Toner and image forming method

• US 6,156,471 A
• Filed: 01/19/2000
• Issued: 12/05/2000
• Est. Priority Date: 01/21/1999
• Status: Expired due to Fees

• Current Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Original Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Inventors: Fujimoto, Masami, Fujikawa, Hiroyuki, Kobori, Takakuni, Tanikawa, Hirohide
• Primary Examiner(s): MARTIN, ROLAND E
• Application Number:
  US09/487,703
• Time in Patent Office: 321 Days
• Field of Search: 430/110, 430/111, 430/120
• US Class Current: 430/108.6
• CPC Class Codes: G03G 9/0819 characterised by the dimensions of the particles
• CPC Class Codes: G03G 9/097 Plasticisers; Charge controlling agents

Abstract

An electrophotographic toner showing good cleanability and is suitable for use in developing an electrostatic latent image formed on an amorphous-silicon photosensitive member is provided. The toner includes toner particles each comprising a binder resin and a colorant, and inorganic fine powder A. The inorganic fine powder A contains 88.0-97.0 wt. % of a rare earth compound comprising a rare earth oxide. The rare earth compound contains 40.0-65.0 wt. % of Ce (calculated as CeO₂), 25.0-45.0 wt. % of La (calculated as La₂ O₃), 1.0-10.0 wt. % of Nd (calculated as Nd₂ O₃) and 1.0-10.0 wt. % of Pr (calculated as Pr₆ O₁₁). The rare earth compound contains further a fluorinated rare earth compound in such an amount as to provide the inorganic fine powder A with a fluorine content of 2.0-11.0 wt. %.

Claims

1. A toner, comprising:

toner particles each comprising a binder resin and a colorant, and inorganic fine powder A, wherein

the inorganic fine powder A contains 88.0-97.0 wt. % of a rare earth compound comprising a rare earth oxide,

the rare earth compound contains 40.0-65.0 wt. % of Ce (calculated as CeO₂), 25.0-45.0 wt. % of La (calculated as La₂ O₃), 1.0-10.0 wt. % of Nd (calculated as Nd₂ O₃) and 1.0-10.0 wt. % of Pr (calculated as Pr₆ O₁₁), and

the rare earth compound contains a fluorinated rare earth compound in such an amount as to provide the inorganic fine powder A with a fluorine content of 2.0-11.0 wt. %.

2. The toner according to claim 1, wherein the inorganic fine powder A has a volume-average particle size of 0.1-4.0 μ

m, and a BET specific surface area according to nitrogen adsorption of 0.5-15.0 m² /g.

3. The toner according to claim 1, wherein the inorganic fine powder A has a volume-average particle size of 0.2-2.0 μ

m, and a BET specific surface area according to nitrogen adsorption of 1.0-10.0 m² /g.

4. The toner according to claim 1, wherein the inorganic fine powder A contains 89.0-96.0 wt. % of the rare earth compound.

5. The toner according to claim 1, wherein the inorganic fine powder A contains 90.0-95.0 wt. % of the rare earth compound.

6. The toner according to claim 1, which toner contains 0.1-10.0 wt. % of the inorganic fine powder A.

7. The toner according to claim 1, which toner contains 0.1-7.0 wt. % of the inorganic fine powder A.

8. The toner according to claim 1, wherein the inorganic fine powder A is an inorganic fine powder obtained by converting bastnaesite into rare earth oxide and partially fluorinating the rare earth oxide with hydrofluoric acid.

9. The toner according to claim 1, wherein the inorganic fine powder A contains less than 100 ppm each of uranium and thorium.

10. The toner according to claim 1, which toner further contains inorganic fine powder B giving a dispersion at a concentration of 4 g/100 cc exhibiting a pH of at least 7.

11. The toner according to claim 1, which toner further contains inorganic fine powder C having been treated with silicone oil.

12. The toner according to claim 1, which toner is positively chargeable.

13. The toner according to claim 1, which toner has a weight-average particle size of 4-13 μ

m.

14. The toner according to claim 1, which toner has a weight-average particle size of 5-12 μ

m.

15. An image forming method, comprising:

a charging step of charging an image-bearing member,

an image forming step of forming an electrostatic image on the charged image-bearing member,

a developing step of developing the electrostatic image with a toner to form a toner image on the image-bearing member,

a transfer step of transferring the toner image onto a recording material via or without via an intermediate transfer member,

a fixing step of heat-fixing the toner image onto the recording material, and

a cleaning step of cleaning a surface of the image bearing member after transfer of the toner image;

wherein

the toner comprises toner particles each comprising a binder resin and a colorant, and inorganic fine powder A,

the inorganic fine powder A contains 88.0-97.0 wt. % of a rare earth compound comprising a rare earth oxide,

the rare earth compound contains 40.0-65.0 wt. % of Ce (calculated as CeO₂), 25.0-45.0 wt. % of La (calculated as La₂ O₃), 1.0-10.0 wt. % of Nd (calculated as Nd₂ O₃) and 1.0-10.0 wt. % of Pr (calculated as Pr₆ O₁₁), and

the rare earth compound contains a fluorinated rare earth compound in such an amount as to provide the inorganic fine powder A with a fluorine content of 2.0-11.0 wt. %.

16. The image forming method according to claim 15, wherein the image-bearing member comprises an amorphous silicon photosensitive member.

17. The image forming method according to claim 16, wherein the amorphous silicon photosensitive member is charged and then exposed to form a digital latent image.

18. The image forming method according to claim 16, wherein the amorphous silicon photosensitive member is charged to a positive potential and exposed to form a digital latent image, which is developed with the toner having a positive triboelectric charge according to a reversal development mode.

19. The image forming method according to claim 15, wherein the image-bearing member is regulated to have a surface temperature of at most 45°

C. during image formation.

20. The image forming method according to claim 15, wherein the image bearing member is cleaned by means of a cleaning blade, a cleaning roller or a combination of these in the cleaning step.

21. The image forming method according to claim 15, wherein the image bearing member is cleaned by means of at least a cleaning roller enclosing therein a magnetic field generating means.

22. The image forming method according to claim 15, wherein the recording material is conveyed for the transfer step by means of an elastic roller.

23. The image forming method according to claim 15, wherein the inorganic fine powder A has a volume-average particle size of 0.1-4.0 μ

m, and a BET specific surface area according to nitrogen adsorption of 0.5-15.0 m² /g.

24. The image forming method according to claim 15, wherein the inorganic fine powder A has a volume-average particle size of 0.2-2.0 μ

m, and a BET specific surface area according to nitrogen adsorption of 1.0-10.0 m² /g.

25. The image forming method according to claim 15, wherein the inorganic fine powder A contains 89.0-96.0 wt. % of the rare earth compound.

26. The image forming method according to claim 15, wherein the inorganic fine powder A contains 90.0-95.0 wt. % of the rare earth compound.

27. The image forming method according to claim 15, wherein the toner contains 0.1-10.0 wt. % of the inorganic fine powder A.

28. The image forming method according to claim 15, wherein the toner contains 0.1-7.0 wt. % of the inorganic fine powder A.

29. The image forming method according to claim 15, wherein the inorganic fine powder A is an inorganic fine powder obtained by converting bastnaesite into rare earth oxide and partially fluorinating the rare earth oxide with hydrofluoric acid.

30. The image forming method according to claim 15, wherein the inorganic fine powder A contains less than 100 ppm each of uranium and thorium.

31. The image forming method according to claim 15, wherein the toner further contains inorganic fine powder B giving a dispersion at a concentration of 4 g/100 cc exhibiting a pH of at least 7.

32. The image forming method according to claim 15, wherein the toner further contains inorganic fine powder C having been treated with silicone oil.

33. The image forming method according to claim 15, wherein the toner is positively chargeable.

34. The image forming method according to claim 15, wherein the toner has a weight-average particle size of 4-13 μ

m.

35. The image forming method according to claim 15, wherein the toner has a weight-average particle size of 5-12 μ

m.