Silicone gel composition and silicone gel produced therefrom

• US 6,169,155 B1
• Filed: 01/14/1999
• Issued: 01/02/2001
• Est. Priority Date: 01/14/1999
• Status: Expired due to Term

• Current Assignee: Dow Corning Corporation (Dow, Inc.)
• Original Assignee: Dow Corning Corporation (Dow, Inc.)
• Inventors: Stanga, Michael Allen, Alvarez, Khristopher Edward, Strong, Michael Raymond, Berry, Paul Anthony
• Primary Examiner(s): Moore, Margaret G.
• Application Number:
  US09/231,447
• Time in Patent Office: 719 Days
• Field of Search: 528/15, 528/31, 528/32, 525/478
• US Class Current: 528/15
• CPC Class Codes: C08G 77/045 containing less than 25 silicon atoms
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/24 halogen-containing groups
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08L 2666/44 Silicon-containing compounds
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes

Abstract

A silicone gel composition, (A) 100 parts by weight of a first polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule and having a viscosity of from 0.2 to 10 Pa·s at 25° C.; (B) at least about 0.5 part by weight of a second polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule, wherein the second polydiorganosiloxane has a viscosity at 25° C. of at least four times the viscosity of the first polydiorganosiloxane at 25° C.; (C) an organohydrogensiloxane having the average formula R⁷Si(SiOR⁸₂H)₃ wherein R⁷ is an alkyl group having 1 to 18 carbon atoms or aryl, R⁸ is an alkyl group having 1 to 4 carbon atoms, in an amount sufficient to provide from 0.1 to 1.5 silicon-bonded hydrogen atoms per alkenyl group in components (A) and (B) combined; and (D) a hydrosilylation catalyst in an amount sufficient to cure the composition. A silicone gel comprising a reaction product of the silicone gel composition. A kit for preparing a silicone gel composition.

Claims

1. A silicone gel composition, comprising:

(A) 100 parts by weight of a first polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule and having a viscosity of from 0.2 to 10 Pa·

s at 25°

C.;

(B) at least about 0.5 part by weight to about 10 parts by weight of a second polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule, wherein the second polydiorganosiloxane has a viscosity at 25°

C. of at least four times the viscosity of the first polydiorganosiloxane at 25°

C.;

(C) an organohydrogensiloxane having the average formula R⁷Si(SiOR⁸₂H)₃ wherein R⁷ is an alkyl group having 1 to 18 carbon atoms or aryl, R⁸ is an alkyl group having 1 to 4 carbon atoms, in an amount sufficient to provide from 0.1 to 1.5 silicon-bonded hydrogen atoms per alkenyl group in components (A) and (B) combined; and

(D) a hydrosilylation catalyst in an amount sufficient to cure the composition.

2. The composition according to claim 1, wherein the viscosity of component (A) is from 0.2 to 5 Pa·

s at 25°

C.

3. The composition according to claim 2, wherein the viscosity of component (A) is from 0.2 to 3 Pa·

s at 25°

C.

4. The composition according to claim 1, wherein component (A) has the formula R⁴R³₂SiO(R³₂SiO)_nSiR³₂R⁴ wherein each R³ is independently selected from the group consisting of monovalent hydrocarbon and monovalent halogenated hydrocarbon groups free of aliphatic unsaturation, R⁴ is alkenyl, and n has a value such that the viscosity of component (A) is from 0.2 to 10 Pa·

s at 25°

C.

5. The composition according to claim 4 wherein R³ is methyl, R⁴ is vinyl, and n has a value such that the viscosity of component (A) is from 0.3 to 0.6 Pa·

s at 25°

C.

6. The composition according to claim 5, wherein component (B) is a dimethylvinylsiloxy-terminated polydimethylsiloxane having a viscosity of from 45 to 65 Pa·

s at 25°

C.

7. The composition according to claim 1, wherein component (B) has the formula R⁶R⁵₂SiO(R⁵₂SiO)_nSiR⁵₂R⁶ wherein each R⁵ is independently selected from the group consisting of monovalent hydrocarbon and monovalent halogenated hydrocarbon groups free of aliphatic unsaturation, R⁶ is alkenyl, and n has a value such that the viscosity of component (B) at 25°

C. is at least four times the viscosity of component (A) at 25°

C.

8. The composition according to claim 1, wherein the concentration of component (B) is from about 1 to about 5 parts by weight per 100 parts by weight of component (A).

9. The composition according to claim 1, wherein the organohydrogensiloxane has the formula CH₃CH₂CH₂Si(SiOMe₂H)₃.

10. The composition according to claim 1, wherein the component (C) is present in an amount sufficient to provide from 0.3 to 1.1 silicon-bonded hydrogen atoms per alkenyl group in components (A) and (B) combined.

11. The composition according to claim 1, wherein the hydrosilylation catalyst is a platinum catalyst.

12. The composition according to claim 1, further comprising a catalyst inhibitor.

13. The composition according to claim 1, further comprising a non-functional silicone fluid.

14. The composition according to claim 13, wherein the silicone fluid has a viscosity of from 0.02 Pa·

s to 10 Pa·

s at 25°

C.

15. The composition according to claim 13, wherein the non-functional silicone fluid is present in an amount from 30 to 150 parts by weight per 100 parts by weight of component (A).

16. The composition according to claim 13, wherein the non-functional silicone fluid has a formula selected from the group consisting of [(R⁹)₂SiO]_n and (R⁹)₃SiO—

[(R⁹)SiO]_q—

Si(R⁹)₃ wherein each R⁹ is independently selected from the group consisting of alkyl, aryl, and —

[(R¹⁰)SiO]_p—

Si(R¹⁰)₃ wherein R¹⁰ is alkyl or aryl, n is from about 2 to about 10, p is 0 or greater, and q is 0 or greater.

17. The composition according to claim 16, wherein the non-functional silicone fluid is a linear trimethylsiloxy-terminated polydimethlysiloxane having a viscosity of about 0.1 Pa·

s at 25°

C.

18. A silicone gel, comprising a reaction product of the composition of claim 1.

19. A silicone gel, comprising a reaction product of the composition of claim 2.

20. A silicone gel, comprising a reaction product of the composition of claim 4.

21. A silicone gel, comprising a reaction product of the composition of claim 7.

22. A silicone gel, comprising a reaction product of the composition of claim 9.

23. A silicone gel, comprising a reaction product of the composition of claim 11.

24. A multi-part silicone composition, comprising:

(A) 100 parts by weight of a first polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule and having a viscosity of from 0.2 to 10 Pa·

s at 25°

C.;

(B) at least about 0.5 part by weight to about 10 parts by weight of a second polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule, wherein the second polydiorganosiloxane has a viscosity at 25°

C. of at least four times the viscosity of the first polydiorganosiloxane at 25°

C.;

(C) an organohydrogensiloxane having the average formula R⁷Si(SiOR⁸₂H)₃ wherein R⁷ is an alkyl group having 1 to 18 carbon atoms or aryl, R⁸ is an alkyl group having 1 to 4 carbon atoms, in an amount sufficient to provide from 0.1 to 1.5 silicon-bonded hydrogen atoms per alkenyl group in components (A) and (B) combined; and

(D) a hydrosilylation catalyst in an amount sufficient to cure the composition, provided neither component (A) nor component (B) are present with components (C) and (D) in the same part.

25. A kit for preparing a silicone gel composition, comprising:

a first package containing a homogeneous mixture of

(A) 5 to 95 parts by weight of a first polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule and having a viscosity of from 0.2 to 10 Pa·

s at 25°

C.;

(B) 0 to 10 parts by weight of a second polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule, wherein the second polydiorganosiloxane has a viscosity at 25°

C. of at least four times the viscosity of the first polydiorganosiloxane at 25°

C.; and

(D) a hydrosilylation catalyst; and

a second package containing

(A) 95 to 5 parts by weight of a first polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule and having a viscosity of from 0.2 to 10 Pa·

s at 25°

C.;

(B) 0 to 10 parts by weight of a second polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule, wherein the second polydiorganosiloxane has a viscosity at 25°

C. of at least four times the viscosity of the first polydiorganosiloxane at 25°

C.; and

(C) an organohydrogensiloxane having the average formula R⁷Si(OSiR⁸₂H)₃ wherein R⁷ is an alkyl group having 1 to 18 carbon atoms or aryl, R⁸ is an alkyl group having 1 to 4 carbon atoms, and wherein the amount of component (A) in the first package and the second package combined is 100 parts by weight, the amount of component (B) in the first package and the second package combined is at least about 0.5 part by weight to about 10 parts by weight, component (C) is present in an amount sufficient to provide from 0.1 to 1.5 silicon-bonded hydrogen atoms per alkenyl group in components (A) and (B) in the first package and the second package combined; and

component (D) is present in an amount sufficient to cure the composition formed by combining the first package and the second package.