Photocatalytically hydrophilifiable coating composition

• US 6,165,256 A
• Filed: 01/15/1999
• Issued: 12/26/2000
• Est. Priority Date: 07/19/1996
• Status: Expired due to Term

• Current Assignee: Toto Limited
• Original Assignee: Toto Limited
• Inventors: Hayakawa, Makoto, Kanno, Mitsuyoshi
• Primary Examiner(s): BRUNSMAN, DAVID M
• Application Number:
  US09/232,494
• Time in Patent Office: 711 Days
• Field of Search: 106/13, 106/286.1, 106/286.3, 106/286.4, 106/287.1, 106/287.13, 106/287.14, 106/287.16, 106/287.18, 106/287.19, 106/287.34
• US Class Current: 106/13
• CPC Class Codes: B01J 31/0272 containing elements other than those covered by B01J31/0201 - B01J31/0255
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: B01J 37/0219 the coating containing organic compounds
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 2217/45 Inorganic continuous phases
• CPC Class Codes: C03C 2217/477 Titanium oxide
• CPC Class Codes: C03C 2217/478 Silica
• CPC Class Codes: C03C 2217/71 Photocatalytic coatings
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C09D 1/00 Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
• CPC Class Codes: C09D 183/02 Polysilicates
• CPC Class Codes: C09D 183/04 Polysiloxanes
• CPC Class Codes: C09D 5/00 Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced electrically insulating plastics, resins or waxes H01B3/30; Filling pastes
• CPC Class Codes: C09D 5/021 Aerosols aerosol compositions C09K3/30

Abstract

A composition is disclosed which can hydrophilify the surface of a member to impart an antifogging property to the surface of the member. The composition for hydrophilifying the surface of the member comprises at least (a) photocatalytic particles of a metallic oxide, (b) a precursor capable of forming a silicone resin film or a precursor capable of forming a silica film, and (c) a solvent, the total content of the photocatalytic particle and the solid matter of the precursor in the composition being 0.01 to 5% by weight. The hydrophilic property can be imparted simply by applying the composition onto a member and drying or heating the composition applied to the member. The resultant hydrophilic thin film is transparent and, hence, does not sacrifice the transparency and appearance of a member required to be transparent. Further, the surface of a member with the above composition applied thereto has such a property that water droplets adhered thereon can be immediately removed by vaporization and the surface is less likely to be soiled and, even when a contaminant is adhered thereon, can easily release the contaminant therefrom.

Claims

1. A composition for hydrophilifying the surface of a member, comprising at least

(a) photocatalytic particles of a metallic oxide,

(b) a silicon-based component selected from the group consisting of silica fine particles, a precursor capable of forming a silica film and combinations thereof, and

(c) a solvent,

wherein the total content of the photocatalytic particles and the silicon in the silicon-based component in the composition is 0.01 to 1% by weight.

2. The composition according to claim 1, which, when applied to the surface of a member, has, upon application of light on the surface of the member, a hydrophilicity of not more than 10°

in terms of the contact angle of the surface with water.

3. The composition according to claim 2, wherein the contact angle of the surface with water is 5°

.

4. The composition according to any one of claims 1 to 3, wherein the average crystallite diameter of the photocatalytic particles is 100 nm or less.

5. The composition according to any one of claims 1 to 3, wherein the photocatalytic particles are constituted by the anatase form of titanium oxide.

6. The composition according to any one of claims 1 to 3, which further comprises a material having a refractive index of not more than 2.

7. The composition according to any one of claims 1 to 3, wherein the solvent is an alcohol.

8. The composition according to any one of claims 1 to 3, which further comprises a surfactant.

9. The composition according to claim 8, wherein the content of the surfactant is less than 10 parts by weight based on one part by weight of the photocatalytic particle.

10. The composition according to claim 9, wherein the content of the surfactant is 0.4 to 2 parts by weight based on one part by weight of the photocatalytic particle.

11. The composition according to any one of claims 1 to 3, which further comprises an acid.

12. The composition according to any one of claims 1 to 3, which further comprises an antibacterial metal or a compound thereof.

13. The composition according to any one of claims 1 to 3, which further comprises at least one metal selected from the group consisting of platinum, palladium, rhodium, ruthenium, osmium, and iridium.

14. The composition according to any one of claims 1 to 3, wherein the photocatalytic oxide is selected from the group consisting of anatase form of titanium oxide, rutile form of titanium oxide, zinc oxide, tin oxide, ferric oxide, dibismuth trioxide, tungsten trioxide, and strontium titanate.

15. The composition according to claim 14, which, when applied to the surface of a member, imparts an antifogging property to the surface of the member.

16. The composition according to claim 14, which, when applied to the surface of a member to form a film, permits condensed water of moisture and/or water droplets adhered onto the surface to be spread on the film, thereby enabling the film to prevent the surface from being fogged or clouded by the condensed water of moisture and/or the water droplets.

17. The composition according to claim 14, which, when applied to the surface of a member to form a film, enables a contaminant adhered onto the surface to be easily washed away by water.

18. An aerosol composition comprising the composition according to any one of claims 1 to 3, and a propellant.

19. A method for hydrophilifying the surface of a member, comprising the steps of:

applying the composition according to any one of claims 1 to 3 onto the surface of a member; and

drying or curing the composition.

20. A member, having a hydrophilified surface, produced by the method according to claim 19.

21. The method according to claim 19, wherein the member is transparent and the member thus obtained is also transparent.

22. The composition according to any one of claims 1 to 3, wherein the precursor of a silica film is selected from the group consisting of tetramethoxysilane, tetraethoxysilane, tetrapropoxysilane, tetrabutoxysilane, diethoxydimethoxysilane, tetrachlorosilane, tetrabromosilane, silanol, and dimethoxydiethoxysilane, and partial hydrolyzates and dehydropolycondensation products of the tetrafunctional hydrolyzable derivatives thereof.