Method of coating and compositions for use therein

• US 6,162,511 A
• Filed: 11/19/1998
• Issued: 12/19/2000
• Est. Priority Date: 05/20/1996
• Status: Expired due to Fees

• Current Assignee: Ballina Pty Limited
• Original Assignee: Ballina Pty Limited
• Inventors: Garnett, John Lyndon, Matthews, Allan Darley
• Primary Examiner(s): PIANALTO, BERNARD D
• Application Number:
  US09/180,990
• Time in Patent Office: 761 Days
• Field of Search: 427/508, 427/514, 427/558, 427/559, 427/595, 427/299, 427/385.5, 106/285, 106/400, 252/600
• US Class Current: 427/514
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: C08F 290/06 Polymers provided for in subclass C08G
• CPC Class Codes: C09D 4/06 Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials

Abstract

A method of preparing a coated substrate comprising: providing a radiation curable composition comprising a resin component including an unsaturated monomer and an unsaturated oligomer, binder or mixture of oligomer and binder; applying the radiation curable composition at a temperature in the range of from 35 to 150° C. to the substrate; and subjecting the applied coating to radiation to thereby cure the coating. The invention also provides a composition for application of pigmented finishes and a method of coating in which a radiation curable composition is applied to a wet substrate.

Claims

1. A method of preparing a coated substrate comprising:

providing a radiation curable coating composition comprising a resin component including an unsaturated monomer and at least one of an unsaturated oligomer, binder or mixture thereof,

a pigment and optionally a filler wherein the total of pigments and filler constitutes at least 10 parts by weight based on 100 parts by weight of resin component;

heating the radiation curable coating composition to provide a hot coating composition of temperature of from 35 to 150°

C.;

applying the hot radiation curable composition to the surface of the substrate at a temperature in the range of from 35 to 150°

C. to the substrate; and

subjecting the applied radiation curable coating to radiation to thereby cure the coating.

2. A method according to claim 1 wherein the radiation curable coating composition is heated to a temperature in the range of from 50 to 120°

C.

3. A method according to claim 1 wherein the radiation is ultraviolet light radiation.

4. A method according to claim 1 wherein the radiation curable coating composition comprises a pigment or filler present in an amount such that the total filler and pigment constitutes at least 40 parts by weight based on 100 parts by weight of the resin component.

5. A method according to claim 4 wherein the radiation curable coating composition comprises a photoinitiator component comprising a combination of an acyl phosphine oxide initiator and an α

-hydroxy-α

,α

-di-substituted acetophenone initiator.

6. A method according to claim 5 wherein photoinitiator component comprises a mixture of 1-hydroxycyclohexylphenylketone and bis-(2,6-dimethyloxybenzoyl)-2,4,4-trimethylpentyl phosphine oxide in a weight ratio of from 10:

1 to 1;

10.

7. A method according to claim 4 wherein the radiation curable coating composition comprises a photoinitiator in an amount of from 0.1 to 60 parts by weight based on 100 parts by weight of resin.

8. A method according to claim 1 wherein the radiation curable coating composition comprises a urethane acrylate prepolymer;

from 50 to 1000 by weight of pigments and/or fillers and water in an amount of from 5 to 100 parts by weight based on 100 by weight of resin component.

9. A method according to claim 1 wherein the radiation curable coating composition is applied to a wet substrate.

10. A method according to claim 9 wherein the substrate is selected from cementitious products and cellulose fibre products.

11. A method according to claim 1 wherein the substrate is recycled paper and the coating comprises in the range of from 40 parts to 200 parts of the total of filler and pigment.

12. A method according to claim 1 wherein the substrate is styrene polymer product and said radiation curable coating is applied to the polymer product which is hot as a result of heat generated during polymerization to form the product.

13. A method according to claim 12 wherein the radiation curable coating is applied to the styrene polymer product when said product is at a temperature in the range of from 50 to 150°

C.

22. A method according to claim 1 wherein the radiation curable coating comprises at least 10 parts of pigment base on 100 parts by weight of resin component.

14. A radiation curable coating composition comprising:

a resin component comprising a monomer and at least one of a prepolymer and a binder polymer, a pigment and optionally a filler present in an amount of at least 40 parts by weight of the total of pigment and filler per 100 parts by weight of resin component;

and a photoinitiator component comprising a combination of an acyl phosphine oxide initiator and an α

-hydroxy-α

,α

-di-substituted acetophenone initiator.

15. A radiation curable coating composition according to claim 14 wherein the composition comprises in the range of from 50 to 200 parts of the total of fillers and pigments by weight based on 100 parts by weight of resin component.

16. A radiation curable coating composition according to claim 14 wherein the weight ratio of acyl phosphine oxide to a α

-hydroxy-α

,α

-di-substituted acetophenone initiator is in the range of from 1;

10 to 10;

1.

17. A radiation curable coating composition according to claim 14 wherein the acyl phosphine oxide is bis-(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentyl phosphine oxide and the α

-hydroxy-α

,α

-di-substituted acetophenone is 1-hydroxycyclohexyl phenyl ketone.

18. A radiation curable coating composition according to claim 14 wherein the resin composition comprises a monomer component comprising one or more compounds comprising a plurality of acrylite or methacrylate functional groups and the prepolymer component comprising an aliphatic or aromatic urethane acrylate.

19. A method of coating a substrate comprising:

providing a radiation curable coating composition comprising a monomer and a prepolymer or binder;

providing a water-wettable substrate having a surface which has been wet with water;

applying the radiation curable composition to the wet surface; and

curing the coating by application of radiation.

20. A method according to claim 19 wherein the substrate is selected from cementitious products and cellulosic products.

21. A method according to claim 19 wherein the substrate is reinforced cement board.