Low spin golf ball comprising silicone material

• US 6,162,134 A
• Filed: 02/11/1999
• Issued: 12/19/2000
• Est. Priority Date: 04/28/1993
• Status: Expired due to Term

• Current Assignee: Callaway Golf Company (Topgolf Callaway Brands Corp.)
• Original Assignee: Spalding Sports Worldwide, Inc. (Berkshire Hathaway Incorporated)
• Inventors: Sullivan, Michael J., Binette, Mark L., Nesbitt, R. Dennis
• Primary Examiner(s): Gerrity, Stephen F.
• Assistant Examiner(s): Kim, Paul D.
• Application Number:
  US09/248,626
• Time in Patent Office: 677 Days
• Field of Search: 473/354, 473/363, 473/364, 473/365, 473/373, 473/374, 473/375, 473/376, 473/377, 473/378
• US Class Current: 473/373
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0031 Hardness
• CPC Class Codes: A63B 37/0033 Thickness
• CPC Class Codes: A63B 37/0034 Deflection or compression
• CPC Class Codes: A63B 37/0045 Thickness
• CPC Class Codes: A63B 37/0065 Deflection or compression
• CPC Class Codes: A63B 37/008 Diameter
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 23/025 Copolymer of an unspecified olefin with a monomer other than an olefin
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 23/0876 Neutralised polymers, i.e. ionomers
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Abstract

The present invention is directed to a golf ball comprising a soft core and a hard cover to produce a golf ball having a reduced spin rate. The present invention is also directed to an improved golf ball comprising at least one interior layer and/or a core comprising a silicone material. It is preferred to also utilize a multi-layer cover in conjunction with the silicone materials. The golf ball of the present invention may also utilize an enlarged diameter which serves to further reduce spin rate. The resulting golf ball exhibits properties of reduced spin without sacrificing durability, playability and resilience.

Claims

1. A golf ball comprising:

a core having a Riehle compression of at least about 0.075;

a cover layer; and

at least one interior layer disposed between said core and said cover layer;

wherein at least one of said core and said at least one interior layer comprises a silicone material.

2. The golf ball of claim I wherein said cover layer comprises a high acid ionomer resin including a copolymer of greater than 16% by weight of an alpha, beta-unsaturated carboxylic acid.

3. A golf ball comprising:

a core;

a cover layer having a Shore D hardness of at least 65; and

at least one interior layer disposed between said core and said cover layer;

wherein at least one of said core and said at least one interior layer comprises a silicone material.

4. The golf ball of claim 3 wherein said cover layer comprises a high acid ionomer resin including a copolymer of greater than 16% by weight of an alpha, beta-unsaturated carboxylic acid.

5. A golf ball comprising:

a core having a Riehle compression of at least 0.075;

a cover layer having a Shore D hardness of at least 65, wherein said cover layer is comprised of at least one high acid ionomer resin comprising a copolymer of greater than 16% by weight of an alpha, beta-unsaturated carboxylic acid, and an alpha olefin of which about 10 to about 90% of the carboxyl groups of the copolymer are neutralized with a metal cation; and

at least one interior layer surrounding said core and disposed between said core and said cover layer;

wherein at least one of said core and said at least one interior layer comprises a silicone material selected from the group consisting of silicone polymers, silicone fluids, silicone elastomers, silicone resins, and combinations thereof.

6. The golf ball according to claim 5 wherein said silicone material is a silicone polymer.

7. The golf ball according to claim 5 wherein said silicone material is a silicone elastomer.

8. The golf ball according to claim 5 wherein said silicone material is a silicone resin.

9. The golf ball according to claim 5 wherein said cover layer comprises an inner cover layer molded on said at least one interior layer, and an outer cover layer molded on said inner cover layer.

10. The golf ball according to claim 5 wherein said interior layer has a thickness of about 0.100 to about 0.010 inches and said cover layer has a thickness of about 0.010 to about 0.05 inches, the golf ball having an overall diameter of 1.680 inches or more.

11. The golf ball according to claim 10 wherein said interior layer has a thickness of about 0.0375 inches and said cover layer has a thickness of about 0.0300 inches, the golf ball having an overall diameter of 1.680 inches or more.

12. The golf ball according to claim 5 wherein said silicone material, upon curing, has a Shore D hardness of from about 55 to about 100.

13. The golf ball according to claim 5 wherein said silicone material, upon curing, has a tensile strength of from about 300 psi to about 600 psi.

14. The golf ball according to claim 5 wherein said silicone material, upon curing, exhibits an elongation of from about 350% to about 650%.

15. The golf ball according to claim 5 wherein said cover is comprised of at least one high acid ionomer resin comprising a copolymer of about 17% to about 25% by weight of an alpha, beta-unsaturated carboxylic acid, and an alpha olefin of which about 10 to about 90% of the carboxyl groups of the copolymer are neutralized with a metal cation.

16. The golf ball according to claim 5 wherein said cover is comprised of at least one high acid ionomer resin comprising from about 18.5% to about 21.5% by weight of an alpha, beta-unsaturated carboxylic acid, and an alpha olefin of which about 10 to about 90% of the carboxyl groups of the copolymer are neutralized with a metal cation.

17. The golf ball according to claim 5 wherein said cover is comprised of polybutadiene, at least one metallic salt of an unsaturated carboxylic acid and a free radical initiator.

18. The golf ball according to claim 5 wherein said cover has a thickness greater than 0.0675 inches.

19. The golf ball according to claim 5 wherein said cover has a thickness ranging from about 0.0675 inches to about 0.130 inches.

20. The golf ball according to claim 5 wherein the golf ball has a diameter of about 1.680 to 1.800 inches.

21. A golf ball comprising:

a core comprising a silicone material, said core having a Riehle compression of at least 0.075;

an inner cover layer molded on said core;

an outer cover layer molded on said inner cover layer said outer cover having a Shore D hardness of at least 65, wherein said outer cover is comprised of at least one high acid ionomer resin comprising a copolymer of greater than 16% by weight of an alpha, beta-unsaturated carboxylic acid, and an alpha olefin of which about 10 to about 90% of the carboxyl groups of the copolymer are neutralized with a metal cation; and

at least one interior layer disposed between said core and said outer cover layer, said interior layer comprising a silicone material.

22. The golf ball according to claim 21 wherein said inner cover layer has a thickness of about 0.375 to about 0.010 inches and said outer cover layer has a thickness of about 0.010 to about 0.375 inches, the golf ball having an overall diameter of 1.680 inches or more.

23. The golf ball according to claim 22 wherein said inner cover layer has a thickness of about 0.030 to 0.375 inches and the outer cover layer has a thickness of about 0.030 to 0.375 inches, the golf ball having an overall diameter of 1.680 inches or more.

24. The golf ball according to claim 21 wherein the outer cover layer composition includes 90 to 10 percent by weight of a hard high modulus ionomer resin and about 10 to 90 percent by weight of a soft low modulus ionomer resin.

25. The golf ball according to claim 24 wherein the outer cover layer composition includes 75 to 25 percent by weight of the hard high modulus ionomer resin and about 25 to 75 percent by weight of the soft low modulus ionomer resin.

26. The golf ball according to claim 21 wherein said silicone material, upon curing, has a Shore D hardness of from about 55 to about 100.

27. The golf ball according to claim 21 wherein said silicone material, upon curing, has a tensile strength of from about 300 psi to about 600 psi.

28. The golf ball according to claim 21 wherein said silicone material, upon curing, exhibits an elongation of from about 350% to about 650%.