Optically clear shampoo compositions containing aminofunctional silicone microemulsions

• US 6,153,569 A
• Filed: 07/24/1998
• Issued: 11/28/2000
• Est. Priority Date: 05/24/1991
• Status: Expired due to Fees

• Current Assignee: Dow, Inc.
• Original Assignee: Dow, Inc.
• Inventors: Halloran, Daniel Joseph
• Primary Examiner(s): FRIES, KERY A
• Application Number:
  US09/122,389
• Time in Patent Office: 858 Days
• Field of Search: 510/121, 510/122, 510/123, 510/124, 510/466, 510/135, 510/137, 510/151, 510/471, 510/473, 510/6, 424/70.12, 424/70.13
• US Class Current: 510/119
• CPC Class Codes: A61K 8/068 Microemulsions
• CPC Class Codes: A61K 8/898 containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair

Abstract

This invention relates to the use of aminofunctional silicone microemulsions to make optically clear compositions. More particularly this invention is directed to optically clear shampoo compositions comprising (A) an aminofunctional silicone microemulsion having an average particle size of less than 0.06 microns, (B) at least one anionic detersive surfactant, (C) at least one foam boosting agent, (D) at least one pH adjusting agent, (E) at least one thickening agent, and (F) water. The optically clear silicone compositions of this invention are useful in the hair care industry, especially as shampoos.

Claims

1. An optically clear shampoo composition comprising:

(A) an aminofunctional silicone microemulsion having an average particle size of less than 0.14 microns comprising;

(i) an aminofunctional polyorganosiloxane having its formula selected from the group consisting of

space="preserve" listing-type="equation">R.sub.3 SiO(R.sub.2 SiO).sub.x (RQSiO).sub.y SiR.sub.3 and

space="preserve" listing-type="equation">HOR.sub.2 SiO(R.sub.2 SiO).sub.x (RQSiO).sub.y SiR.sub.2 OH

wherein R is selected from the group consisting of alkyl, aryl, and alkenyl radicals, Q is a polar radical having the formula --R'"'"'NHR² wherein R'"'"' is a divalent linking group composed of carbon and hydrogen atoms having from 2 to 10 carbon atoms, and R² is selected from the group consisting of a hydrogen atom, alkyl radicals containing from 1 to 4 carbon atoms, and the --CH₂ CH₂ NH₂ radical, the value of y is at least one, and the sum of x+y is less than 500;

(ii) a surfactant which is insoluble in the polyorganosiloxane; and

(iii) water;

(B) at least one anionic detersive surfactant;

(C) at least one foam boosting agent;

(D) at least one pH adjusting agent;

(E) at least one thickening agent; and

(F) water.

2. A composition according to claim 1, wherein R is methyl, Q is a polar radical having the formula --R'"'"'NHCH₂ CH₂ NH₂, R'"'"' is selected from the group consisting of propylene, and --CH₂ CH(CH₃)CH₂ --.

3. A composition according to claim 1, wherein (A)(ii) is selected from the group consisting of anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants, combinations of 2 or more types of nonionic surfactants, combinations of nonionic surfactants and anionic surfactants, and combinations of nonionic surfactants and cationic surfactants.

4. A composition according to claim 3, wherein the anionic surfactants are selected from the group consisting of alkali metal sulforicinates, sulfonated glyceryl esters of fatty acids, salts of sulfonated monovalent alcohol esters, amides of amino sulfonic acids, sulfonated products of fatty acids nitrites, sulfonated aromatic hydrocarbons, condensation products of naphthalene sulfonic acids with formaldehyde, sodium octahydroanthracene sulfonate, alkali metal alkyl sulfates, ether sulfates having alkyl groups of 8 or more carbon atoms, alkylarylsulfonates having 1 or more alkyl groups having 8 or more carbon atoms, alkylbenzenesulfonic acid alkali metal salts, sulfuric esters of polyoxyethylene alkyl ether, alkylnaphthylsulfonic acid sodium salts, alkylnaphthylsulfonic acid potassium salts, and alkylnaphthylsulfonic acid amine salts.

5. A composition according to claim 3, wherein the cationic surfactants are selected from the group consisting of fatty acid amines, fatty acid amides, fatty acid amine salts, fatty acid amide salts.

6. A composition according to claim 3, wherein the nonionic surfactants are selected from the group consisting of polyoxyethylene alkyl ethers, polyoxyethylene alkylphenol ethers, polyoxyethylene lauryl ethers, polyoxyethylene sorbitan monoleates, polyoxyethylene alkyl esters, polyoxyethylene sorbitan alkyl esters, polyethylene glycol, polypropylene glycol, diethylene glycol, ethoxylated trimethylnonanols, and polyoxyalkylene glycol modified polysiloxanes.

7. A composition according to claim 3, wherein the amphoteric surfactants are selected from the group consisting of amino acid surfactants and betaine acid surfactants.

8. A composition according to claim 1, wherein (A)(ii) is selected from the group consisting of 2,6,8-trimethyl-4-nonyloxypolyethylene oxyethanol, 2,6,8-trimethyl-4-nonyloxypolyethylene oxyethanol, alkylene-oxypolyethylene oxyethanol, octylphenoxy polyethoxy ethanols, nonionic ethoxylated tridecyl ethers, alkali metal salts of dialkyl sulfosuccinates, polyethoxylated quaternary ammonium salts, ethylene oxide condensation products of primary fatty amines, and polyoxyalkylene glycol modified polysiloxanes.

9. A composition according to claim 1, wherein (B) is selected from the group consisting of selected from the group consisting of alkali metal sulforicinates, sulfonated glyceryl esters of fatty acids, salts of sulfonated monovalent alcohol esters, amides of amino sulfonic acids, sulfonated products of fatty acids nitrites, sulfonated aromatic hydrocarbons, condensation products of naphthalene sulfonic acids with formaldehyde, sodium octahydroanthracene sulfonate, alkali metal alkyl sulfates, ether sulfates having alkyl groups of 8 or more carbon atoms, alkylarylsulfonates having 1 or more alkyl groups having 8 or more carbon atoms, alkylbenzenesulfonic acid alkali metal salts, sulfuric esters of polyoxyethylene alkyl ether, alkylnaphthylsulfonic acid sodium salts, alkylnaphthylsulfonic acid potassium salts, and alkylnaphthylsulfonic acid amine salts.

10. A composition according to claim 1, wherein (B) is selected from the group consisting of sodium lauryl sulfate, ammonium lauryl sulfate, triethanolamine lauryl sulfate, sodium lauryl ether sulfate, and ammonium lauryl ether sulfate.

11. A composition according to claim 1, wherein (C) is selected from the group consisting of fatty acid alkanolamides and amine oxides.

12. A composition according to claim 11, wherein the fatty acid alkanolamides are selected from the group consisting of isostearic acid diethanolamide, lauric acid diethanolamide, capric acid diethanolamide, coconut fatty acid diethanolamide, linoleic acid diethanolamide, myristic acid diethanolamide, oleic acid diethanolamide, stearic acid diethanolamide, coconut fatty acid monoethanolamide, oleic acid monoisopropanolamide, and lauric acid monoisopropanolamide.

13. A composition according to claim 11, wherein the amine oxides are selected from the group consisting of N-cocodimethylamine oxide, N-lauryl dimethylamine oxide, N-myristyl dimethylamine oxide, N-stearyl dimethylamine oxide, N-cocamidopropyl dimethylamine oxide, N-tallowamidopropyl dimethylamine oxide, bis(2-hydroxyethyl) C12-15 alkoxypropylamine oxide.

14. A composition according to claim 1, wherein (C) is selected from the group consisting of lauric acid diethanolamide, N-lauryl dimethylamine oxide, coconut acid diethanolamide, myristic acid diethanolamide, and oleic acid diethanolamide.

15. A composition according to claim 1, wherein (D) is a water soluble acid.

16. A composition according to claim 15, wherein the water soluble acid is selected from the group consisting of carboxylic acids and mineral acids.

17. A composition according to claim 16, wherein the mineral acid is selected from the group consisting of hydrochloric acid, sulfuric acid, and phosphoric acid and the carboxylic acid is selected from the group consisting of acetic acid, lactic acid, succinic acid, adipic acid, and citric acid.

18. A composition according to claim 1, wherein (E) is selected from the group consisting of sodium alginate, gum arabic, polyoxyethylene, guar gum, hydroxypropyl guar gum, cellulose derivatives, starch, starch derivatives, locust bean gum, electrolytes, saccharides, saccharides derivatives, a combination of a cellulose derivative and an electrolyte, and a combination of a starch derivative and an electrolyte.

19. A composition according to claim 1, wherein (E) is selected from the group consisting of cellulose derivatives, saccharide derivatives, and electrolytes.

20. A composition according to claim 18, wherein the cellulose derivative is selected from the group consisting of methylcellulose, methylhydroxypropylcellulose, hydroxypropylcellulose, and polypropylhydroxyethylcellulose, the starch derivative is selected from the group consisting of hydroxyethylamylose and starch amylose, the electrolyte is selected from the group consisting of sodium chloride and ammonium chloride, the saccharide is selected from the group consisting of fructose and glucose, and the saccharide derivative is PEG-20 methyl glucose diolate.

21. A composition according to claim 19, wherein the cellulose derivative is selected from the group consisting of methylcellulose, methylhydroxypropylcellulose, hydroxypropylcellulose, and polypropylhydroxyethylcellulose, the saccharide derivative is PEG-20 methyl glucose diolate, and the electrolyte is selected from the group consisting of sodium chloride and ammonium chloride.

22. A method of shampooing hair comprising:

(I) wetting hair;

(II) applying to the hair an optically clear shampoo composition comprising;

(A) an aminofunctional silicone microemulsion having an average particle size of less than 0.14 microns comprising;

(i) an aminofunctional polyorganosiloxane having its formula selected from the group consisting of

space="preserve" listing-type="equation">R.sub.3 SiO(R.sub.2 SiO).sub.x (RQSiO).sub.y SiR.sub.3 and

space="preserve" listing-type="equation">HOR.sub.2 SiO(R.sub.2 SiO).sub.x (RQSiO).sub.y SiR.sub.2 OH

wherein R is selected from the group consisting of alkyl, aryl, and alkenyl radicals, Q is a polar radical having the formula --R'"'"'NHR² wherein R'"'"' is a divalent linking group composed of carbon and hydrogen atoms having from 2 to 10 carbon atoms, and R² is selected from the group consisting of a hydrogen atom, all radicals containing from 1 to 4 carbon atoms, and the --CH₂ CH₂ NH₂ radical, the value of y is at least one, and the sum of x+y is less than 500;

(ii) a surfactant which is insoluble in the polyorganosiloxane; and

(iii) water;

(B) at least one anionic detersive surfactant;

(C) at least one foam boosting agent;

(D) at least one pH adjusting agent;

(E) at least one thickening agent; and

(F) water;

(III) massaging the optically clear hair conditioning composition into the hair; and

(IV) rinsing the optically clear hair conditioning composition from the hair with water.