coating to said housing.

8. The coated housing of claim 7 wherein said adhesion promoting agent comprises a bisphenol derivative.

9. The coated housing of claim 1 wherein said ultraviolet radiation absorbing, blocking or screening additive comprises a benzotriazole.

10. The coated housing of claim 1 wherein said outside surface of said housing is treated after molding but before application of said transparent polymeric coating to enhance adhesion of said coating to said outside surface.

11. The coated housing of claim 1 wherein said outside surface is modified prior to application of said transparent coating using a treatment selected from corona surface treatment, plasma surface modification, and chemical surface treatment.

12. The coated housing of claim 1 wherein said transparent coating includes a tint of a desired color whereby the appearance of the color of said resinous plastic material is enhanced.

13. The coated housing of claim 12 wherein said tint has the color of said resinous plastic material of said housing.

14. The coated housing of claim 13 wherein said tint is provided by a pigmentation.

15. The coated housing of claim 1 wherein said resinous plastic material of said housing is selected from the group consisting of polycarbonate/polyethylene terephthalate blend, acrylonitrile butadiene styrene copolymer, acrylonitrile/styrene/acrylate, and nylon.

16. The coated housing of claim 1 wherein said transparent coating includes a plurality of particles dispersed therein to enhance the metallic appearance of said coated housing.

17. The coated housing of claim 16 wherein said particles comprise flakes of material selected from metal and mica.

18. The coated housing of claim 17 wherein said metal flakes comprise aluminum.

19. The coated housing of claim 17 wherein said metal flakes comprise flakes oriented in a predetermined pattern in said coating.

20. The coated housing of claim 17 wherein said metal flakes comprise flakes oriented generally parallel to said outside surface of said housing.

21. The coated housing of claim 1 wherein said resinous plastic material includes a plurality of particles mixed therein prior to molding, said particles being visible in said outside surface after molding such that the metallic appearance of said coated housing is enhanced.

22. A coated housing for exterior rearview mirrors for vehicles comprising:

a molded housing having an outside surface and an inside surface, said outside surface being exposed and visible from the vehicle exterior, said housing being adapted to house a reflective rearview mirror element when mounted on a vehicle, said housing being molded from a resinous plastic material of a predetermined color and being unpainted; and

a coating of transparent polymeric material on at least a portion of said outside housing surface, said transparent polymeric material having a refractive index from about 1.35 to about 1.67 measured at the sodium D line and at 20°

C., and having at least one of a tint compound and a pigmentation in a desired color to enhance the color of said resinous plastic material of said housing, whereby said coated outside housing surface portion of said exterior rearview mirror has at least one of enhanced scratch resistance, enhanced resistance to surface crazing, increased resistance to ultraviolet radiation degradation, increased gloss and increased depth of color in appearance as compared to said housing when uncoated with said coating.

23. The coated housing of claim 22 wherein said tint compound is matched to the color of said resinous plastic material of said housing.

24. The coated housing of claim 23 wherein said resinous plastic material includes a plurality of particles mixed therein prior to molding, said particles being visible in said outside surface after molding such that the metallic appearance of said coated housing is enhanced.

25. The coated housing of claim 23 wherein said resinous plastic material includes an adhesion promoting agent mixed therein prior to molding of said housing, said agent providing increased adhesion of said transparent coating to said housing.

26. The coated housing of claim 23 wherein said exterior surface of said housing is treated after molding but before application of said transparent polymeric coating to enhance adhesion of said coating to said outside surface.

27. The coated housing of claim 22 wherein said transparent polymeric material also has incorporated therein at least one ultraviolet radiation absorbing, blocking or screening additive to resist ultraviolet radiation degradation of said resinous plastic material of said housing.

28. The coated housing of claim 27 wherein said ultraviolet radiation absorbing material, blocking or screening additive comprises a benzotriazole.

29. The coated housing of claim 22 wherein said coating has a thickness in the range of between about 25 to 50 microns.

30. The coated housing of claim 29 wherein said resinous plastic material of said housing is selected from the group consisting of polycarbonate/polyethylene terephthalate blend, acrylonitrile butadiene styrene copolymer, acrylonitrile/styrene/acrylate, and nylon.

31. The coated housing of claim 22 wherein said resinous plastic material includes an adhesion promoting agent mixed therein prior to molding of said housing, said agent providing increased adhesion of said transparent coating to said housing.

32. The coated housing of claim 31 wherein said adhesion promoting agent comprises a bisphenol derivative.

33. The coated housing of claim 22 wherein said outside surface of said housing is treated after molding but before application of said transparent polymeric coating to enhance adhesion of said coating to said outside surface.

34. The coated housing of claim 22 wherein said outside surface is modified prior to application of said transparent coating using a treatment selected from corona surface treatment, plasma surface modification, and chemical surface treatment.

35. The coated housing of claim 22 wherein said tint compound is provided by a pigmentation.

36. The coated housing of claim 22 wherein said resinous plastic material of said housing is selected from the group consisting of polycarbonate/polyethylene terephthalate blend, acrylonitrile butadiene styrene copolymer, acrylonitrile/styrene/acrylate, and nylon.

37. The coated housing of claim 36 wherein said coating layer includes an ultraviolet radiation absorbing material.

38. The coated housing of claim 22 wherein said transparent coating includes a plurality of particles dispersed therein to enhance the metallic appearance of said coated housing.

39. The coated housing of claim 38 wherein said particles comprise flakes of material selected from metal and mica.

40. The coated housing of claim 39 wherein said metal flakes comprise aluminum.

41. The coated housing of claim 39 wherein said metal flakes comprise flakes oriented in a predetermined pattern in said coating.

42. The coated housing of claim 39 wherein said metal flakes comprise flakes oriented generally parallel to said outside surface of said housing.

43. The coated housing of claim 22 wherein said resinous plastic material includes a plurality of particles mixed therein prior to molding, said particles being visible in said outside surface after molding such that the metallic appearance of said coated housing is enhanced.