Electrochromic metal oxides

• US 6,165,388 A
• Filed: 02/24/1999
• Issued: 12/26/2000
• Est. Priority Date: 12/26/1995
• Status: Expired due to Fees

• Current Assignee: Monsanto Company (Bayer AG)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Coleman, James Patrick
• Primary Examiner(s): KOPEC, MARK T
• Application Number:
  US09/257,156
• Time in Patent Office: 671 Days
• Field of Search: 252/500, 252/518.1, 252/520.1, 252/521.5, 359/273, 204/901, 345/105
• US Class Current: 252/520.1
• CPC Class Codes: C09K 9/00 Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: G02F 1/1523 comprising inorganic material
• CPC Class Codes: H01B 1/08 oxides

Abstract

Tin oxide doped with an electrochemically effective amount of a metal, e.g., antimony or niobium, which provides a color change when the doped tin oxide is exposed to an electrochemical potential in the presence of mobile ions. Particles of electrochromic doped tin oxide, e.g., coated on a white or pastel pigment substrate, have a contrast ratio greater than 1.2, where contrast ratio is a measure of electrochromic functionality of a material and is the ratio of reflectance of the material in an oxidized state to the color of the material in a reduced state and where color is a photodiode measurement of the value of light reflected off the oxidized or reduced material from a constant source of light shining on the material. Such doped tin oxide-containing particles are useful as electrochromic material in display devices, and may be employed in display devices that advantageously exhibit a linear or nearly linear relationship between stored electrical charge and voltage, and which also exhibit linear or nearly linear optical characteristics as a function of voltage. Electrochromically active materials made from metal oxides and doped with substances other than antimony and niobium have also been found with high contrast ratios. These additional doped materials may be substituted for electrochromically active antimony-doped tin oxide in electrochromic displays.

Claims

1. A method of producing an electrochromic contrast ratio greater than 1.2 by applying an electrochemical potential to particulate doped tin oxide in contact with mobile ions, thereby electrochromically activating said doped tin oxide particles, wherein said activated doped tin oxide electrochromically exhibits a contrast ratio greater than 1.2.

2. A method of generating an elcctrochromic reflectance having a linear relationship with an applied voltage comprising coating an electrode with an electrically conductive particulate electrochromic doped metal oxide having a surface area of at least 10 m² /g , and activating said electrochromic doped metal oxide to exhibit a contrast ratio greater than 1.2.

3. The method of claim 2 wherein the electrochromic doped metal oxide has distinctly different colors in its oxidized and reduced forms.

4. A method for producing a change in electrochromic reflectance of an electrochromic device to which a voltage is applied comprising changing the applied voltage wherein the change in reflectance is a linear function of the applied voltage, said device comprising electrochromically activated particulate doped metal oxide, wherein said activated doped metal oxide electrochromically exhibits a contrast ratio greater than 1 2.