Nighttime solar cell

• US 6,162,985 A
• Filed: 07/22/1999
• Issued: 12/19/2000
• Est. Priority Date: 05/09/1997
• Status: Expired due to Term

• Current Assignee: Ronald J. Parise
• Original Assignee: Ronald J. Parise
• Inventors: Parise, Ronald J.
• Primary Examiner(s): Gorgos, Kathryn
• Assistant Examiner(s): Parsons, Thomas H
• Application Number:
  US09/359,108
• Time in Patent Office: 516 Days
• Field of Search: 136/201, 136/205, 136/206, 136/243, 136/246
• US Class Current: 136/201
• CPC Class Codes: H01M 10/443 in response to temperature
• CPC Class Codes: H01M 8/04007 related to heat exchange
• CPC Class Codes: H02S 10/10 including a supplementary source of electric power, e.g. hybrid diesel-PV energy systems combinations with gas-turbine plants F02C6/00
• CPC Class Codes: H10N 10/00 Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects integrated devices or assemblies of multiple devices H10N19/00
• CPC Class Codes: Y02E 10/50 Photovoltaic [PV] energy
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

This invention is a thermoelectric-photovoltaic device for converting electrical energy from both thermal radiation and sunlight. Thermoelectric energy is produced from thermoelectric cells when a temperature difference is present between two different semiconductor materials. Photovoltaic energy is produced from photovoltaic cells when two different semiconductor materials are exposed to sunlight. To achieve increased electrical energy production, one of the semiconductor materials is placed in a cell having a reduced pressure atmosphere to increase the radiative energy thermal exchange with the black sky at night.

Claims

1. An electricity generating device for use in an environment having an ambient pressure, using an electricity generating cell comprising:

a first junction surface disposed in contact with a first semiconductor material;

a second junction surface disposed in contact with a second semiconductor material;

a third junction surface disposed in contact with the first semiconductor material and the second semiconductor material;

the first and second junction surfaces disposed within a pressure cell having a pressure less than the ambient pressure; and

the first and second junction surfaces at a temperature different from the third surface junction producing a thermoelectric potential between the first and second junction surfaces.

2. An electricity generating device as set forth in claim 1, further comprising heat augmentation disposed in thermal communication with the third junction surface.

3. An electricity generating device as set forth in claim 1, wherein the first and second junction surfaces are at about the same temperature and the third junction surface at a greater temperature.

4. An electricity generating device as set forth in claim 1, wherein the first and second junction surfaces are at about the same temperature and the third junction surface is at a lesser temperature.

5. An electricity generating device as set forth in claim 1, wherein the first and second junction surfaces are at different temperatures.

6. An electricity generating device as set forth in claim 1, wherein

the electricity generating cell has a thermal resistivity;

the first semiconductor material is disposed in a distance between the first junction surface and the third junction surface; and

the first semiconductor material has a geometry which increases said thermal resistivity as compared to a second electricity generating cell having a first semiconductor material having a straight geometry which spans a substantially equivalent distance.

7. An electricity generating device as set forth in claim 6, wherein said geometry is curved, coiled, snaking, or a combination thereof.

8. An electricity generating device as set forth in claim 6, further comprising at least one first film insulator disposed adjacent to and in contact with said first semiconductor material.

9. An electricity generating device as set forth in claim 8, further comprising at at least one second film insulator disposed adjacent to and in contact with said second semiconductor material.

10. An electricity generating device as set forth in claim 1, further comprising a plurality of first semiconductor materials and a plurality of second semiconductor materials oriented in a cascading arrangement.

11. An electricity generating device as set forth in claim 10, further comprising thermal conductors connecting successive rows of said first semiconductor materials and said second semiconductor materials.

12. An electricity generating device as set forth in claim 11, wherein said thermal conductors are metallic materials or semiconductor materials.

13. An electricity generating device as set forth in claim 1, wherein said first semiconductor material is oriented at a first angle between said first surface junction and said third surface junction, and said second semiconductor material is oriented at a second angle between said second surface junction and said third surface junction;

and wherein said first and second angles are 30°

, 45°

, 60°

, 90°

, or 180°

.

14. An electricity generating device as set forth in claim 1, wherein said first material has a length and a cross-sectional area, wherein said length is greater than said cross-sectional area.

15. An electricity generating device as set forth in claim 14, wherein a ratio of said length to said cross-sectional area is at least about 4.

16. An electricity generating device as set forth in claim 14, wherein a ratio of said length to said cross-sectional area is at least about 5.

17. An electricity generating device as set forth in claim 14, further comprising a mechanical support disposed between said first surface junction and said third surface junction.

18. An electricity generating device as set forth in claim 17, further comprising a mechanical support disposed between said second surface junction and said third surface junction.

19. An electricity generating device as set forth in claim 1, wherein said first semiconductor material and said second semiconductor material are disposed within said pressure cell.

20. An electricity generating device as set forth in claim 19, wherein said third junction surface is disposed within said pressure cell.

21. An electricity generating device as set forth in claim 20, further comprising first heat augmentation disposed in thermal communication with the third junction surface.

22. An electricity generating device as set forth in claim 21, further comprising second heat augmentation disposed in thermal communication with said pressure cell.

23. An electricity generating device as set forth in claim 19, further comprising

the thermoelectric potential having an electrical current;

the first and second junction surfaces electrically connected such that the current flows to a current flow direction circuitry;

the current flow direction circuitry operable to detect the direction of the current;

the current flow direction circuitry further operable to orient the direction of an output current; and

the current flow circuitry electrically connected to a load.

24. An electricity generating device as set forth in claim 1, further comprising

the thermoelectric potential having an electrical current;

the first and second junction surfaces electrically connected such that the current flows to a current flow direction circuitry;

the current flow direction circuitry operable to detect the direction of the current;

the current flow direction circuitry further operable to orient the direction of an output current; and

the current flow circuitry electrically connected to a load.

25. An electricity generating device as set forth in claim 1, further comprising a mechanical support disposed between said first junction surface and said third junction surface.

26. An electricity generating device as set forth in claim 1, further comprising heat augmentation disposed in thermal communication with said pressure cell.

27. An electricity generating device as set forth in claim 26, wherein said heat augmentation is a finned heat exchanger, fluid heat exchange, baffled heat exchanger, radiation shield, heat transfer composition, or a combination thereof.

28. An electricity generating device as set forth in claim 1, further comprising heat augmentation disposed in thermal communication with the first junction surface.

29. An electricity generating device as set forth in claim 1, further comprising a heat exchanger disposed in heat exchange communication with the second junction surface.

30. An electricity generating device as set forth in claim 1, further comprising a first radiation heat transfer area disposed in thermal communication with said first junction surface.

31. An electricity generating device as set forth in claim 30, wherein said radiation heat transfer area is disposed in thermal communication with said second junction surface.

32. An electricity generating device as set forth in claim 1, further comprising a plurality of electricity generating cells electrically connected together.

33. An electricity generating device as set forth in claim 32, wherein the first and second junction surfaces of said plurality of electricity generating cells is at least partially disposed within a single pressure cell.

34. An electricity generating device as set forth in claim 32, wherein each of the electricity generating cells is at least partially disposed within separate pressure cells.

35. An electricity generating device as set forth in claim 32, wherein the plurality of electricity generating cells are connected in series fashion.

36. An electricity generating device as set forth in claim 32, wherein the plurality of electricity generating cells are connected in parallel fashion.

37. An electricity generating device as set forth in claim 1, further comprising a photovoltaic cell disposed within the electricity generating cell, the photovoltaic cell comprising a third semiconductor material and a fourth semiconductor material, the third and fourth semiconductor materials converting sunlight to electrical energy.

38. An electricity generating device as set forth in claim 37, wherein the fourth semiconductor material is the first semiconductor material.

39. An electricity generating device as set forth in claim 37, wherein the photovoltaic cell includes a light concentrating device for focusing sunlight onto the third and fourth semiconductor materials.

40. An electricity generating device as set forth in claim 37, further comprising a plurality of electricity generating cells and a plurality of photovoltaic cells electrically connected together.

41. An electricity generating device as set forth in claim 40, wherein the first and second junction surfaces of said plurality of electricity generating cells are disposed within a single pressure cell.

42. An electricity generating device as set forth in claim 40, wherein the first and second junction surfaces of each of said plurality of electricity generating cells are disposed within separate pressure cells.

43. An electricity generating device as set forth in claim 40, wherein the plurality of electricity generating cells are connected in series fashion to said plurality of photovoltaic cells.

44. An electricity generating device as set forth in claim 40, wherein the plurality of electricity generating cells are connected in parallel fashion to said plurality of photovoltaic cells.

45. An electricity generating device as set forth in claim 37, wherein the first semiconductor material, second semiconductor material, third semiconductor material, and fourth semiconductor material are chosen based upon the thermal characteristics of that portion of the device.

46. An electricity generating device as set forth in claim 37, wherein the electricity generating cell is connected in series fashion to the photovoltaic cell.

47. An electricity generating device as set forth in claim 37, wherein the electricity generating cell is connected in parallel fashion to the photovoltaic cell.

48. An electricity generating device as set forth in claim 1, wherein at least a portion of said pressure cell is capable of transmitting sunlight to the photovoltaic cell.

49. An electricity generating device as set forth in claim 48, wherein the portion of said pressure cell capable of transmitting sunlight has a reflectivity coating.

50. An electricity generating device as set forth in claim 1, wherein said first material has a length and a cross-sectional area, wherein said length is greater than said cross-sectional area.

51. An electricity generating device as set forth in claim 50, wherein a ratio of said length to said cross-sectional area is at least about 4.

52. An electricity generating device as set forth in claim 50, wherein a ratio of said length to said cross-sectional area is at least about 5.

53. An electricity generating device as set forth in claim 50, further comprising a mechanical support disposed between said first surface junction and said third surface junction.

54. An electricity generating device as set forth in claim 53, further comprising a mechanical support disposed between said second surface junction and said third surface junction.

55. An electricity generating device as set forth in claim 50, further comprising

the thermoelectric potential having an electrical current;

the first and second junction surfaces electrically connected such that the current flows to a current flow direction circuitry;

the current flow direction circuitry operable to detect the direction of the current;

the current flow direction circuitry further operable to orient the direction of an output current; and

the current flow circuitry electrically connected to a load.

56. An electricity generating device as set forth in claim 1, further comprising a photovoltaic cell disposed within the electricity generating cell, the photovoltaic cell comprising a third semiconductor material and a fourth semiconductor material, the third and fourth semiconductor materials converting sunlight to electrical energy.

57. An electricity generating device as set forth in claim 56, wherein the photovoltaic cell includes a light concentrating device for focusing sunlight onto the third and the fourth semiconductor materials.

58. An electricity generating device as set forth in claim 56, wherein the fourth semiconductor material is the first semiconductor material.

59. An electricity generating device as set forth in claim 56, further comprising a plurality of electricity generating cells and a plurality of photovoltaic cells electrically connected together.

60. An electricity generating device as set forth in claim 59, wherein the plurality of electricity generating cells are connected in parallel fashion to said plurality of photovoltaic cells.

61. An electricity generating device as set forth in claim 56, wherein the first semiconductor material, second semiconductor material, third semiconductor material, and fourth semiconductor material are chosen based upon the thermal characteristics of that portion of the device.

62. An electricity generating device as set forth in claim 56, wherein the electricity generating cell is connected in parallel fashion to the photovoltaic cell.

63. An electricity generating device using an electricity generating cell having a thermal resistivity, comprising:

a first junction surface disposed in contact with a first semiconductor material;

a second junction surface disposed in contact with a second semiconductor material;

a third junction surface disposed in contact with the first semiconductor material and the second semiconductor material;

the first and second junction surfaces at a temperature different from the third surface junction producing a thermoelectric potential between the first and second junction surfaces;

the first semiconductor material is disposed in a distance between the first junction surface and the third junction surface; and

the first semiconductor material has a geometry which increases said thermal resistivity as compared to a second electricity generating cell having a first semiconductor material having a straight geometry which spans a substantially equivalent distance.

64. An electricity generating device as set forth in claim 63, wherein the first and second junction surfaces are at about the same temperature and the third junction surface at a greater temperature.

65. An electricity generating device as set forth in claim 63, wherein the first and second junction surfaces are at about the same temperature and the third junction surface is at a lesser temperature.

66. An electricity generating device as set forth in claim 63, wherein the first and second junction surfaces are at different temperatures.

67. An electricity generating device as set forth in claim 63, wherein said geometry is curved, coiled, snaking, or a combination thereof.

68. An electricity generating device as set forth in claim 67, further comprising at least one first film insulator disposed adjacent to and in contact with said first semiconductor material.

69. An electricity generating device as set forth in claim 68, further comprising at least one second film insulator disposed adjacent to and in contact with said second semiconductor material.

70. An electricity generating device as set forth in claim 63, further comprising a plurality of first semiconductor materials and a plurality of second semiconductor materials oriented in a cascading arrangement.

71. An electricity generating device as set forth in claim 70, further comprising thermal conductors connecting successive rows of said first materials and said second materials.

72. An electricity generating device as set forth in claim 71, wherein said thermal conductors are metallic materials or semiconductor materials.

73. An electricity generating device as set forth in claim 63, wherein said first semiconductor material is oriented at a first angle between said first surface junction and said third surface junction, and said second semiconductor material is oriented at a second angle between said second surface junction and said third surface junction;

and wherein said first and second angles are 30°

, 45°

, 60°

, 90°

, or 180°

.

74. An electricity generating device as set forth in claim 63, further comprising

the thermoelectric potential having an electrical current;

the first and second junction surfaces electrically connected such that the current flows to a current flow direction circuitry;

the current flow direction circuitry operable to detect the direction of the current;

the current flow direction circuitry further operable to orient the direction of an output current; and

the current flow circuitry electrically connected to a load.

75. An electricity generating device as set forth in claim 63, further comprising a mechanical support disposed between said first junction surface and said third junction surface.

76. An electricity generating device as set forth in claim 63, further comprising heat augmentation disposed in thermal communication with said electricity generating cell.

77. An electricity generating device as set forth in claim 76, wherein said heat exchanger is a finned heat exchanger, fluid heat exchange, baffled heat exchanger, radiation shield, heat transfer composition, or a combination thereof.

78. An electricity generating device as set forth in claim 76, further comprising heat augmentation disposed in thermal communication with the first junction surface.

79. An electricity generating device as set forth in claim 78, further comprising heat augmentation disposed in heat exchange communication with the second junction surface.

80. An electricity generating device as set forth in claim 63, further comprising a first radiation heat transfer area disposed in thermal communication with said first junction surface.

81. An electricity generating device as set forth in claim 63, further comprising a second radiation heat transfer area disposed in contact with said second junction surface.

82. An electricity generating device as set forth in claim 63, further comprising a plurality of electricity generating cells electrically connected together.

83. An electricity generating device as set forth in claim 81, wherein the plurality of electricity generating cells are connected in parallel fashion.

84. A method of converting thermal radiation and sunlight into electrical energy utilizing a device having a full sunlight exposure position, a partial sunlight exposure position, and a full shade position, comprising:

forming the device by electrically connecting, in a parallel fashion, at least one electricity generating cell with at least one photovoltaic cell;

producing electrical energy from both the photovoltaic cell and the electricity generating cell in the full sunlight exposure position; and

producing energy from the electricity generating cell in the full shade position.

85. A method of converting thermal radiation and sunlight into electrical energy as set forth in claim 84, further comprising positioning the device in a low orbit about the earth.

86. A method of converting thermal radiation and sunlight into electrical energy as set forth in claim 84, further comprising positioning the device in a terrestrial setting.

87. A method of converting thermal radiation and sunlight into electrical energy as set forth in claim 84, wherein the electricity generating cell comprises a first junction surface disposed in contact with a first semiconductor material, a second junction surface disposed in contact with a second semiconductor material, a third junction surface disposed in contact with the first semiconductor material and the second semiconductor material, the first and second junction surfaces at a temperature different from the third surface junction producing a thermoelectric potential between the first and second junction surfaces, and the first and second junction surfaces are disposed within a pressure cell having a pressure less than the ambient pressure.

88. A method of converting thermal radiation and sunlight into electrical energy as set forth in claim 84, wherein said device is a thermoelectric-photovoltaic array, the array comprising a plurality of electricity generating cells connected electrically, in a parallel fashion, with a plurality of photovoltaic cells.

89. A method of converting thermal radiation and sunlight into electrical energy as set forth in claim 88, further comprising producing electrical energy from a portion of the photovoltaic cells and from the electricity generating cells in the partial sunlight exposure position.

90. A method of converting thermal radiation and sunlight into electrical energy as set forth in claim 84, further comprising orienting the device such that the thermoelectric cell and the photovoltaic cell are in a perpendicular arrangement with the sunlight throughout the orbit.

91. A method of converting thermal radiation into electrical energy, comprising:

utilizing an energy generating device comprising a first junction surface disposed in contact with a first semiconductor material;

a second junction surface disposed in contact with a second semiconductor material;

a third junction surface disposed in contact with the first semiconductor material and the second semiconductor material;

the first and second junction surfaces at a temperature different from the third surface junction producing a thermoelectric potential between the first and second junction surfaces;

the first semiconductor material is disposed in a distance between the first junction surface and the third junction surface; and

the first semiconductor material has a geometry which increases said thermal resistivity as compared to a second electricity generating cell having a first semiconductor material having a straight geometry which spans a substantially equivalent distance; and

producing electrical energy.

92. A method of converting thermal radiation into electrical energy as set forth in claim 91, further comprising positioning the device in a low orbit about the earth.

93. A method of converting thermal radiation into electrical energy as set forth in claim 91, further comprising positioning the device in a terrestrial setting.

94. A method of converting thermal radiation into electrical energy as set forth in claim 91, wherein said device is a thermoelectric array, the array comprising a plurality of electricity generating cells connected electrically, in a parallel fashion.

95. A method of converting thermal radiation into electrical energy as set forth in claim 91, further comprising using space as a cold sink.

96. A method of converting thermal radiation into electrical energy, comprising:

utilizing an electricity generating cell comprising a first junction surface disposed in contact with a first semiconductor material, a second junction surface disposed in contact with a second semiconductor material, a third junction surface disposed in contact with the first semiconductor material and the second semiconductor material, the first and second junction surfaces at a temperature different from the third surface junction producing a thermoelectric potential between the first and second junction surfaces, and the first and second junction surfaces are disposed within a pressure cell having a pressure less than the ambient pressure; and

producing electrical energy.

97. A method of converting thermal radiation into electrical energy as set forth in claim 96, wherein said device is a thermoelectric array, the array comprising a plurality of electricity generating cells connected electrically, in a parallel fashion.

98. A method of converting thermal radiation into electrical energy as set forth in claim 96, further comprising using space as a cold sink.