Gas barrier composition and molded resin

• US 6,162,892 A
• Filed: 09/28/1999
• Issued: 12/19/2000
• Est. Priority Date: 09/30/1998
• Status: Expired due to Fees

• Current Assignee: Dow Corning Toray Silicone Company Limited (Dow, Inc.)
• Original Assignee: Dow Corning Toray Silicone Company Limited (Dow, Inc.)
• Inventors: Hayashi, Masayuki, Kobayashi, Hideki
• Primary Examiner(s): HAMPTON HIGHTOWER, PATRICIA
• Application Number:
  US09/407,499
• Time in Patent Office: 448 Days
• Field of Search: 528/10, 528/38, 528/60, 528/26, 528/44, 528/220, 528/229, 528/86, 528/87, 528/125, 528/403, 528/310, 428/441.1
• US Class Current: 528/310
• CPC Class Codes: C08G 18/3893 containing silicon
• CPC Class Codes: C08G 59/4085 silicon containing compounds
• CPC Class Codes: C08G 59/504 containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]

Abstract

The invention relates to a gas barrier composition as well as to composite structures having at least one surface of a molded resin coated with the composition, said composition comprising:

(A) an alkoxysilyl functional polyamine compound, or a hydrolyzate thereof, said polyamine compound having three or more amine groups, at least one nitrogen atom of said amine groups being bonded to a hydrogen atom and at least one nitrogen of said amine groups being bonded to an alkoxysilyl group expressed by the formula

--W--SiR.sup.2.sub.3-f (OR.sup.1).sub.f

wherein R¹ is an alkyl group having 1 to 6 carbon atoms, R² is a monovalent hydrocarbon group having 1 to 10 carbon atoms, W is a divalent hydrocarbon group having 2 to 10 carbon atoms, and f is an integer having a value of 1 to 3; and

(B) an organic compound which is free of acrylic groups, said organic compound having an aromatic ring or an alicyclic hydrocarbon group and having per molecule at least two functional groups that are reactive with the amine groups, the alkoxy groups, or both, of component A.

Claims

1. A gas barrier composition comprising:

(A) an alkoxysilyl functional polyamine compound, or a hydrolyzate thereof, said polyamine compound having three or more amine groups, at least one nitrogen atom of said amine groups being bonded to a hydrogen atom and at least one nitrogen of said amine groups being bonded to an alkoxysilyl group expressed by the formula

space="preserve" listing-type="equation">--W--SiR.sup.2.sub.3-f (OR.sup.1).sub.f

wherein R¹ is an alkyl group having 1 to 6 carbon atoms, R² is a monovalent hydrocarbon group having 1 to 10 carbon atoms, W is a divalent hydrocarbon group having 2 to 10 carbon atoms, and f is an integer having a value of 1 to 3; and

(B) an organic compound which is free of acrylic groups, said organic compound having an aromatic ring or an alicyclic hydrocarbon group and having per molecule at least two functional groups that are reactive with the amine groups, the alkoxy groups, or both, of component A.

2. A gas barrier composition according to claim 1, wherein said alkoxysilyl functional polyamine compound (A) is expressed by a formula selected from ##STR7## wherein R is selected from hydrogen or a monovalent organic group, Q is a divalent hydrocarbon group having 2 to 6 carbon atoms, and a, b, and c are integers, each having a value of at least 1, with the proviso that at least one R group is hydrogen and at least one R group is an alkoxysilyl group expressed by the formula

3. A gas barrier composition according to claim 1, wherein the hydrolyzate of component A is a co-hydrolyzate with an alkoxysilane expressed by the formula R³ _4-g Si(OR⁴)_g in which R³ is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, R⁴ is an alkyl group with 1 to 6 carbon atoms, and g is an integer having a value of 1 to 4.

4. A gas barrier composition according to claim 2, wherein the hydrolyzate of component A is a co-hydrolyzate with an alkoxysilane expressed by the formula R³_4-g Si(OR⁴)_g in which R³ is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, R⁴ is an alkyl group with 1 to 6 carbon atoms, and g is an integer having a value of 1 to 4.

5. A gas barrier composition according to claim 1, wherein said compound B has at least two groups selected from epoxy groups or isocyanate groups per molecule.

6. A gas barrier composition according to claim 2, wherein said compound B has at least two groups selected from epoxy groups or isocyanate groups per molecule.

7. A gas barrier composition according to claim 3, wherein said compound B has at least two groups selected from epoxy groups or isocyanate groups per molecule.

8. A gas barrier composition according to claim 4, wherein said compound B has at least two groups selected from epoxy groups or isocyanate groups per molecule.

9. A molded resin having a coating of the gas barrier composition according to claim 1 coated on at least one side thereof.

10. A molded resin having a coating of the gas barrier composition according to claim 2 coated on at least one side thereof.

11. A molded resin having a coating of the gas barrier composition according to claim 3 coated on at least one side thereof.

12. A molded resin having a coating of the gas barrier composition according to claim 4 coated on at least one side thereof.

13. A molded resin having a coating of the gas barrier composition according to claim 5 coated on at least one side thereof.

14. A molded resin having a coating of the gas barrier composition according to claim 6 coated on at least one side thereof.

15. A composite having a layer of the gas barrier composition according to claim 1 laminated between molded resins.

16. A composite having a layer of the gas barrier composition according to claim 2 laminated between molded resins.

17. A composite having a layer of the gas barrier composition according to claim 3 laminated between molded resins.

18. A composite having a layer of the gas barrier composition according to claim 4 laminated between molded resins.

19. A composite having a layer of the gas barrier composition according to claim 5 laminated between molded resins.

20. A composite having a layer of the gas barrier composition according to claim 6 laminated between molded resins.