Composite electrode including current collector

• US 6,159,635 A
• Filed: 09/29/1998
• Issued: 12/12/2000
• Est. Priority Date: 09/29/1998
• Status: Expired due to Term

• Current Assignee: Electrovaya Incorporated
• Original Assignee: Electrofuel, Inc.
• Inventors: Dasgupta, Sankar, Jacobs, James K.
• Primary Examiner(s): CHANEY, CAROL DIANE
• Application Number:
  US09/161,664
• Time in Patent Office: 805 Days
• Field of Search: 429/61, 429/62, 429/216, 429/232
• US Class Current: 429/216
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/4235 Safety or regulating additives or arrangements in electrodes, separators or electrolyte H01M10/4242 takes precedence
• CPC Class Codes: H01M 2200/106 PTC
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/134 Electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/667 in the form of layers, e.g. coatings
• CPC Class Codes: H01M 4/668 Composites of electroconductive material and synthetic resins
• CPC Class Codes: H01M 50/461 with adhesive layers between electrodes and separators
• CPC Class Codes: H01M 6/10 with wound or folded electrodes

Abstract

A composite electrode for a rechargeable lithium battery is described. The composite electrode has a metallic current collector in contact with an electrically conducting organic polymer laminate made of a blended and annealed polymeric mixture containing fine carbon particles, and coated with an electrode-active substance bearing layer. The conducting polymer is capable of reversible resistivity changes of several orders of magnitude in only a portion of the laminate, thereby reducing locally excessive current flow and over-heating in the rechargeable lithium battery.

Claims

1. In a rechargeable lithium battery having a negative electrode, a positive electrode, a metallic current collector adjacent each electrode and a non-aqueous electrolyte, the improvement comprising, that an organic polymer laminate having two opposing faces and rendered electrically conductive by embedded electrically conductive particles, is inserted between at least one of the electrodes and the adjacent metallic current collector, thereby forming a composite electrode including said positive or said negative electrode, comprising said electrically conductive organic polymer laminate having one face in contact with said metallic current collector and another face with said positive or said negative electrode, said electrically conductive organic polymer laminate having a thickness, said thickness and said opposing faces defining a total volume, said electrically conductive organic polymer laminate having a positive temperature coefficient of resistivity, a resistivity switch temperature Trs, between 75 and 120°

C., said electrically conductive organic polymer laminate being capable of reversible resistivity change of at least 2 orders of magnitude within a 5°

temperature band of said T_rs, and wherein said electrically conductive organic polymer is capable of having said reversible resistivity change in a portion of the total volume of said electrically conductive organic polymer laminate.

2. An improved rechargeable lithium battery as claimed in claim 1, wherein said positive or said negative electrode included in said composite electrode, is comprising a blended mixture of an electrode-active substance, carbon particles and a binder, and said blended mixture is applied as a coherent electrode layer.

3. An improved rechargeable lithium battery as claimed in claim 1, wherein said reversible resistivity change in said portion of the total volume of said electrically conductive organic polymer laminate is caused by a localized temperature change greater than 5°

relative to the average temperature of said rechargeable lithium battery.

4. An improved rechargeable lithium battery as claimed in claim 1, wherein said volume portion of said electrically conductive organic polymer laminate is less than 50 vol. % of the total volume of said electrically conductive organic polymer laminate.

5. An improved rechargeable lithium battery as claimed in claim 1, wherein said resistivity switch temperature Trs is at least 50°

below the melting temperature of said electrically conductive organic polymer laminate.

6. An improved rechargeable lithium battery as claimed in claim 1, wherein said electrically conductive particles are selected from the group consisting of fine carbon and carbon black and said electrically conductive particles have size less than 0.1 μ

m.

7. An improved rechargeable lithium battery as claimed in claim 1, wherein said electrically conductive organic polymer laminate has thickness between 4 and 50 μ

m.

8. An improved rechargeable lithium battery as claimed in claim 1, wherein said electrically conductive polymer laminate comprises at least one of the group consisting of polyethylene, copolymers of ethylene and ethyl acrylate, copolymers of ethylene and acrylic acid, polyolefins, polyethers, fluorinated ethylene-propylene copolymers, polyvinylidene fluoride, mixtures of polyethylene and a copolymer of ethylene and ethyl acrylate, and mixtures of polyethylene and a copolymer of ethylene and acrylic acid.

9. An improved rechargeable lithium battery as claimed in claim 8, wherein said electrically conductive polymer comprises electrically conductive particles selected from the group consisting of fine carbon, and carbon black in less than 15 vol. %.

10. An improved rechargeable lithium battery as claimed in claim 2, wherein said electrode-active substance is selected from the group consisting of a positive active substance and a negative active substance.

11. An improved rechargeable lithium battery as claimed in claim 1, wherein said composite electrode is a composite negative electrode and said negative electrode included in said composite negative electrode is a lithium metal or a lithium alloy foil.

12. An improved rechargeable lithium battery as claimed in claim 1, wherein said metallic current collector sheet has two opposing faces and each face is in contact with an electrically conductive organic polymer laminate.

13. An improved rechargeable lithium battery as claimed in claim 2, wherein said coherent electrode layer has opposing faces, one face of said coherent electrode layer being in contact with said electrically conductive organic polymer laminate, and the other face of said coherent electrode layer is bearing a lithium ion containing adhesive coating.

14. A rechargeable lithium battery comprising:

i) a first metallic current collector;

ii) a composite positive electrode comprising a first organic polymer laminate rendered electrically conductive by embedded electrically conductive particles, said first electrically conductive organic polymer laminate having a first thickness and a first pair of faces, said first thickness and said first pair of faces defining a first total volume, wherein said first electrically conductive organic polymer laminate has a positive temperature coefficient of resistivity, a resistivity switch temperature T_rs, between 75 and 120°

C., said first electrically conductive organic polymer laminate being capable of reversible resistivity change of at least 2 orders of magnitude within a 5°

temperature band of said T_rs, and wherein said first electrically conductive organic polymer is capable of having said reversible resistivity change in a portion of said first total volume of said first electrically conductive organic polymer laminate, one of said first pair of faces being in contact with said first metallic current collector, and the other of said first pair of faces of said first electrically conductive organic polymer laminate being in contact with a positive electrode further comprising a positive active substance, thereby forming a composite positive electrode including a positive electrode and a metallic current collector;

iii) a non-aqueous lithium ion conducting electrolyte having a third pair of faces; and

iv) a composite negative electrode comprising a second organic polymer laminate rendered electrically conductive by embedded electrically conductive particles, said second electrically conductive organic polymer laminate having a second thickness and a second pair of faces, said second thickness and said second pair of faces defining a second total volume, wherein said second electrically conductive organic polymer laminate has a positive temperature coefficient of resistivity, a resistivity switch temperature T_rs, between 75 and 120°

C., said second electrically conductive organic polymer laminate being capable of reversible resistivity change of at least 2 orders of magnitude within a 5°

temperature band of said T_rs, and wherein said second electrically conductive organic polymer is capable of having said reversible resistivity change in a portion of said second total volume of said second electrically conductive organic polymer laminate, one of said second pair of faces of said second electrically conductive organic polymer laminate being in contact with a negative electrode comprising a negative active substance, and the other of said second pair of faces is in contact with a second metallic current collector, thereby forming a composite negative electrode including a negative electrode and a second metallic current collector.

15. A rechargeable lithium battery as claimed in claim 14, wherein a lithium ion containing adhesive coating is inserted between said composite negative electrode comprising said negative active substance, and one of said third pair of faces of said non-aqueous lithium ion conducting electrolyte.

16. A rechargeable lithium battery as claimed in claim 14, wherein a lithium ion containing adhesive coating is inserted between said composite positive electrode comprising said positive active substance, and the other of said third pair of faces of said non-aqueous lithium ion conducting electrolyte.

17. A rechargeable lithium battery as claimed in claim 14, wherein said first and said second electrically conductive organic polymer laminates have the same compositions and the same resistivity switch temperatures T_rs.