Process for preparing an aqueous powder coating dispersion and using the same

• US 6,159,556 A
• Filed: 02/06/1998
• Issued: 12/12/2000
• Est. Priority Date: 05/19/1995
• Status: Expired due to Term

• Current Assignee: BASF Coatings AG (BASF SE)
• Original Assignee: BASF Coatings AG (BASF SE)
• Inventors: Moller, Dietmar, Woltering, Joachim
• Primary Examiner(s): Parker, Fred J.
• Application Number:
  US08/952,567
• Time in Patent Office: 1,040 Days
• Field of Search: 427/475, 427/485, 427/486, 427/421, 523/403, 525/408, 525/411
• US Class Current: 427/475
• CPC Class Codes: C08J 3/03 in aqueous media
• CPC Class Codes: C09D 163/00 Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
• CPC Class Codes: C09D 5/02 Emulsion paints including aerosols

Abstract

The present invention relates to an aqueous powder coating dispersion comprising a solid, pulverulent component A and an aqueous component B, in which component A. is a powder coating comprising

a) at least one epoxide-containing binder with a content of from 30 to 45%, preferably from 30 to 35%, of glycidyl-containing monomers and, if desired, with a content of aromatic vinyl compounds, preferably styrene,

b) at least one crosslinking agent, preferably straight-chain aliphatic dicarboxylic acids and/or carboxy-functional polyesters, and

c) if desired, catalysts, auxiliaries, typical powder coating additives, such as degassing agents, levelling agents, UV absorbers, free-radical scavengers and antioxidants,

and component B. is an aqueous dispersion comprising

a) at least one nonionic thickener and

b) if desired, catalysts, auxiliaries, defoaming agents, dispersion auxiliaries, wetting agents, preferably carboxy-functional dispersants, antioxidants, UV absorbers, free-radical scavengers, biocides, small quantities of solvent and/or hygroscopic agents.

Claims

1. An aqueous powder coating dispersion, comprising the result of

dispersing a solid pulverulent component A into an aqueous component B to provide an aqueous dispersion of a powder coating composition having a glass transition temperature of from 20 to 90°

C., a viscosity of from 10 to 1000 mPas at a shear rate of 500 s^-1, and a solids content of from 20 to 40% by weight,

subjecting said aqueous dispersion of a powder coating to a grinding process while maintaining a temperature of from 0 to 60°

C. to provide an aqueous powder coating dispersion having a solids content of from 20 to 40% by weight,

wherein solid pulverulent component A is a powder coating composition comprising

a) at least one epoxide-containing binder comprising from 30 to 45% by weight of glycidyl-containing monomers,

b) at least one crosslinking agent, and

component B is an aqueous dispersion comprising

a) at least one nonionic thickener.

2. The aqueous powder coating dispersion of claim 1, wherein the grinding process has a specific energy input between 20 and 500 Wh/kg.

3. An aqueous powder coating dispersion comprising

incorporating a first portion of the ground aqueous dispersion of a powder coating of claim 1 into an aqueous dispersion comprising one or more additives selected from the group consisting of defoamers, dispersion auxiliaries, wetting agents, thickeners, and mixtures thereof, to create an aqueous dispersion containing the first portion of ground aqueous dispersion of a powder coating,

incorporating one or more additional additives selected from the group consisting of defoamers, dispersion auxiliaries, wetting agents, thickeners, and mixtures thereof, into the aqueous dispersion containing the first portion of ground aqueous dispersion of a powder coating, and

incorporating a second portion of the ground aqueous dispersion of a powder coating of claim 1 into the aqueous dispersion containing the first portion of ground aqueous dispersion of a powder coating and one or more additional additives to an aqueous dispersion of a powder coating.

4. The aqueous powder coating dispersion of claim 1 which is a powder clearcoat dispersion.

5. The aqueous powder coating dispersion of claim 1 having a pH between 4.0 and 7.0.

6. The aqueous powder coating dispersion of claim 1 wherein the epoxide-containing containing binder A a) further comprises aromatic vinyl compounds.

7. The aqueous powder coating dispersion of claim 1 wherein the epoxide-functional binders comprise polyacrylate resins which contain epoxide groups, and the glycidyl-containing monomers are selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, allyl glycidyl esters and mixtures thereof.

8. The aqueous powder coating dispersion of claim 1 wherein nonionic thickener a) of component B comprises at least one nonionic associative thickener comprising:

aa) a hydrophilic structure and

ab) hydrophobic groups capable of associative interaction in an aqueous medium.

9. The aqueous powder coating dispersion according to claim 8, wherein nonionic associative thickener a) comprises polyurethane chains as hydrophilic structure aa).

10. The aqueous powder coating dispersion according to claim 9, wherein nonionic associative thickener a) comprises polyurethane chains with polyether units as hydrophilic structure aa).

11. The aqueous powder coating dispersion of claim 1, having a particle size not more than 20 μ

m.

14. The aqueous powder coating dispersion of claim 1 wherein the aqueous dispersion of a powder coating composition subjected to grinding has a glass transition temperature of from 40 to 70°

C., a viscosity of from 50 to 300 mPas at a shear rate of 500 s^-1 and a solids content of from 20 to 40% by weight and the grinding process is maintained at a temperature of from 5 to 35°

C.

15. The aqueous powder coating dispersion of claim 1, wherein the grinding process has a specific energy input between 50 to 250 Wh/kg.

16. The aqueous powder dispersion of claim 1 wherein epoxide containing binder Aa) comprises from 30 to 35% by weight of glycidyl-containing monomers.

17. The aqueous powder dispersion of claim 1 wherein crosslinking agent Ab) is selected from the group consisting of straight chain aliphatic dicarboxylic acids, carboxy functional polyesters, and mixtures thereof.

18. The aqueous powder dispersion of claim 5 having a pH between 5.5 and 6.5.

19. The aqueous powder coating dispersion of claim 6 wherein the epoxide containing binder Aa) comprises no more than 35% by weight of aromatic vinyl compounds based on the weight of component Aa).

20. The aqueous powder coating dispersion of claim 19 wherein the epoxide containing binder Aa) comprises 10-25% by weight of aromatic vinyl compounds based on the weight of component Aa).

21. The aqueous powder coating dispersion of claim 6 wherein the epoxide containing binder Aa) further comprises styrene.

12. A process for the preparation of an aqueous powder coating dispersion comprising

preparing an aqueous dispersion of a powder coating composition by dispersing a solid pulverulent component A into an aqueous component B, the resulting aqueous dispersion having a glass transition temperature of from 20 to 90°

C., a viscosity of from 10 to 1000 mPas at a shear rate of 500 s^-1, and a solids content of from 20 to 40% by weight, and

grinding the aqueous dispersion of a powder coating composition while maintaining a temperature of from 0 to 60°

C. to provide a ground aqueous dispersion of a powder coating,

establishing a pH of from 4.0 to 7.0 in the ground aqueous dispersion of a powder coating, and

filtering the ground aqueous dispersion of a powder coating dispersion to provide an aqueous powder coating dispersion,

wherein solid pulverulent component A is a powder coating composition comprising

a) at least one epoxide-containing binder comprising from 30 to 45% by weight of glycidyl-containing monomers,

b) at least one crosslinking agent selected from the group consisting of straight chain aliphatic dicarboxylic acids, carboxy-functional polyesters, and mixtures thereof, and

component B is an aqueous dispersion comprising

a) at least one nonionic thickener.

13. The process of claim 12, further comprising grinding the aqueous dispersion of a powder coating composition in a grinding apparatus.

22. A process of coating an article with an aqueous dispersion of a powder coating composition, comprising

providing an aqueous powder coating dispersion comprising the result of

subjecting an aqueous dispersion of a powder coating composition comprising at least one crosslinking agent, the aqueous dispersion having a glass transition temperature of from 20 to 90°

C., a viscosity of from 10 to 1000 mPas, and a solids content of from 20 to 40% by weight, to a grinding process while maintaining a temperature of from 0 to 60°

C. , and

applying the aqueous dispersion of a powder coating composition to an article by means of electrostatically assisted rotation or pneumatic application.

23. The process of claim 22 wherein the article is an automotive car body or a component thereof.