Thermoplastic interlayer film

• US 6,159,608 A
• Filed: 08/10/1998
• Issued: 12/12/2000
• Est. Priority Date: 09/28/1995
• Status: Expired due to Fees

• Current Assignee: Saint-Gobain Performance Plastics Corporation (Compagnie De Saint-Gobain)
• Original Assignee: Saint-Gobain Performance Plastics Corporation (Compagnie De Saint-Gobain)
• Inventors: Friedman, Michael, Visscher, Glenn T.
• Primary Examiner(s): NAKARANI, DHIRAJLAL S
• Application Number:
  US09/131,859
• Time in Patent Office: 855 Days
• Field of Search: 524/261, 524/262, 524/264, 524/265, 524/284, 524/300, 524/306, 524/314, 524/423, 524/425, 524/427, 524/543, 525/333.8, 525/342, 428/441, 428/520, 428/442
• US Class Current: 428/442
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/1055 characterized by the resin layer, i.e. interlayer
• CPC Class Codes: B32B 17/10587 created by embossing
• CPC Class Codes: B32B 17/10678 comprising UV absorbers or stabilizers, e.g. antioxidants
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/10788 containing ethylene vinylacetate
• CPC Class Codes: B32B 2307/40 having particular optical properties light or UV resistant B32B2307/71
• CPC Class Codes: B32B 2307/50 having particular mechanical properties
• CPC Class Codes: B32B 2323/046 LDPE, i.e. low density polyethylene
• CPC Class Codes: B32B 2551/00 Optical elements
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C08J 2323/08 Copolymers of ethene C08J2323/16 takes precedence
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: Y10T 428/31645 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31649 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer

Abstract

High clarity optical and safety glass laminate interlayer films and optical laminates are described. The films and their laminates comprise very low density polyethylene and/or its copolymers, preferably polymerized with metallocene catalysts, and modified with additives, such as coupling agents, clarifying or nucleation agents, UV-light absorbers, pigment or color concentrate, and IR-light blockers. The very low density polyethylene is laminated to EVA film for improved bondability in optical laminates.

Claims

1. An interlayer film for use in an optical laminate, the optical laminate having a haze value of less than 4% at a film thickness of 125 to 1000 mcm, comprising a film of at least one substantially linear low density polyolefin, having a polydispersity index of less than 3.5, a density from about 0.850 to 0.905 g/ccm and less than 20%, by weight, crystallinity, laminated to at least one film of ethylene vinyl acetate copolymer.

2. The interlayer film of claim 1, further comprising a nucleation agent in an amount of from about 0.05% to about 2.0% by weight of the interlayer film;

and a crosslinking agent in the amount of from about 0.05% to about 2% by weight of the interlayer film.

3. The interlayer film of claim 1 further comprising a UV-light absorber in an amount of from about 0.1% to about 1.5% weight of the interlayer film.

4. The interlayer film of claim 1, further comprising additives selected from the group consisting of colorizing agents and IR-light blockers.

5. The interlayer film of claim 1, further comprising a coupling agent in an amount of from about 0.2% to about 2.0% by weight of the interlayer film.

6. The interlayer film of claim 1, comprising a film of a metallocene catalyzed linear low density polyethylene;

a nucleation agent in an amount of from about 0.01% to about 2.0%, by weight; and

a crosslinking agent in the amount of from about 0.05% to 2%, by weight, of the interlayer film.

7. An optical laminate comprising at least one layer consisting of the interlayer film of claim 1.

8. The optical laminate of claim 7, wherein the optical laminate is a safety glass.

9. The optical laminate of claim 8, wherein the optical laminate is selected from the group consisting of windshields for automobiles, trains, ships, boats and other transportation vehicles, sound screens, and window and door glass for buildings and architectural structures.

10. An optical laminate comprising at least one layer of the interlayer film of claim 1, wherein the optical laminate has a haze value of no more than 2% at a film thickness of 125 to 1,000 mcm, and the polyolefin has a polydispersity index of less than 2.5, a density of less than 0.880 g/ccm and a crystallinity less than 15%, by weight.

11. An optical laminate comprising at least one layer of the interlayer film of claim 1, wherein the optical laminate has a haze value of no more than 1% at a film thickness of 125 to 1,000 mcm, and the polyolefin has a polydispersity index of less than 2.5, a density of less than 0.880 g/ccm and a crystallinity less than 10%, by weight.